• 제목/요약/키워드: H2S sensing

검색결과 212건 처리시간 0.029초

Zinc phthalocyanine(ZnPc)화합물의 이용한 유기용제 센서 (Solvent Sensing Properties of Thin Films Based on Zinc phthalocyanine (ZnPc) Compounds)

  • 김동현;강영구;김정훈;노상철;김현주
    • 한국가스학회지
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    • 제9권4호
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    • pp.26-29
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    • 2005
  • 본 연구에서는 Metallophthalocyanine Macrocyclic Compounds인 Zinc phthalocyanine(ZnPc)를 이용하여 박막 films를 만들어 solvent sensor의 특성에 대한 연구을 수행하였다. 측정에 사용한 유기용제의 종류는 Acetic acid, Ethyl alcohol, Methyl alcohol, Ammonia 및 1,1,1-trichloroethane이였으며, solvent sensing 특성으로는 전기저항 변화를 측정 분석하였다. 또한 Zinc phthalocyanines과 $N,N'-diphenyl-N,N'-bis(1-naphthyl)-1,\;1-biphenyl-4,4'-diamine\;and/or\; Poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylene-vinylene]$를 blend하여 spin-coating, evaporation박막을 만들어 유기용제 농도에 따라서 전기 저항 변화를 측정 분석하였다.

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Sb-첨가 SnO2 나노선 네트워크를 이용한 고속응답 가스센서 (Fast Responding Gas Sensors Using Sb-Doped SnO2 Nanowire Networks)

  • 곽창훈;우형식;이종흔
    • 센서학회지
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    • 제22권4호
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    • pp.302-307
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    • 2013
  • The Sb-doped $SnO_2$ nanowire network sensors were prepared by thermal evaporation of the mixtures between tin and antimony powders. Pure $SnO_2$ nanowire networks showed high sensor resistance in air ($99M{\Omega}$), similar gas responses to 4 diffferent gases (5 ppm $C_2H_5OH$, CO, $H_2$, and trimethylamine), and very sluggish recovery speed (90% recovery time > 800 s). In contrast, 2 wt% Sb-doped $SnO_2$ showed the selective detection toward $C_2H_5OH$ and trimethylamine, relatively low resistance ($176k{\Omega}$) for facile measurement, and ultrafast recovery speed (90% recovery times: 6 - 18 s). The change of gas sensing charactersitics by Sb doping was discussed in relation to gas sensing mechanism.

A Fiber Optic Sensor for Determination of 2,4-Dichlorophenol Based on Oxygen Oxidation Catalyzed by Iron(III) Tetrasulfophthalocyanine

  • Tong, Yilin;Li, Dapeng;Huang, Jun;Zhang, Cong;Li, Kun;Ding, Liyun
    • Bulletin of the Korean Chemical Society
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    • 제34권11호
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    • pp.3307-3311
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    • 2013
  • A new fiber optical sensor was developed for the determination of 2,4-dichlorophenol (DCP). The sensor was based on DCP oxidation by oxygen with the catalysis of iron(III) tetrasulfophthalocyanine (Fe(III)PcTs). The optical oxygen sensing film with $Ru(bpy)_3Cl_2$ as the fluorescence indicator was used to determine the consumption of oxygen in solution. A lock-in amplifier was used for detecting the lifetime of the oxygen sensing film by measuring the phase delay change of the sensor head. The different variables affecting the sensor performance were evaluated and optimized. Under the optimal conditions (i.e. pH 6.0, $25^{\circ}C$, Fe(III)PcTs concentration of 0.62 mg/mL), the linear detection range and response time of the sensor are $1.0{\times}10^{-6}-9.0{\times}10^{-6}$ mol/L and 250 s, respectively. The sensor displays high selectivity, good repeatability and stability, and can be used as an effective tool in analyzing DCP concentration in practical samples.

SnO2 나노 분말의 합성 및 가스 감응 특성 (Gas Sensing Characteristics and Preparation of SnO2 Nano Powders)

  • 이지영;유윤식;유일
    • 한국전기전자재료학회논문지
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    • 제24권7호
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    • pp.589-593
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    • 2011
  • [ $SnO_2$ ]nano powders were prepared by solution reduction method using tin chloride($SnCl_2{\cdot}2H_2O$), hydrazine($N_2H_4$) and NaOH. The $SnO_2$ thick films for gas sensors were fabricated by screen printing method on alumina substrates and annealed at $300^{\circ}C$ in air, respectively. XRD patterns of the $SnO_2$ nano powders showed the tetragonal structure with (110) dominant orientation. The particle size of $SnO_2$ nano powders at the ratio of $SnCl_2:N_2H_4$+NaOH= 1:6 was about 60 nm. The sensing characteristics were investigated by measuring the electrical resistance of each sensor in a test box. Sensitivity of $SnO_2$ gas sensor to 5 ppm $CH_4$gas and 5 ppm $CH_3CH_2CH_3$ gas was investigated for various $SnCl_2:N_2H_4$+NaOH proportion. The highest sensitivity to $CH_4$ gas and $CH_3CH_2CH_3$ gas of $SnO_2$ sensors was observed at the $SnCl_2:N_2H_4$+NaOH= 1:8 and $SnCl_2:N_2H_4$+NaOH= 1:6, respectively. Response and recovery times of $SnO_2$ gas sensors prepared by $SnCl_2:N_2H_4$+NaOH= 1:6 was about 40 s and 30 s, respectively.

Hydrogen sensing of Nano thin film and Nanowire structured cupric oxide deposited on SWNTs substrate: A comparison

  • ;;오동훈;;정혁;김도진
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2009년도 춘계학술발표대회
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    • pp.52.1-52.1
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    • 2009
  • Cupric oxide (CuO) is a p-type semiconductor with band gap of ~1.7 eV and reported to be suitable for catalysis, lithium-copper oxide electrochemical cells, and gas sensors applications. The nanoparticles, plates and nanowires of CuO were found sensing to NO2, H2S and CO. In this work, we report about the comparison about hydrogen sensing of nano thin film and nanowires structured CuO deposited on single-walled carbon nanotubes (SWNTs). The thin film and nanowires are synthesized by deposition of Cu on different substrate followed by oxidation process. Nano thin films of CuO are deposited on thermally oxidized silicon substrate, whereas nanowires are synthesized by using a porous thin film of SWNTs as substrate. The hydrogen sensing properties of synthesized materials are investigated. The results showed that nanowires cupric oxide deposited on SWNTs showed higher sensitivity to hydrogen than those of nano thin film CuO did.

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액체누설 감지용 테이프형 필름센서 (Tape-Type Liquid Leakage Film Sensor)

  • 유동근;김경신;유홍근;한국희;김동준;김정현;한상호;조광섭
    • 한국진공학회지
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    • 제20권2호
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    • pp.146-154
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    • 2011
  • 접착테이프 형태의 액체누설 감지 필름 센서와 이를 이용하고 경보 장치를 포함한 감지 시스템을 개발하였다. 액체누설 감지 필름형 테이프 센서는 베이스 필름층, 전도성 라인층, 보호 필름층으로 구성되며, 테이프의 두께 $300{\sim}500{\mu}m$, 폭 3.55 cm, 그리고 단위 테이프의 길이는 200 m이다. 전도성 라인층의 필름에는 3개의 전도선과 1개의 저항선이 있다. 이들은 도전성 은나노 잉크를 전자인쇄방식으로 설치한다. 이들 저항선과 전도선 사이에 액체가 누설되어 전기적으로 상호 통전되면, 두 선사이의 저항변화를 전압의 변화로 계측하여 누설 위치를 감지한다. 물을 포함한 전도성 액체에 대한 누설 위치 감지에서 길이 200 m에서 오차 범위는 ${\pm}1m$ 이내이다.

이종접합 가스센서의 가스감지기구 (Gas Sensing Mechanism of CuO/ZnO Heterojunction Gas Sensor)

  • 이승환;추교섭;박정호;성영권
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 하계학술대회 논문집 C
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    • pp.1114-1116
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    • 1995
  • P/N(CuO/ZnO) Heterojunction gas sensors were made by 2-step sintering methods and its gas sensing property was measured by varying the injected gases and the operating temperatures. As the applied voltage was increased in air ambients, the current-voltage characteristics shown the ohmic properties. However, when the CO gas ambients, 500 ppm at $200^{\circ}C$, the current-voltage characteristics behaves like a rectifying diode s after 3 mins later and its conduction mechanism is discussed qualitatively for the first times.

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휴대용 기기를 위한 CMOS DC-DC 변환기 설계 (Design of a CMOS DC-to-DC Converter for Portable Devices)

  • 오남걸;이재경;조인형;장수훈;차충현;유종근
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 학술대회 논문집 정보 및 제어부문
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    • pp.520-521
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    • 2008
  • This paper describes a low voltage, low-power CMOS buck DC/DC converter, which has a simple common-gate current sensing circuit. It consumes low power because it includes less transistors than other converters which use operational amplifiers for current sensing. The designed DC-DC converter is fabricated in a 0.18um CMOS technology. A maximum efficiency of 88% has been obtained with the proposed circuit. It has $2V{\sim}3.7V$ input voltage range, $1V{\sim}2.5V$ output voltage range and maximum output current of 1000mA.

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