• Fire Science and Engineering
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• v.15 no.1
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• pp.34-40
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• 2001

Fire extinguishing efficiency of mixed gaseous agents were investigated by the cup-burner test and predicting by the model of flame extinguishing concentration. The binary mixed agents that tested were carbon dioxide/HFC-23, carbon dioxide/HCFC-22, carbon dioxide/HFC-227ea, carbon dioxide/HFC-125, carbon dioxide/FIC-13I1, Hexafluoropropylene/HFC-23 and ternary mixed agents were carbon dioxide/HFC-23/HFC-l34a, carbon dioxide/HFC-23/HFC-227ea, carbon dioxide/HFC-23/HFC-125. A model which contains the flame extinguishing concentration and composition of pure components predicted the flame extinguishing concentration of mixture well. This model was superior when each component of the mixture exhibit physical fire extinguishing performance.

• Fire Science and Engineering
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• v.12 no.1
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• pp.9-14
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• 1998

The hepatfluoropropane(HFC-227ea) synthesis by fluorinatino of hepafluoroproylene(HFP) over activated carbon has been studied. The reaction temperature was varied from 5$0^{\circ}C$ to 40$0^{\circ}C$ at a constant feed mole ration and a residence time. The optimized reaction temperature was found to be about 20$0^{\circ}C$ at 2.5HF/HFP mole ratio and 238 sec. residence time. From these reaction conditions, the yield of HFC-227ea was obtained above 99% and the deactivation of activated carbon was not appeared. Accordingly, the activated carbon showed good performance to obtain heptafluoropropane by fluorinatin of hexafluoropropylene.

• Fire Science and Engineering
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• v.16 no.3
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• pp.16-25
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• 2002

For Freon-23, a conventional extinguished agent regulated by Montreal Protocol and HFC-227ea, its alternative, the empirical equations were correlated in terms of saturated pressure, density, viscosity, enthalpy and surface tension. They were obtained by regression analysis from the experimental data in the literature. The empirical equations of saturated pressure were expressed as the second and third order function of temperature. The empirical equation of density was expressed as compressibility factor and saturated pressure by a function of temperature. The empirical equation of viscosity was formulated as a power function. Heat capacities as well as enthalpies were well fitted by empirical form of the second-order temperature. Finally, surface tension simply has linear function form in terms of temperature.

• Fire Science and Engineering
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• v.18 no.1
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• pp.7-12
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• 2004

For CFCs and Halons regulated by Montreal Protocol and their alternatives of HFC-23, HFC-125 HFC-227ea, HFC-236fa and the mixtures of inert gases of $Ar, N_2 and CO_2$, the thermodynamic properties of saturated pressure, density, enthalpy and viscosity were compared. In this study, the data from literature were expressed as a function of temperature. Thermodynamic properties of HFC compounds were similar to those of Halon-1301. Inert gas was mainly used as a mixture, but the physical properties of the inert gas does not have the favorable advantages over those of Halon-1301.

• Fire Science and Engineering
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• v.28 no.4
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• pp.1-7
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• 2014

Several complex devices and equipments are installed in the car's engine room, including various kind of oils or other flammable materials. So re-ignition is very likely to take place in it. In addition, it is restrictive for the driver or the occupant to open the bonnet and to spray the fire extinguisher in the engine room due to the high possibility of explosion. Therefore, a fire extinguishing system, which can detect a fire and inject the fire extinguishing agent to extinguish it, and fire extinguishing agents including HFC-227ea, which can stand the high temperature within the engine room and hold the viscosity sufficient to keep it in the kind of foam, were developed and tested. And the suffocation effect and the cooling effect come from the fire extinguishing principle of the foam fire extinguishing agent and the inhibiter catalyst effect come from the one of HFC-227ea was led simultaneously, and fire extinguishing agents without the secondary damage caused by residuals after the fire extinguishment like a case of the powder fire extinguishing agent, were developed. And experiments using a vehicle collision after the discharge is complete, foreign material can be removed without extinguishing the advantage that experimental results obtained.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.704-710
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• 2017

Although the desalination technique using gas hydrate formation is at a development stage compared to the commercially well-established reverse osmosis (RO), it still draws attention because of its simplicity and moderate operational conditions especially when using refrigerants for guest gases. In this study, DFT (density functional theory)-based molecular modeling was employed to explain the energetics of the gas hydrate formation using HFC (hydrofluorocarbon) and HCFC (hydrochlorofluorocarbon) refrigerants. For guest gases, R-134a, R-227ea, R-236fa, and R-141b were selected and three cavity structures ($5^{12}$, $5^{12}6^2$, and $5^{12}6^4$) composed of water molecules were constructed. The geometries of guest gas, cavity, and cavity encapsulating guest gas were optimized by molecular modeling respectively and their located energies were then used for the calculation of binding energy between the guest gas and cavity. Finally, the comparison of binding energies was used to propose which refrigerant is more favorable for the gas hydrate formation energetically. In conclusion, R-236fa was the best choice in terms of thermodynamic spontaneity, less toxicity, and low solubility in water.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 1997.11a
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• pp.542-549
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• 1997

HFC-227ea and HCFC Blend A were evaluated using full-scale fire tests to obtain information on their fire suppression performance, drop-in capability, thermal decomposition products and physical behaviour of the agent such as its flow characteristics in the piping system. Also, full-scale tests were conducted with Halon 1301 to provide a basis for comparison. Halon 1301, at concentrations of 5% to 7.5%, showed effective total-flooding fire- extinguishing performance for all test scenarios. HFC-227ea, at a design concentration of 7.6% or higher, and HCFC Blend A, at a design concentration of 12%, extinguished all fires in the test facility, however, these agents produced higher concentrations of acid gases than Halon 1301. The quantity of the acid gases generated during fire suppression was dependent on agent concentration, agent discharge time, fire type and size as well as extinguishment time.

• Journal of the Korean Institute of Gas
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• v.11 no.3
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• pp.7-12
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• 2007

The search for a new fire-extinguishing agent with all the desirable properties of halon 1301 has not been successful. To study binary gaseous extinguishing agents instead, one has to determine the extinguishing concentrations for several compositions of a given chemical in an inert gas. This process is expensive and time consuming. The fire suppression efficiencies of gas mixtures of HFC 125 and HFC 227ea with nitrogen as total flooding agents were studied by cup burner method. It was shown that addition of small amounts of those extinguishants to nitrogen can enhance the suppression effectiveness of the inert gas. As expected, the degree of synergism was highest at low concentrations of the chemical. For each binary system, extinguishing concentrations of the pure compounds and one binary data were used to predict the extinguishing concentrations for the entire range of binary composition. The predicted values were very close to experimental data.

• Journal of the Korean Institute of Gas
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• v.20 no.2
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• pp.30-34
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• 2016

In this study, we synthesized a phenol foam using a resol-type phenol resin as a research for replacing the polyurethane foam used as an insulator for cryogenic temperature, such as LNG or LPG. Foaming agents for synthesizing a phenolic foam was used HCFC-141b or n-pentane, cyclopentane, n-hexane, cyclohexane and a mixture of HFC-365mfc and HFC-227ea respectively. Cyclohexane as a blowing agent exhibited the most superior insulating performance and compressive strength. The heat resistance of polyurethane foam and phenolic foam blown by the cyclohexane, was higher than polyurethane foam.

• Fire Science and Engineering
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• v.10 no.3
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• pp.29-40
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• 1996

The AFFF(Aqueous Film Forming Foam : 3M Company's Light Water) agent are synthetic compounds that foams which are similar to those produced by protein based materials. The foam extinguishing agent was used In the extinguisher was the AFFF agent. We sought, however, to make other foams by using halon 1301 (CF$_3$Br) and halon alternatives, such as HCFC Blend A($CHCIF_2$ 82%, $CF_3$CHCIF 9.5%m $C_{10}$$H_{16}$ 3.75%), HFC-227ea ($CF_3$ $CHFCF_3$) We selected these alternatives instead of air in order to raise the expansion ratio of the AFFF agent. By these means we discovered that it is possible to increase the expansion ratio of the AFFF agent up to 44:1 and up to 24:1 when HFC-227ea was used as a halon alternatives. Therefore our new foam extinguishing agents can be used in a portable extinguish agents can be used in a portable extinguishers.