• Journal of Sensor Science and Technology
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• v.26 no.6
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• pp.420-426
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• 2017

A colorimetric sensor was investigated to achieve a low-cost warning device for harmful gaseous formaldehyde (HCHO). The sensor is based on selective reactions between hydroxylamine sulfate and HCHO, leading to the production of sulfuric acid. The produced acid results in color-changing response through the acid-base reaction with dye molecules impregnated on a solid membrane substrate. For attaining this purpose, sensors were fabricated by drop-casting a dye solution prepared using different pH indicators on various commercially available polymer sheets, and their colorimetric responses were evaluated in terms of sensitivity and reliability. The colorimetric sensor using bromophenol blue (BPB) and nylon sheet was found to exhibit the best performance in HCHO detection. An initial bluish green of a sensor was changed to yellow when exposed to gaseous formaldehyde. The color change was recorded using an office scanner and further analyzed in term of RGB distance for quantifying sensor's response at different HCHO(g) concentrations. It exhibited a recognizable colorimetric response even at 50 ppb, being lower than WHO's standard of 80 ppb. In addition, the sensor was found to have quite good selectivity in HCHO detection under the presence of common volatile organic compounds such as ethanol, toluene, and hexane.

• Korean Journal of Remote Sensing
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• v.35 no.4
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• pp.503-516
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• 2019

We have estimated the vertical column density (VCD) of formaldehyde (HCHO) on a global scale using a multiple linear regression method (MRM) with Ozone Monitoring Instrument (OMI) and Moderate-Resolution Imaging Spectroradiometer (MODIS) data. HCHO VCDs were estimated in regions of biogenic, pyrogenic, and anthropogenic emissions using independent variables, including $NO_2$ VCD, land surface temperature (LST), an enhanced vegetation index (EVI), and the mean fire radiative power (MFRP), which are strongly correlated with HCHO. To evaluate the HCHO estimates obtained using the MRM, we compared estimates of HCHO VCD data measured by OMI ($HCHO_{OMI}$) with those estimated by multiple linear regression equations (MRE) ($HCHO_{MRE}$). Good MRM performances were found, having the average statistical values (R = 0.91, slope = 1.03, mean bias = $-0.12{\times}10^{15}molecules\;cm^{-2}$, percent difference = 11.27%) between $HCHO_{MRE}$ and $HCHO_{OMI}$ in our study regions where high HCHO levels are present. Our results demonstrate that the MRM can be a useful tool for estimating atmospheric HCHO levels.

• Journal of the Korean Society of Radiology
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• v.15 no.7
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• pp.1057-1064
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• 2021

This study was conducted by simulating the same environmental conditions as the actual biopsy to observe the change in formaldehyde(HCHO) concentration in the indoor air during ultrasound guided biopsy. Changes in HCHO concentration in the room were measured by successively performing five steps: sealing the ultrasound room, ventilation, opening formalin containers, sealing formalin containers, and re-ventilating. Trends of measured HCHO concentration changes were visualized using graphs. As a result of analyzing the consistency of the concentration change values measured three times using the intra-class correlation coefficient, it was found to be 0.989, which was statistically significant(p<0.05). Based on the results of this study, we hope that medical workers working in the HCHO exposure environment of the field of radiology part will improve their awareness of the necessity of exposure management at work, and actively discuss the establishment of an environment for exposure control and preparation of countermeasures.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.63-71
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• 2006

An automated carbonyl measurement system was constructed. Atmospheric carbonyl compounds were extracted onto DNPH containing collection solution while flowing through a glass coil. Each carbonyl species was separated on a HPLC column and quantified by UV absorption detector. Using this system, carbonyl compounds were continuously measured at the campus of Korea University in Seoul, Korea during June, 2005. Sampling resolution was 30 minutes and the detection limit of HCHO was 0.19 ppbv. Also, $\O_{3}$, it's precursors, and meteorological parameters were measured. The maximum, minimum, average, and median concentrations of HCHO during the whole experiment was 35.8 ppbv, 1.4 ppbv, 11.7 ppbv, and 9.3 ppbv respectively. Formaldehyde showed a distinct diurnal variation with a broad maximum around 13 $\sim$ 15, which was 1 $\sim$ 3 hours ahead of an ozone maximum. During a couple of days, however, HCHO concentrations were kept high through the night or increased concomitantly with NOx in the morning. These results imply that HCHO was mainly produced from the photochemical oxidation of VOCs, but local emission sources couldn't be ruled out. The differences between daily maximum and minimum of $O_{3}$ and HCHO were calculated for 11 days of June, when typical diurnal variations were observed for the two species. A strong positive correlation was found between $\Delta O_{3}$ and $\Delta HCHO$ and the average mole ratio of $\Delta HCHO$ to $\Delta O_{3}$ was 2.6. It indicates that formaldehyde played a key role in $\Delta O_{3}$ production as an indicator species in Metropolitan Seoul during June, 2005.

• KIEAE Journal
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• v.10 no.4
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• pp.81-86
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• 2010

The main sources of the new house syndrome(sometimes it called sick building syndrome) are a concentration of formaldehyde (HCHO) and a concentration of total volatile organic compounds(TVOC). I had field measurements of indoor air quality in the apartment unit at medium-size cities(Y city, C city). I measured indoor air temperature, HCHO concentration in 16 units, TVOC concentration in 6 units and air tightness in 7 units. And I measured outdoor air quality, HCHO concentration and TVOC concentration. Mean concentration of HCHO was $357{\mu}g/m^3$(2006 standard=$120{\mu}g/m^3$), mean concentration of TVOC was $3,092{\mu}g/m^3$ and mean effective air leakage area was 193 cm2. There was a close relation between the indoor air temperature and HCHO concentration, between the indoor air temperature and TVOC concentration. Air tightness also had relation.

• Journal of Korean Society for Atmospheric Environment
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• v.18 no.1
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• pp.11-23
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• 2002

The concentrations of aldehydes were measured in downtown area of Buchun and Kwanghwamoon of Seoul from October 1997 to August 1998 using 2-series impingers. The data have been analysed to identify the seasonal pattern of aldehyde sources in metropolitan areas. The measured concentration (in ppbv) of aldehydes were 8.86 $\pm$ 7.28 HCHO (formaldehyde) and 7.79$\pm$7.29 $CH_3$CHO (acetaldehyde) in Buchun, while recording 10.13$\pm$8.58 (HCHO) and 7.64$\pm$6.65 ($CH_3$CHO) in Kwanghwamoon. Their diurnal variation patterns showed significant increase of HCHO and $CH_3$CHO concentration in early afternoon, indicating an increase in secondary sources. Their concentrations however decreased in the nighttime, regardless of seasons. The strength of correlations between certain pairs such as (1) HCHO and CO and (2) $CH_3$CHO and CO were generally high during the winter months (0.64< r < 0.84), suggesting the possibility of similar source processes for HCHO, $CH_3$CHO and CO. On the other hand during the summer months, their correlations are frequently lower than winter months. We suggested that the complexity of source/sink processes during the summer period may reduce the correlations between aldehyde and CO.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2001.11a
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• pp.163-164
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• 2001

휘발성유기화합물(VOCs)과 포름알데히드(HCHO)의 발생원은 매우 다양할 뿐만아니라 주변환경과 인체에 미치는 영향이 매우 크다. VOCs와 포름알데히드의 발생원으로는 크게 인위적인 발생원, 자연적인 발생원, 실내에서의 발생원으로 구분할 수 있다. 현대인들의 하루생활 중 80%이상이 실내에서 이루어지고 있어 실내에서의 발생되는 오염물질에 대한 특성파악과 적절한 제어방안이 요구된다. VOCs와 포름알데히드의 발생원중에서 실내에서의 발생원으로는 여러 가지가 있으나, 신축건물과 리모델링에 사용되는 건축자재에서의 방출은 매우 크다고 할 수 있다. (중략)

• Textile Coloration and Finishing
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• v.2 no.1
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• pp.14-20
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• 1990

The cotton fabrics were treated with formaldehyde in the presence of zinc nitrate catalyst and urea. The effects of HCHO concentration, urea concentration, catalyst ratio, cure time and cure temperature on the physical properties of fabrics were studied. Cotton fabric finished with HCHO and urea had the lower tensile strength and tear strength than untreated one. These strength losses resulted from tighter oxymethylene crosslinks. The enhanced wrinkle recovery for fabric treated with formaldehyde in the presence of urea was indicative of the formation of urea-formaldehyde polymer. These experimental conditions were set up according to table of orthogonal arrays.

• Journal of Sensor Science and Technology
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• v.17 no.3
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• pp.183-187
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• 2008

A sub-ppm level MEMS gas sensor that can be used for the detection of formaldehyde (HCHO) is presented. It is realized by using a zinc oxide (ZnO) thin-film material with a Ni-seed layer as a sensing material and by bulk micromachining technology. To enhance sensitivity of the MEMS gas sensor with Ni-seed layer was embedded with ZnO sensing material and sensing electrodes. As experimental results, the changed sensor resistance ratio for HCHO gas was 9.65 % for 10 ppb, 18.06 % for 100 ppb, and 35.7 % for 1 ppm, respectively. In addition, the minimum detection level of the fabricated MEMS gas sensor was 10 ppb for the HCHO gas. And the measured output voltage was about 0.94 V for 10 ppb HCHO gas concentration. The noise level of the fabricated MEMS gas sensor was about 50 mV. The response and recovery times were 3 and 5 min, respectively. The consumption power of the Pt micro-heater under sensor testing was 184 mW and its operating temperature was $400^{\circ}C$.

• Environmental Analysis Health and Toxicology
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• v.19 no.2
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• pp.177-182
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• 2004

Alcohol consumption and exposure to endocrine disruptors and industrial solvents have been implicated in impaired spermatogenesis, increase in the incidence of malformed sperm and decrease in the percentage of moving sperm. The aim of this study was to determine and compare the direct effects of some organic solvents(bisphenol A; BPA, dibutyl phthalate; DBP, formaldehyde; HCHO, dimethylsulphoxide; DMSO, ethanol) on mucus penetration distance, motility and survival rate of human sperm in vitro. Semen samples from 3 health subjects were prepared using swim-up method and 0.0005-0.5% organic solvents were added to the test medium. BPA, DBP, HCHO and DMSO produced significant decreases in the motility and survival rate with a different potency. The most potent inhibition of mucus penetration distance, motility and survival rate was observed after exposure to HCHO. A concentration of 0.0005% HCHO significantly inhibited sperm motility. When ethanol m.: added directly to sperm, at concentrations equivalent to that in serum after heavy drinking, these damaging effects were lowest compared with other solvents. Present study shows that each compound has different toxic potency to human sperm and we need special caution for the use of HCHO.