• Economic and Environmental Geology
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• v.33 no.5
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• pp.405-415
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• 2000

This study was carried out to understand the formation of acid mine drainage (AMD) by pyrophyllite (so-called Napseok)-rainwater interaction (weathering), dispersion patterns of heavy metals, and patterns of mixing with non-polluted water in the Tongnae pyrophyllite mine. Based on the mass balance and reaction path modeling, using both the geochemistry of water and occurrence of the secondary minerals (weathering products), the geochemical evolution of AMD was simulated by computer code of SOLVEQ and CHILLER. It shows that the pH of stream water is from 6.2 to 7.3 upstream of the Tongnae mine. Close to the mine, the pH decreases to 2. Despite being diluted with non-polluted tributaries, the acidity of mine drainage water maintains as far as downstream. The results of modeling of water-rock interaction show that the activity of hydrogen ion increases (pH decreases), the goncentration of ${HCO_3}^-$ decreases associated with increasing $H^+$ activity, as the reaction is processing. The concentration of ${SO_4}^{2-}$first increases minutely, but later increases rapidly as pH drops below 4.3. The concentrations of cations and heavy metals are controlled by the dissolution of reactants and re-dissolution of derived species (weathering products) according to the pH. The continuous adding of reactive minerals, namely the progressively larger degrees of water-rock interaction, causes the formation of secondary minerals in the following sequence; goethite, then Mn-oxides, then boehmite, then kaolinite, then Ca-nontronite, then Mgnontronite, and finally chalcedony. The results of reaction path modeling agree well with the field data, and offer useful information on the geochemical evolution of AMD. The results of reaction path modeling on the formation of AMD offer useful information for the estimation and the appraisal of pollution caused by water-rock interaction as geological environments. And also, the ones can be used as data for the choice of appropriate remediation technique for AMD.

• Journal of the Korean institute of surface engineering
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• v.54 no.4
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• pp.164-170
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• 2021

Vanadium redox flow batteries (VRFB) have emerged as large-scale energy storage systems (ESS) due to their advantages such as low cross-contamination, long life, and flexible design. However, Hydrogen evolution reaction (HER) in the negative half-cell causes a harmful influence on the performance of the VRFB by consuming current. Moreover, HER hinders V²⁺/V³⁺ redox reaction between electrode and electrolyte by forming a bubble. To address the HER problem, carbon nanotube/graphite felt electrode (CNT/GF) with oxygen functional groups was synthesized through the hydrothermal method in the H₂SO₄ + HNO₃ (3:1) mixed acid solution. These oxygen functional groups on the CNT/GF succeed in suppressing the HER and improving charge transfer for V²⁺/V³⁺ redox reaction. As a result, the oxygen functional group applied electrode exhibited a low overpotential of 0.395 V for V²⁺/V³⁺ redox reaction. Hence, this work could offer a new strategy to design and synthesize effective electrodes for HER suppression and improving the energy density of VRFB.

• Journal of Environmental Science International
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• v.25 no.4
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• pp.473-481
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• 2016

We examined the effects of ocean acidification (OA) and eutrophication on the physiology of a red alga, Gracilariopsis chorda, using specimens collected at Wando Island, Korea, in July of 2015. The samples were transported to a laboratory and placed on growth media for treatments involving low or high levels of ammonium ($4{\mu}M$ or $60{\mu}M\;NH_4{^+}$) and low or high pH(7.5 or 8.2). The control treatment used filtered seawater (pH 8.2 and $4{\mu}M\;NH_4{^+}$). All experiments were conducted at $20^{\circ}C$ and under a lighting intensity of $80{\mu}mol\;photons\;m^{-2}\;s^{-1}$, with or without an injection of $CO_2$ (pH 7.5). In addition, we calculated rates of respiration under darkness, at a pH of 7.5 and $60{\mu}M\;NH_4{^+}$. Fluctuations in pH as well as the evolution of photosynthetic oxygen and $NH_4{^+}$ uptake rates were monitored for 6 h. The greatest increase in pH levels, from 7.50 to 8.65, occurred in response to $60{\mu}M\;NH_4{^+}$, whereas the largest decrease, from 7.50 to 7.42, was associated with elevated respiration rates. At a pH of 7.5, rates of oxygen evolution were higher (236% saturation) for samples treated with $60{\mu}M\;NH_4{^+}$ than for the control (121% saturation). Ammonium uptake was highest at pH 7.5 and $60{\mu}M\;NH_4{^+}$, with a rate of $0.526{\pm}0.002{\mu}mol\;g^{-1}\;FW\;h^{-1}$, followed in order by the treatments of $pH\;8.2/60{\mu}\;NH_4{^+}$, $pH\;7.5/4{\mu}M\;NH_4{^+}$, and the control ($pH\;8.2/4{\mu}M\;NH_4{^+}$). We speculated that the rates of photosynthesis and $NH_4{^+}$ uptake could be enhanced at a higher ammonium concentration and lower pH because $CO_2$ concentrations were increased through greater photosynthetic activity. Therefore, these findings suggest that the physiology of G. chorda populations can be improved by the interaction of optimized $CO_2$ concentrations and an adequate supply of essential nutrients such as ammonium.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.2
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• pp.58.1-58.1
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• 2014

Energetic gas outflows from active galactic nuclei (AGNs) may have a crucial role in galaxy evolution. In this contribution, we present a census of ionized gas outflows using a large sample (~23,000) of local (z < 0.1) type-2 AGNs selected from the Sloan Digital Sky Survey DR 7. By measuring the velocity offset of narrow emission lines, i.e., [O III] ${\lambda}5007$ and the Balmer lines, with respect to the systemic velocity measured from the stellar absorption lines, we find ~47% of AGNs showing an [O III] line-of-sight velocity offset ${\geq}20km\;s-1$. The fraction in type-2 AGNs is similar to that in type-1 AGNs after considering the projection effect. AGNs with larger [O III] velocity offsets, in particular with no or weak $H{\alpha}$ velocity offsets, tend to have higher Eddington ratios, implying that the [O III] velocity offset is related to on-going black hole activity. Also, we find the different distributions of the host galaxy inclination between the AGNs with blueshifted [O III] and the AGNs with redshifted [O III], supporting the model of biconical outflow with dust obscuration. Meanwhile, for ~3% of AGNs, [O III] and $H{\alpha}$ exhibit comparable large velocity offsets, suggesting a more complex gas kinematics than decelerating outflows in the narrow-line region.

• Publications of The Korean Astronomical Society
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• v.32 no.1
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• pp.87-91
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• 2017

Polycyclic aromatic hydrocarbons (PAHs) are considered to be carriers of the unidentified infrared bands, which are ubiquitously observed in the Universe. PAHs are mainly formed around evolved carbon-rich stars and injected into interstellar space. Planetary nebulae (PNe), a late stage of low- and intermediate stellar mass evolution, are suitable objects to investigate the formation and evolution of PAHs. The shortest PAH feature is located in $3.3{\mu}m$, which is important to examine the excitation and size distribution of PAHs. While the number of samples had been limited before, the high sensitivity of AKARI /IRC has drastically increased the number of samples. We obtained the $2-5{\mu}m$ spectra of Galactic PNe with AKARI /IRC and compiled a near-infrared spectral catalog, containing 73 PNe. We investigate the detection rate and the evolution of the PAH features. The characteristics of the catalog are illustrated and the origin of the evolution of the PAH features is discussed.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.2
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• pp.63.1-63.1
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• 2014

The galaxy disk warp is a common phenomenon, yet their properties and formation mechanism(s) are still unclear. Here, we introduce a new automatic measurement method for the warp properties of stellar disks in nearby edge-on galaxies, including warp's angle, shape, and asymmetry. We obtain isophotal maps of edge-on galaxies and express each of isophote contours in polar coordinates (${\Phi}$, R) centered on the galaxy centers. Two peaks in the ${\Phi}$-R diagram correspond to the outermost tips of each isophote. The locations of peaks, in turn, inform us of the misalignment between their inner and outer galactic planes, i.e., the warp. We apply this method to SDSS Stripe 82 co-added data and discuss its reliability and validity. Based on the measurement of warp properties, we also investigate their correlations with both intrinsic and environmental properties of warped galaxies.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.2
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• pp.47.1-47.1
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• 2014

The calcium infrared triplet (CaT) is one of the prominent absorption features in the infrared wavelength regime. Recently, this absorption feature has been getting attention in the prediction of metallicity of stellar populations because of its strong sensitivity to the calcium abundance and metallicity of a star. However, we find that measuring metallicity directly from CaT is very dangerous because the formation mechanism of CaT is very inefficient in the cool stars which are abundant in metal-rich populations. This characteristics of CaT make the CaT-metallicity relation to converge around ~ $8{\AA}$ in the metal-rich regime. Our results suggest that, because of the converging CaT-metallicity relation in the metal-rich regime, the metallicity of simple stellar populations greater than [Fe/H]~-0.5 is unreliable when the linear conversion between CaT and metallicity is applied to derive metallicity. Based on these results, we suggest that CaT is not a good metallicity indicator for the metal-rich stellar populations.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.2 no.1
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• pp.95-110
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• 1998

Evolutionary Algorithms (EAs) are population-based optimization methods based on the principle of Darwinian natural selection. The representative methodology in EAs is genetic algorithm (GA) proposed by J. H. Holland, and the theoretical foundations of GA are the Schema Theorem and the Building Block Hypothesis. In the meaning of these foundational concepts, simple genetic algorithm (SGA) allocate more trials to the schemata whose average fitness remains above average. Although SGA does well in many applications as an optimization method, still it does not guarantee the convergence of a global optimum in GA-hard problems and deceptive problems. Therefore as an alternative scheme, there is a growing interest in a co-evolutionary system, where two populations constantly interact and co-evolve in contrast with traditional single population evolutionary algorithm. In this paper we show why the co-evolutionary algorithm works better than SGA in terms of an extended schema theorem. And predator-prey co-evolution and symbiotic co-evolution, typical approaching methods to co-evolution, are reviewed, and dynamic fitness landscape associated with co-evolution is explained. And the experimental results show a co-evolutionary algorithm works well in optimization problems even though in deceptive functions.

• Journal of The Korean Astronomical Society
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• v.38 no.2
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• pp.187-190
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• 2005

The Cosmic Evolution Survey (COSMOS) is a Hubble Space Telescope (HST) treasury project. The COSMOS aims to perform a 2 square degree imaging survey of an equatorial field in I(F814W) band, using the Advanced Camera for Surveys (ACS). Such a wide field survey, combined with ground-based photometric and spectroscopic data, is essential to understand the interplay between large scale structure, evolution and formation of galaxies and dark matter. In 2004, we have obtained high-quality, broad band images of the COSMOS field (B, V, r', i', and z') using Suprime-Cam on the Subaru Telescope, and we have started our new optical multi-band program, COSMOS-21 in 2005. Here, we present a brief summary of the current status of the COSMOS project together with contributions from the Subaru Telescope. Our future Subaru program, COSMOS-21, is also discussed briefly.

• The Bulletin of The Korean Astronomical Society
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• v.39 no.2
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• pp.69.2-69.2
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• 2014

We present space-based near-IR (NIR) and optical photometry of globular clusters (GCs) of 16 early-type galaxies in the Fornax and Virgo Clusters. The NIR imaging data for the nearby galaxies was acquired with the IR Channel of the Wide Field Camera 3 (WFC3/IR) in the F110W ($J_{110}$) and F160W ($H_{160}$) bandpasses. We introduce the full sample of our WFC3/IR program, describe data reductions and photometric measurements including GC candidate selection criteria, and then show selected GCs' color-magnitude diagrams. The tilted features in the diagrams related to the morphological types of host galaxies are discussed in the context of galaxy formation and evolution histories. Combining F475W ($g_{475}$) and F850LP ($z_{850}$) data taken from the Advanced Camera for Surveys Virgo and Fornax Cluster Surveys with our NIR data, we investigate the bimodality in optical-NIR color distribution and the nonlinear feature of the optical-NIR color relation as a function of optical color for these extragalactic GC systems.