• Journal of the Korean Society of Clothing and Textiles
• /
• v.23 no.4
• /
• pp.584-592
• /
• 1999

Highly conductive polyaniline(PAn)-nylon 6 composite fabric was prepared by immersing the nylon 6 fabric in 0.5M aniline+0.35M HCl aqueous solution at 4$0^{\circ}C$ for 2hours, Polymerization was then followed by mixing the prepared oxidant and dopant solution(0.5M(NH4)2S2O+0.35M HCl) to the diffusion bath at 5$^{\circ}C$ for 30 minutes. The conductivity of prepared PAn-nylon 6 composite fabrics reached as high as 0.5$\times$10-1S/cm. Their conductivity were significantly affected by the aniline and oxidant concentration. As compared to those of nylon 6 fabric heat of fusion melting point the degree of crystallinity and tensile strength of PAn-nylon 6 did not significantly changed by inclusion of PAn. In the aspect of serviceability wheras the fabric conductivity was significantly decreased after multiple washion no significant changes in the fabric conductivity were observed after abrading the composite fabric over 50 cycles. However we found that the fabric conductivity could be recovered by acid re-doping with HCl.

• Journal of the Korean Chemical Society
• /
• v.59 no.5
• /
• pp.423-428
• /
• 2015

(1S)-(+)-10-camphorsulfonic acid (CSA) and HCl were used together as a binary dopant in the electrodeposition of polyaniline (PAni). (+)-CSA and HCl were added in different mole ratios (9:1 and 6:4). (+)-CSA-doped and binary-doped PAni exhibited markedly different ultraviolet-visible and circular dichroism spectral characteristics due to differences in their conformations. Distinct helical structures are observed in the scanning electron microscopy images of (+)-CSA-doped PAni. The X-ray diffraction pattern of (+)-CSA-doped PAni exhibited remarkably higher crystallinity than that of HCl-doped PAni which is associated with the helical ordering along the polymer chains. The conformational changes due to the binary doping in chiral PAni had a significant effect on its chiroptical and electrochemical properties, morphology, and crystallinity, thus determined its conductivity.

• Journal of the Korean Applied Science and Technology
• /
• v.32 no.1
• /
• pp.85-92
• /
• 2015

The 50 mole% HCl doped polyaniline(PAni) was synthesized by polymerization of aniline in the presence of hydrochloric acid and ammonium persulfate(APS) as dopant and oxidant, respectively. Then, conducting biodegradable cellulose acetate composite films were also prepared with PAni in acetone to find their applicability to antistatic packaging materials. The tensile strength of PCA05 film with 5 wt% of PAni was decreased by 27% from $377.1kg_f/cm^2$ for CA film itself to $275.2kg_f/cm^2$. Elongation was also decreased from 7.65% to 4.35%. Surface registance of $7.0{\times}10^9{\Omega}/sq$ could be achieved for the PCA containing 5 wt% of PAni. Therefore, this PCA05 film can be applied to antistatic package film for electronic board. In addition, decomposition temperature of these PCA films obtained by thermogravimetric analysis(TGA) was decreased with the amount of PAni in PCA films, and the final weight of char was directly proportional to PAni contents. From this thermal result we can calculate the content of PAni in unknown PCA films.

• Polymer(Korea)
• /
• v.33 no.3
• /
• pp.203-206
• /
• 2009

Polyaniline Emeraldine salt (PANI-salt) prepared by the common chemical oxidative polymerization caused the corrosion of the metallic injection mold by protonic acid such as HCl which used as a dopant. PANI-salt, polyaniline doped with dodecylbenzenesulfonic acid (DBSA), was obtained by the emulsion polymerization in nonpolar organic solvent, toluene. In this study DBSA was used as a dopant along with a surfactant. PANI-salt and high impact polystyrene (HIPS) have a good solubility in toluene. Blends with different ratio of PANI and HIPS were prepared through a solution-cast blending. The structure of PANI-salt was characterized by FT-IR and UV-Vis. The morphology, thermal, and electrical properties for PANI-HIPS blends were investigated. Injection molded under $103^{\circ}C$, 120 psi, PANI-HIPS showed the highest electrical conductivity ($6.02{\times}10^{-5}\;S/cm$) after blending PANI (50 mL) and HIPS (1 g).

• Journal of the Korean Chemical Society
• /
• v.58 no.5
• /
• pp.456-462
• /
• 2014

Binary-doped conducting chiral polyaniline (PAni) was synthesized by electrochemical polymerization of aniline at low-temperature ($0^{\circ}C$) and room-temperature (RT) conditions. (+)-Camphorsulfonic acid (CSA) and hydrochloric acid (HCl) were used as a binary dopant. Formation of the binary-doped PAni rather than a mixture of the corresponding single-doped PAni was confirmed by cyclic voltammogram, FT-IR and circular dichroism spectra. The temperature influenced the electrochemical behavior and doping level, thus determining the crystallinity and morphology of the PAni. However, among other results, morphology of the PAni is found to be most strongly depends on the polymerization temperature. With increased temperature from the initial state to RT, morphology of the PAni changed from fibrous to short-fibrous structure. The sheet resistance of the PAni films on an ITO was measured by using four-point probe dc method.

• Journal of the Korean Ceramic Society
• /
• v.28 no.7
• /
• pp.517-524
• /
• 1991

The CVD process of BPSG (BoroPhosphoSilicate Glass) and its thin film properties were studied. B2H6, PH3, SiH4 and O2 gases were reacted in a AP (Atmospheric Pressure) CVD system in the temperature range of 300℃ and 460℃. The interaction of B2H6 and PH3 was studied from the deposition rate and dopant incorporation change point of view. The dependency of BPSG step coverage on the temperature was changed with different O2/(B2H6+PH3+SiH4) ratio. Finally, the boundary which distinguishes the stable BPSG's from the ones that react with Di (Deionized) water or cleaning chemicals such as H2SO4, HCl, H2O2, NH4OH etc could be defined.

• Applied Chemistry for Engineering
• /
• v.8 no.2
• /
• pp.172-178
• /
• 1997

Polyaniline(PANI)-stearic acid(SA) composite monolayer was formed at the air-water interface. The stearic acid as a surfactant was used to promote PANI monolayer formation. Uniform PANI-SA monolayer assemblies with Y type and transfer ratio of ca. 1 were fabricated using the Langmuir-Blodgett(LB) technique. The PANI-SA composite LB films with high electrical conductivity of $10^{-1}{\sim}10^{-2}S/cm$ were obtained by doping of HCl or $I_2$, and their conductivity revealed essentially close value as that of conventional PAHI-HCl complex. Especially, iodine is found to be the most promising dopant, since it gives a remarkable stability for the application as a polymer electrode in the MIM molecular device consisted of acceptor, sensitizer, and donor. The structure and physical properties of PANI-SA LB films were investigated through the near-ir UV, FT-IR, and Cyclic voltammetry.