• 제목/요약/키워드: HCFC-123

검색결과 23건 처리시간 0.017초

Pentachloroethane의 불소화 반응에 관한 연구 (A Study on the Fluorination of Pentachloroethane)

  • 박건유;권영수;김훈식;이상득;이병권
    • 공업화학
    • /
    • 제4권2호
    • /
    • pp.318-323
    • /
    • 1993
  • CFC-11$(CFCl_3)$의 대체품인 HCFC-123$(CF_3CHCl_2)$의 합성을 위하여 Pentachloroethane($CHCl_2CCl_3$)을 제조하고, 이것을 antimony pentahalide 촉매의 존재하에서 불화수소와 반응시켰다. $CHCl_2CCl_3$의 불소화 반응은 촉매와 반응물간의 Cl-F교환 mechanism에 의해 진행되었으며 $CHCl_2CCl_3$의 불화도는 반응온도가 높을수록 증가하는 경향을 보여 주었다. 촉매농도 또한 생성물의 불화도에 영향을 미치나 반응온도에 비해 상대적으로 낮았다. $CCl_3CFCl_2$, $CFCl_2CFCl_2$, $CF_2ClCFCl_2$와 같은 부산물의 생성원인을 규명하기 위한 실험을 실시하여 부산물 생성 mechanism을 제안하였다.

  • PDF

수평 전열관내 비공비 혼합냉매 R134a/R123의 강제대류비등 열전달에 관한 연구 (A Study on Forced Convective Boiling Heat Transfer of Non-Azeotropic Refrigerant Mixture R134a/R123 Inside Horizontal Smooth Tube)

  • 임태우;한규일
    • 대한기계학회논문집B
    • /
    • 제27권3호
    • /
    • pp.381-388
    • /
    • 2003
  • An experimental study was carried out to measure the heat transfer coefficient in flow boiling to mixtures of HFC-l34a and HCFC-123 in a uniformly heated horizontal tube. Tests were run at a pressure of 0.6 MPa and in the ranges of heat flux 1-50 kw/$m^2$, vapor quality 0-100 % and mass velocity 150-600 kg/$m^2$s. Heat transfer coefficients of mixture were less than the interpolated values between pure fluids both in the low quality region where the nucleate boiling is dominant and in the high quality region where the convective evaporation is dominant. Measured data of heat transfer are compared to a few available correlations proposed for mixtures. The correlation of Jung et. al. satisfactorily predicted the present data, but the data in lower quality was overpredicted and underpredicted the high quality data. The correlation of Kandlikar considerably underpredicted most of the data. and showed the mean deviation of 35.1%.

루프형 히트파이프를 이용한 LED 헤드램프 열적 특성 (LED Headlamp Thermal Characteristics by Looped Heat Pipe)

  • 노형철;박경석;강병도;손성만
    • 한국정밀공학회:학술대회논문집
    • /
    • 한국정밀공학회 2006년도 춘계학술대회 논문집
    • /
    • pp.443-444
    • /
    • 2006
  • The influence of the heat sources on LED junction temperature are Engine room air, Back plate, Electric power device, and so on. LED lamp cooling system is considered to be an important subject fur high light efficiency. Because LED Chip will be problem When LED junction temperature be over $135^{\circ}C$, In this Study, The Looped Heat Pipe System is considered to prevent LED Chip fall. The LHPS is consist of evaporator part, condenser part, heat pipe part. The working fluid of LHPS is HCFC-123. In this study, to prevent LED Chipfall, we study thermal characteristics for Looped Heat Pipe System with LED lamp.

  • PDF