• Bulletin of the Korean Chemical Society
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• 제26권10호
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• pp.1525-1528
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• 2005

The synthesis and characterization of ${K_3[Ru(C_2O_4)3]{\cdot}4H_2O\;(C_2O_4}^{2-}$ = oxalato anoin) complex are described, and its redox properties (in buffer solution of pH = 12) have been investigated. This complex is used for in situ generation of oxoruthenates complexes which have been characterized by electronic spectroscopy. Reaction of ${K_3[Ru(C_2O_4)3]{\cdot}4H_2O$ with excess ${S_2O_8}^{2-}$ in molar KOH generates trans-${[RuO_3(OH)_2]^{2-}/S_2O_8}^{2-}$ reagent while with excess ${BrO_3}^-$ in molar $Na_2CO_3$ generates ${[RuO_4]^-/BrO_3}^-$ reagent. Avoiding the direct use of [$RuO_4$] the organic-soluble $(n-Pr_4N)^+[RuO_4]^-$, (TPAP) has been isolated by reaction of $K_3[Ru(C_2O_4)3]{\cdot}4H_2O$ with excess ${BrO_3}^-$ in molar carbonate and n-$Pr_4$NOH. In a mixture of $H_2O/CCl_4$ ruthenium tetraoxide can be generated by reaction of $K_3[Ru(C_2O_4)3]{\cdot}4H_2O$ with excess ${IO_4}^-$. The catalytic activities of oxoruthenates that have been made from $K_3[Ru(C_2O_4)3]{\cdot}4H_2O$ towards the oxidation of benzyl alcohol, piperonyl alcohol, benzaldehyde and benzyl amine at room temperature have been studied.

• 상하수도학회지
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• 제24권1호
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• pp.109-117
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• 2010

In the present study, the degradation characteristics of Lindane by Advanced Oxidation Processes(UV/$H_2O_2$, Photo-Fenton process) were studied. The degradation efficiency of Lindane in aqueous solution was investigated at various initial pH values, Fenton's reagent concentrations and initial concentrations of Lindane. GC-ECD was used to analyze lindane. Lindane has not been degraded without application of AOPs over two hours. But, approximately 5% of lindane was degraded with UV or $H_2O_2$ alone. Lindane with UV/$H_2O_2$ process showed approximately 7% higher removal efficiency than $H_2O_2$ process. In the UV/$H_2O_2$ process, the pH values did not affect the removal efficiency. The optimal mole ratio of $H_2O_2/Fe^{2+}$ for lindane degradation is about 1.0 in Photo-Fenton process. Also, the experimental results showed that lindane removal efficiency increased with the decrease of initial concentration of lindane. Under the same conditions, the order lindane of removal efficiency is as following : Photo-Fenton process > UV/$H_2O_2$ process > $H_2O_2$ process. In addition, intermediate products were identified by GC-MS techniques. Than PCCH(Pentachlorocyclohexene) was identified as a reaction intermediate of the Photo-Fenton process.

• Toxicological Research
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• 제18권4호
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• pp.363-367
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• 2002

Reactive of gen species (ROS) contribute to several cellular function and are involved in the regulation of signal transduction, gene expression, and proliferation. In the present study, we investigated the effect of $H_2O_2$ treatment on IgM secretion in LPS-stimulated murine B Iymphoma, CH12.LX. Cells were treated directly With $H_2O_2$ and stimulated with LPS. $H_2O_2$ treatment during 72 h time period inhibited IgM secretion in LPS-stimulated CH12.LX cells in a dose- and time-dependent manners. After treatment with 50 $\mu\textrm{M}$ $H_2O_2$ during 72 h time period, the level of IgM in LPS-stimulated CH12.LX cells was markedly decreased, whereas cell viability was not significantly changed. Addition of $H_2O_2$ concomitantly with LPS, or 12 h post-LPS stimulation, produced a significant inhibition of IgM secretion, Whereas inhibitory effect of $H_2O_2$ on IgM secretion was not observed when added 24 h after LPS stimulation. These findings suggest that $H_2O_2$ can inhibit the secretion of IgM in LPS-stimulated CH15.LX cells, and may alter the events necessary for terminal B cell differentiation.

• 상하수도학회지
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• 제10권4호
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• pp.64-72
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• 1996

The effect of $O_3$, $O_3/pH$, and $O_3/H_2O_2$, $O_3/UV$, and $H_2O_2/UV$ advanced oxidation process(AOP) were investigated for the treatment of tetrachloroethylen(PCE) at various condition. The removal efficiency of 10, 20, and 30ppm PCE by ozonation were almost same, only about 60%. And pseudo first-order rate constants, ko for overall oxidation was about 0.097($min^{-1}$). In the $O_3/pH$ AOP experiment for the 20ppm PCE, the removal rate of PCE increased with the increase of pH. However, mineralization rate of PCE at pH 7 was higher than at pH 10. In the $O_3/H_2O_2$ AOP, the removal rate of PCE was the highest at peroxide-to-ozone dosage ratio of about 0.9, which PCE was removed over 99.95%. Despite 42% of PCE was directly photolyzed by the UV irradiation, the removal efficiency of PCE by $O_3/UV$ AOP was only about 70%. In $H_2O_2/UV$ AOP, the removal efficiency of PCE increased to about 98% in proportion to the $H_2O_2$ injection concentration at constant UV intensity of 5W/l.

• 한국재료학회지
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• 제22권5호
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• pp.253-258
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• 2012

Activated magnetite ($Fe_3O_{4-{\delta}}$) was applied to reducing $CO_2$ gas emissions to avoid greenhouse effects. Wet and dry methods were developed as a $CO_2$ removal process. One of the typical dry methods is $CO_2$ decomposition using activated magnetite ($Fe_3O_{4-{\delta}}$). Generally, $Fe_3O_{4-{\delta}}$ is manufactured by reduction of $Fe_3O_4$ by $H_2$ gas. This process has an explosion risk. Therefore, a non-explosive process to make $Fe_3O_{4-{\delta}}$ was studied using $FeC_2O_4{\cdot}2H_2O$ and $N_2$. $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$ were used as starting materials. So, ${\alpha}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method. During the calcination process, $FeC_2O_4{\cdot}2H_2O$ was decomposed to $Fe_3O_4$, CO, and $CO_2$. The specific surface area of the activated magnetite varied with the calcination temperature from 15.43 $m^2/g$ to 9.32 $m^2/g$. The densities of $FeC_2O_4{\cdot}2H_2O$ and $Fe_3O_4$ were 2.28 g/$cm^3$ and 5.2 g/$cm^3$, respectively. Also, the $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by CO. From the TGA results in air of the specimen that was calcined at $450^{\circ}C$ for three hours in $N_2$ atmosphere, the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was estimated. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was 0.3170 when the sample was heat treated at $400^{\circ}C$ for 3 hours and 0.6583 when the sample was heat treated at $450^{\circ}C$ for 3 hours. $Fe_3O_{4-{\delta}}$ was oxidized to $Fe_3O_4$ when $Fe_3O_{4-{\delta}}$ was reacted with $CO_2$ because $CO_2$ is decomposed to C and $O_2$.

• 공업화학
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• 제10권6호
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• pp.885-888
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• 1999

본 연구에서는 $Na_2B_4O_7{\cdot}10H_2O/Na_2B_4O_7{\cdot}5H_2O$ 반응계의 열분해 탈수반응에 의한 반응속도상수를 결정하고 반응계의 재현성 및 화학축열재의 반복사용에 따른 내구성을 검토하였다. 반응계의 열분해 탈수반응의 차수는 1차이었고, 열분해 탈수 반응속도는 수증기의 분압차에 정비례하였다. 반응계의 반응속도상수는 약 0.27이었고, 반응속도상수와 반응차수에 대한 반응의 재현성이 우수하였다. 또한 화학축열재의 내구성은 연속적으로 반복 사용하여도 활성변화는 ${\pm}5%$ 범위 내에 있었다.

• 공업화학
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• 제8권6호
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• pp.1029-1033
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• 1997

본 연구에서는 $Na_2B_4O_7{\cdot}10H_2O$의 열분해 반응계를 이용하여 축열식 열교환기에 적용하기 위한 반응속도의 비등온 해석에 대한 기초연구를 수행하였다. $Na_2B_4O_7{\cdot}10H_2O/Na_2B_4O_7{\cdot}5H_2O$ 계에서 반응의 평형온도가 373K 이하의 저온 온도범위에서 화학축열재로 적합하였으며, 열효율이 일정하여 장시간 사용할 수 있었다. 계 내의 반응 개시온도는 가열속도 증가에 따라 저온 영역에서 고온영역으로 이동하였으며, 수증기 분압의 변화가 있어도 저하되지 않았다. 열분해 탈수반응에 의한 반응속도식의 차수는 0.67차로서 반응의 비등온 해석에 의하여 화학축열재로 사용할 수 있었다.

• 공업화학
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• 제33권4호
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• pp.419-424
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• 2022

The oxidative degradation performance of the Erionyl Navy R dye was studied in this article. The investigation mainly focused on a comparative study between chemical oxidations by sodium hypochlorite (NaClO) and hydrogen peroxide (H₂O₂), and catalytic oxidations including the Fenton (Fe²⁺-H₂O₂) and Fenton-Like (Fe²⁺/ Fe³⁺/Co²⁺/ Mn²⁺-H₂O₂) or modified Fenton-like (Fe²⁺/ Fe³⁺ -NaClO) reactions. A discoloration and degradation of the Erionyl Navy R occurred after 30 minutes, which varies according to the oxidation system involved; 31%, 54%, <20%, 95%, and >96% losses were observed for Co²⁺-H₂O₂, Mn²⁺-H₂O₂, Fe²⁺-NaClO, Fe³⁺-NaClO), and Fe²⁺-H₂O₂ and Fe³⁺-H₂O₂, respectively.

• 한국세라믹학회지
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• 제25권4호
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• pp.364-372
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• 1988

The mechanical properties and microstructure of ceramics of the system Al2O3-ZrO2-Y2O3 sintered at 1$650^{\circ}C$ for 2h after powder preparation by the precipitation method from Al2(SO4)3.18H2O, ZrOCl2.8H2O and YCl3.6H2O were investigated. The Al2O3-ZrO2-Y2O3 ceramics sintered at 1$650^{\circ}C$ for 2h after mixing alpha-Al2O3 and ZrO2-Y2O3 powders, both were separately precipitated and calcined, were found to have the relative density higher than 97.5% so that the strengthening and toughening mechanisms could be explained mainly as the stress-induced phase transformation. On the other hand, the sintered bodies prepared by co-precipitating the three starting materials were measured to have the relative density lower than 85% so that the degradation of strength were observed above 15 vol% ZrO2 contents due to the high porosity by which the effect of stress-induced phase transformation was assumed to be depressed.

• 산업진흥연구
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• 제3권2호
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• pp.1-8
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• 2018

본 연구에서는 탄화수소 개질을 위한 예비 개질기에서 에탄의 반응 메커니즘과 이에 적합한 반응속도식에 대한 연구를 수행하였다. 반응 mechanism 분석을 통해 ethane의 개질 반응 중 (CO2+H2,C2H6+H2,C2H6+H2O)3개의 반응이 진행되는 것을 확인할 수 있었으며, 각각의 반응 속도 (CO2+H2($r=3.42{\times}10-5molgcat.-1\;s-1$), C2H6+H2($r=3.18{\times}10-5mol\;gcat.-1s-1$), C2H6+H2O($r=1.84{\times}10-5mol\;gcat.-1s-1$)) 를 구하였다. 이를 통해 C2H6+H2O반응이 rate determining step (RDS)임을 확인하고, Langmuir-Hinshelwood model (L-H model)을 통해 이 반응의 반응식을 r=kS*(KAKBPC2H6PH2O)/(1+KAPC2H6+KBPH2O)2 (KA=2.052,KB=6.384,$kS=0.189{\times}10-2$)로 나타낼 수 있었다. 이렇게 얻어진 반응식은 반응 메커니즘을 고려하지 않고 유도된 power rate law와 비교하였으며, power rate law는 좁은 농도 변화 영역 (ethane 약 2.5-4%, water 약 60-75%)에서는 비교적 유사한 fitting이 이루어졌지만, 넓은 농도 변화영역에서는 반응 mechanism을 토대로 얻은 L-H model 반응식이 실험값과 더 유사한 값을 보이는 것을 확인하였다.