• 한국세라믹학회지
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• 제54권6호
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• pp.506-510
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• 2017

One of the characteristics of polycrystalline graphene that determines its material properties is grain size. Mechanical properties such as Young's modulus, yield strain and tensile strength depend on the grain size and show a reverse Hall-Petch effect at small grain size limit for some properties under certain conditions. While there is agreement on the grain size effect for Young's modulus and yield strain, certain MD simulations have led to disagreement for tensile strength. Song et al. showed a decreasing behavior for tensile strength, that is, a pseudo Hall-Petch effect for the small grain size domain up to 5 nm. On the other hand, Sha et al. showed an increasing behavior, a reverse Hall-Petch effect, for grain size domain up to 10 nm. Mortazavi et al. also showed results similar to those of Sha et al. We suspect that the main difference of these two inconsistent results is due to the different modeling. The modeling of polycrystalline graphene with regular size and (hexagonal) shape shows the pseudo Hall-Petch effect, while the modeling with random size and shape shows the reverse Hall-Petch effect. Therefore, this study is conducted to confirm that different modeling is the main reason for the different behavior of tensile strength of the polycrystalline structures. We conducted MD simulations with models derived from the Voronoi tessellation for two types of grain size distributions. One type is grains of relatively similar sizes; the other is grains of random sizes. We found that the pseudo Hall-Petch effect and the reverse Hall-Petch effect of tensile strength were consistently shown for the two different models. We suspect that this result comes from the different crack paths, which are related to the grain patterns in the models.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 춘계학술대회논문집
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• pp.49-52
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• 2003

The effects of nitrogen on the deformation behavior of duplex stainless steel have been studied The variation of strength was correlated with the characteristic microstructures. Analysis based on Hall-Petch relation confirmed that nitrogen enhances phase-boundary strengthening effect. The evolution of dislocation structure, slip traces, and misorientation distribution during deformation were also characterized to elucidate the effect of nitrogen on inelastic deformation mechanism.

• Composites Research
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• 제29권6호
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• pp.375-378
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• 2016

Characteristics of nanocrystalline materials are known substantially dependent on the microstructure such as grain size, crystal orientation, and grain boundary. Thus it is desired to have systematic characterization methods on the various nanomaterials with complex geometries, especially in low dimensional nature. One of the interested nanomaterials would be a pure two-dimensional material, graphene, with superior mechanical, thermal, and electrical properties. In this study, mechanical properties of "polycrystalline" graphene were numerically investigated by molecular dynamics simulations. Subdomains with various sizes would be generated in the polycrystalline graphene during the fabrication such as chemical vapor deposition process. The atomic models of polycrystalline graphene were generated using Voronoi tessellation method. Stress strain curves for tensile deformation were obtained for various grain sizes (5~40 nm) and their mechanical properties were determined. It was found that, as the grain size increases, Young's modulus increases showing the reverse Hall-Petch effect. However, the fracture strain decreases in the same region, while the ultimate tensile strength (UTS) rather shows slight increasing behavior. We found that the polycrystalline graphene shows the reverse Hall-Petch effect over the simulated domain of grain size (< 40 nm).

• 소성∙가공
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• 제14권1호
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• pp.65-70
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• 2005

A phase mixture model was employed to simulate the deformation behaviour of metallic materials covering a wide grain size range from micrometer to nanometer scale. In this model a polycrystalline material is treated as a mixture of two phases: grain interior phase whose plastic deformation is governed by dislocation and diffusion mechanisms and grain boundary 'phase' whose plastic flow is controlled by a boundary diffusion mechanism. The main target of this study was the effect of grain size on stress and its strain rate sensitivity as well as on the strain hardening. Conventional Hall-Petch behaviour in coarse grained materials at high strain rates governed by the dislocation glide mechanism was shown to be replaced with inverse Hall-Petch behaviour in ultrafine grained materials at low strain rates, when both phases deform predominantly by diffusion controlled mechanisms. The model predictions are illustrated by examples from literature.

• Composites Research
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• 제32권3호
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• pp.141-147
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• 2019

In this study, micro-sized and nano-sized pure aluminum (Al) powders were compressed by unidirectional pressure at room temperature. Although neither type of Al bulk was heated, they had a high relative density and improved mechanical properties. The microstructural analysis showed a difference in the process of densification according to particle size, and the mechanical properties were measured by the Vickers hardness test and the nano indentation test. The Vickers hardness of micro Al and nano Al fabricated in this study was five to eight times that of ordinary Al. The grain refinement effect was considered to be one of the strengthening factors, and the Hall-Petch equation was introduced to analyze the improved hardness caused by grain size reduction. In addition, the effect of particle size and dispersion of aluminum oxide in the bulk were additionally considered. Based on these results, the present study facilitates the examination of the effect of particle size on the mechanical properties of compacted bulk fabricated by the powder metallurgy method and suggests the possible way to improve the mechanical properties of nano-crystalline powders.

• 열처리공학회지
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• 제33권6호
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• pp.271-276
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• 2020

The relationship between the hardness and interlamellar spacing of discontinuous precipitates (DPs) formed by continuous cooling was studied for Mg-9%Al-1%Zn alloy. After solution treatment at 683 K for 24 h, the specimens were cooled to room temperature with different cooling rates ranging from 0.2 to 2 K·min^-1, in order to obtain DPs with various interlamellar spacings. It was found that cooling rate of 2 K·min^-1 yielded only small amount of nodular DPs at the grain boundaries, while cooling rates below 2 K·min^-1 yielded both DPs and continuous precipitates (CPs). The volume fraction of DPs increased with increasing cooling rate up to 0.5 K·min^-1, over which it abruptly decreased. The hardness of DPs was increased with an increase in the cooling rate, whereas the interlamellar spacing of the DPs was decreased with respect to cooling rate. The hardness of the DPs formed by continuous cooling was correlated with the interlamellar spacing and can follow a Hall-Petch type relation as in the case of pearlite with lamellar morphology.

• 한국표면공학회지
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• 제35권3호
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• pp.158-164
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• 2002

Nanocomposites consisting of a nanocrystalline brass matrix (grain size ; 20-100nm) with sub-micron sized Al2O3 particles (60-200nm) were prepared by pulsed current electrodeposition. The microhardness of the nanocomposite with a grain size of 90-100nm was approximately 1.7 times higher than that of a comparable electrodeposit with no particles. However, significant variations in microhardness were not observed between the nanocomposites with grain sizes of 20 nm and the comparable electrodeposit.

• 소성∙가공
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• 제12권4호
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• pp.284-289
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• 2003

The effects of nitrogen on the deformation behavior of duplex stainless steel have been studied. The variation of strength was correlated with the characteristic microstructures pertaining to nitrogen. Analysis based on Hall-fetch relation confirmed that nitrogen enhances phase-boundary strengthening effect. The evolution of dislocation structure, slip traces and misorientation distribution during deformation were also characterized to elucidate the effect of nitrogen on inelastic deformation mechanism. It has been verified in this study that the higher nitrogen content provides a dual-phase microstructure with smaller strength difference between austenite and ferrite resulting into the earlier transfer of inelastic deformation from austenite to ferrite.

• 한국세라믹학회지
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• 제50권1호
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• pp.37-42
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• 2013

Tristructural-isotropic (TRISO)-coated particles were fabricated by a fluidized-bed chemical vapor deposition (FBCVD) method for use in a very high temperature gas-cooled reactor (VHTR). ZrC as a constituent layer of TRISO coating layers was deposited by a chloride process using $ZrCl_4$ and $CH_4$ source gases in a temperature range of $1400^{\circ}C$ and $1550^{\circ}C$. The change in the microstructure of ZrC depending on the deposition temperature and its effect on the hardness were evaluated. As the deposition temperature increased to $1500^{\circ}C$, the grain size of the ZrC increased and the hardness of the ZrC decreased according to the Hall-Petch relationship. However, at $1550^{\circ}C$, the ZrC layer was highly non-stoichiometric and carbon-rich and did not obey the Hall-Petch relationship in spite of the decrease of the grain size. A considerable amount of pyrolytic carbon at the grain boundaries of the ZrC as well as coarse granular pyrolytic carbon were locally distributed in the ZrC layer deposited at $1550^{\circ}C$. Therefore, the hardness decreased largely due to the formation of a large amount of pyrolytic carbon in the ZrC layer.

• 한국재료학회지
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• 제4권2호
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• pp.241-249
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• 1994

항공기용 고력 AI합금인 7075 AI합금의 물성개선을 위한 가공열처리 방안으로서 과시효처리후 온간 및 냉간 압연에 의한 소성가공이 재결정조직과 강도에 미치는 영향에 대하여 연구하였다. 소송가공후 재결정처리에 의해 결정립을 미세화하는 공정에서 소성가공 전 과시효를 함으로써 재결정립의 미세화 정도는 더욱 현저하였다. 이는 과시효에 의한 조대한 석출물이 재결정처리시 핵생성 site로서 작용하였음을 의미한다. 본 연구에서 항복강도와 재결정립의 크기와는 Hall-petch식을 만족하지 않았으며 이는 등축이 아닌 연신된 결정조직에 기인된 결과로 보이며, 항복강도가 재결정립의 종횡비에 직선적으로 비례하였다. 또한 결정립 미세화를 통한 강도, 인성향상을 목적으로 하는 TMT(Thermo mechanical Treatment)공정에서는 심한 냉간가공에 의해서보다는 온간에서의 소성가공이 바람직함을 알 수 있었다.