• 제목/요약/키워드: H2 evolution

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MAGNETIC HELICITY CHANGES OF SOLAR ACTIVE REGIONS BY PHOTOSPHERIC HORIZONTAL MOTIONS

  • MOON Y.-J.;CHAE JONGCHUL;PARK Y. D.
    • Journal of The Korean Astronomical Society
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    • v.36 no.spc1
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    • pp.37-44
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    • 2003
  • In this paper, we review recent studies on the magnetic helicity changes of solar active regions by photospheric horizontal motions. Recently, Chae(200l) developed a methodology to determine the magnetic helicity change rate via photospheric horizontal motions. We have applied this methodology to four cases: (1) NOAA AR 8100 which has a series of homologous X-ray flares, (2) three active regions which have four eruptive major X-ray flares, (3) NOAA AR 9236 which has three eruptive X-class flares, and (4) NOAA AR 8668 in which a large filament was under formation. As a result, we have found several interesting results. First, the rate of magnetic helicity injection strongly depends on an active region and its evolution. Its mean rate ranges from 4 to $17 {\times} 10^{40}\;Mx^2\;h^{-1}$. Especially when the homologous flares occurred and when the filament was formed, significant rates of magnetic helicity were continuously deposited in the corona via photospheric shear flows. Second, there is a strong positive correlation between the magnetic helicity accumulated during the flaring time interval of the homologous flares in AR 8100 and the GOES X-ray flux integrated over the flaring time. This indicates that the occurrence of a series of homologous flares is physically related to the accumulation of magnetic helicity in the corona by photospheric shearing motions. Third, impulsive helicity variations took place near the flaring times of some strong flares. These impulsive variations whose time scales are less than one hour are attributed to localized velocity kernels around the polarity inversion line. Fourth, considering the filament eruption associated with an X1.8 flare started about 10 minutes before the impulsive variation of the helicity change rate, we suggest that the impulsive helicity variation is not a cause of the eruptive solar flare but its result. Finally, we discuss the physical implications on these results and our future plans.

Study of Continuous Production of Alcohol using Biologically Sandwich-styled Immobilization Carrier (샌드위치식 고분자담체를 이용한 알코올 연속생산연구)

  • Park, Young-G.;Kim, Hee-Jung
    • KSBB Journal
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    • v.23 no.3
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    • pp.213-218
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    • 2008
  • The present study was to investigate the continuous production of alcohol using immobilized carrier manufactured by polymeric materials. Fermentation runs with a crushed rice, with constituents recovered from batch culture and with ones from continuous culture were thus compared. The performances of immobilized carrier were governed by sandwitched synthetic polymers, the evolution of the continuous culture was steadily governed by the production of alcohol in the lag time of batch culture. The main focus was set on the enhancement of the alcohol production by an newly-developed polymeric forms. This polymeric form led to a drastic increase of the microorganism and the production cost in the continuous reactor was thereby reduced. The sandwitched polymeric-formed carrier, which was resistant to external environments, serves as an interesting alternative to maintain the stability of biological process. These whole results were discussed with the aim to better understand the continuous process implied in the microorganism's build-up during cultivation of fermentation broth.

Effect of Heat Treatment Environment on the Properties of Cold Sprayed Cu-15 at.%Ga Coating Material for Sputtering Target (스퍼터링 타겟용 저온 분사 Cu-15 at.%Ga 코팅 소재의 특성에 미치는 열처리 분위기의 영향)

  • Choi, Byung-Chul;Park, Dong-Yong;Kim, Hyung-Jun;Oh, Ik-Hyun;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.552-561
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    • 2011
  • This study attempted to manufacture a Cu-15 at.%Ga coating layer via the cold spray process and investigated the effect of heat treatment environment on the properties of cold sprayed coating material. Three kinds of heat treatment environments, $5%H_2$+argon, pure argon, and vacuum were used in this study. Annealing treatments were conducted at $200{\sim}800^{\circ}C$/1 hr. With the cold sprayed coating layer, pure ${\alpha}$-Cu and small amounts of $Ga_2O_3$ were detected in the XRD, EDS, EPMA analyses. Porosity significantly decreased and hardness also decreased with increasing annealing temperature. The inhomogeneous dendritic microstructure of cold sprayed coating material changed to the homogeneous and dense one (microstructural evolution) with annealing heat treatment. Oxides near the interface of particles could be reduced by heat treatment especially in vacuum and argon environments. Vacuum environment during heat treatment was suggested to be most effective one to improve the densification and purification properties of cold sprayed Cu-15 at.%Ga coating material.

Dependence of Halo Properties on Galactic Potentials

  • Kim, Youngkwang;Lee, Young Sun;Beers, Timothy C.
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.2
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    • pp.51.1-51.1
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    • 2017
  • We present the dependence of halo properties on two different Galactic potentials: the $St{\ddot{a}}ckel$ potential and the Milky Way-like potential known as "Galpy". Making use of the Sloan Digital Sky Survey Data Release 12 (SDSS DR12), we find that the shape of the metallicity distribution and rotation velocity distribution abruptly changes at 15 kpc of $Z_{max}$ (the maximum distance of stellar orbit above or below the Galactic plane) and 32 kpc of $r_{max}$ (the maximum distance of an orbit from the Galactic center) in the $St{\ddot{a}}ckel$, which indicates that the transition from the inner to outer halo occurs at those distances. When adopting the $St{\ddot{a}}ckel$ potential, stars with $Z_{max}$ > 15 kpc show a retrograde motion of $V_{\phi}=-60km\;s^{-1}$, while stars with $r_{max}$ > 32 kpc show $V_{\phi}=-150km\;s^{-1}$. If we impose $V_{\phi}$ < $-150km\;s^{-1}$ to the stars with $Z_{max}$> 15 kpc or $r_{max}$> 32, we obtain the peak of the metallicity distribution at [Fe/H] = -1.9 and -1.7 respectively. However, there is the transition of the metallicity distribution at $Z_{max}=25kpc$, whereas there is no noticeable retrograde motion in the Galpy. The reason for this is that stars with high retrograde motion in the $St{\ddot{a}}ckel$ potential are unbound and stars with low rotation velocity reach to larger region of $Z_{max}$ and $r_{max}$ due to shallower potential in the Galpy. These results prove that as the adopted Galactic potential can affect the interpretation of the halo properties, it is required to have a more realistic Galactic potential for the thorough understanding of the dichotomy of the Galactic halo.

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Cell Age Optimization for Hydrogen Production Induced by Sulfur Deprivation Using a Green Alga Chlamydomonas reinhardtii UTEX 90

  • KIM , JUN-PYO;KANG, CHANG-DUK;SIM, SANG-JUN;KIM, MI-SUN;PARK, TAI-HYUN;LEE, DONG-HYUN;KIM, DUK-JOON;KIM, JI-HEUNG;LEE, YOUNG-KWAN;PAK, DAE-WON
    • Journal of Microbiology and Biotechnology
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    • v.15 no.1
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    • pp.131-135
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    • 2005
  • Under sulfur deprived conditions, PS II and photosynthetic $O_2$ evolution by Chlamydomonas reinhardtii UTEX 90 are inactivated, resulting in shift from aerobic to anaerobic condition. This is followed by hydrogen production catalyzed by hydrogenase. We hypothesized that the photosynthetic capacity and the accumulation of endogenous substrates such as starch for hydrogen production might be different according to cell age. Accordingly, we investigated (a) the relationships between hydrogen production, induction time of sulfur deprivation, increase of chlorophyll after sulfur deprivation, and residual PS II activity, and (b) the effect of initial cell density upon sulfur deprivation. The maximum production volume of hydrogen was 151 ml $H_2$/l with 0.91 g/l of cell density in the late-exponential phase. We suggest that the effects of induction time and initial cell density at sulfur deprivation on hydrogen production, up to an optimal concentration, are due to an increase of chlorophyll under sulfur deprivation.

The first photometric analysis of the close binary system NSVS 1461538

  • Kim, Hyoun-Woo;Kim, Chun-Hwey
    • The Bulletin of The Korean Astronomical Society
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    • v.41 no.1
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    • pp.41.2-41.2
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    • 2016
  • The follow-up BVRI photometric observations of NSVS 1461538, which was discovered as an $Algol/{\beta}$ Lyr eclipsing variable by Hoffman, Harrison & McNamara (2009), were performed for three years from 2011 to 2013 by using the 61-cm telescope and CCD cameras of Sobaeksan Optical Astronomy Observatory (SOAO). New light curves have deep depths both of the primary and secondary eclipses, rounded shapes outside eclipses and a strong O'Connell effect, indicating that NSVS 1461538 is a typical W UMa close binary system rather than an $Algol/{\beta}$ Lyr type binary star. A period study with all the timings shows that the orbital period may vary in a sinusoidal way with a period of about 5.6 yr and a small semi-amplitude of about 0.008 d. The cyclical period variation was interpreted as a light-time effect due to a tertiary body with a minimum mass of $0.66M{\odot}$. The first photometric solution with the Wilson-Devinney binary model shows that the system is a W-subtype contact binary with the mass ratio ($q=m_c/m_h$) of 3.46, orbit inclination of 85.6 deg and fill-out factor of 30%. From the existing empirical relationship between parameters, the absolute dimension was estimated. The masses and radii of the component stars are $0.28M{\odot}$ and $0.71R{\odot}$ for the less massive but hotter primary star, respectively, and $0.96M{\odot}$ and $1.21R{\odot}$ for the more massive secondary, respectively. Possible evolution of the system is discussed in the mass-radius and the mass-luminosity planes.

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Probing the Conditions for the Atomic-to-Molecular Transition in the Interstellar Medium

  • Park, Gyueun;Lee, Min-Young
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.50.2-51
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    • 2021
  • Stars form exclusively in cold and dense molecular clouds. To fully understand star formation processes, it is hence a key to investigate how molecular clouds form out of the surrounding diffuse atomic gas. With an aim of shedding light in the process of the atomic-to-molecular transition in the interstellar medium, we analyze Arecibo HI emission and absorption spectral pairs along with TRAO/PMO 12CO(1-0) emission spectra toward 58 lines of sight probing in and around molecular clouds in the solar neighborhood, i.e., Perseus, Taurus, and California. 12CO(1-0) is detected from 19 out of 58 lines of sight, and we report the physical properties of HI (e.g., central velocity, spin temperature, and column density) in the vicinity of CO. Our preliminary results show that the velocity difference between the cold HI (Cold Neutral Medium or CNM) and CO (median ~ 0.7 km/s) is on average more than a factor of two smaller than the velocity difference between the warm HI (Warm Neutral Medium or WNM) and CO (median ~ 1.7 km/s). In addition, we find that the CNM tends to become colder (median spin temperature ~ 43 K) and abundant (median CNM fraction ~ 0.55) as it gets closer to CO. These results hints at the evolution of the CNM in the vicinity of CO, implying a close association between the CNM and molecular gas. Finally, in order to examine the role of HI in the formation of molecular gas, we compare the observed CNM properties to the theoretical model by Bialy & Sternberg (2016), where the HI column density for the HI-to-H2 transition point is predicted as a function of density, metallicity, and UV radiation field. Our comparison shows that while the model reproduces the observations reasonably well on average, the observed CNM components with high column densities are much denser than the model prediction. Several sources of this discrepancy, e.g., missing physical and chemical ingredients in the model such as the multi-phase ISM, non-equilibrium chemistry, and turbulence, will be discussed.

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A Study on the Evolution of 3,4-DCA and TCAB in Some Selected Soils(Part II) -Degradation of $^{14}C-3,4-DCA\;and\;^{14}C-TCAB$- (수종토양중(數種土壤中)에서 3,4-DCA 및 TCAB의 변화(變化)에 관(關)한 연구(硏究)(제2보(劑二報)) -$^{14}C-3,4-DCA$$^{14}C-TCAB$ 의 분해(分解)-)

  • Lee, Jae-Koo;Fournier, J.C.
    • Applied Biological Chemistry
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    • v.21 no.2
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    • pp.71-80
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    • 1978
  • In an attempt to elucidate the fate of 3,4-DCA and TCAB in various French soils, uniformly $^{14}C-ring-labeled$ 3,4-DCA and TCAB mere utilized and the following results obtained. 1) The rate of breakdown of $^{14}C-3,4-DCA$ into $^{14}CO_2$ was relatively higher in the early stage than that in the later stage. In 6 months of incubation in alkaline soil (pH 7.9), the rate was as high as 6.5% at dose 1 (1.5 ppm) and as low as 1.92% at dose 2(94 ppm), whereas in organic acid soil (pH 5.5) the rate was 4.91% at dose 1 and 4.24% at dose 2, respectively, without making any great difference between the two levels. 2) At dose 1, 47.70% of the initial radioactivity of $^{14}C-3,4-DCA$ was bound to soil in organic acid soil and 29.49% bound in alkaline soil, whereas at dose 2, 38.40% in organic acid soil and 20.30% in alkaline soil, respectively. 3) The amount of formation of $^{14}C-TCAB$ from $^{14}C-3,4-DCA$ seems to depend largely on the concentration of 3,4-DCA applied rather than on soil types. At dose 2, the amount was 50% of the total radioactivity extracted in organic acid soil and 30% in alkaline soil, corresponding to 1.8% and 1.4% of the initial radioactivity applied to soil, respectively. Cis-TCAB also seemed to be formed at dose 2 in both soils. Meanwhile, at dose 1, even though $^{14}C-TCAB$ was detected in trace on tlc and glc in both soils, the amount does not exceed 2 to 3% of the radioactivity extracted, corresponding to 0.05 to 0.1% of the initial radioactivity. 4) The rate of breakdown of $^{14}C-TCAB$ into $^{14}CO_2$ ranged from 0.05 to 0.20% in all the four soils. Most of the applied $^{14}C-TCAB$ remained intact after 3 months, not producing any detectable metabolites. 5) The fact that much more $^{14}C-TCAB$ was adsorbed to alkaline soil than to the other soils strongly indicates that in alkaline condition trans-isomer was converted tocisisomer which has the higher adsorption affinity than the former.

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Determination of Adsorption Isotherms of Hydrogen at an Ir Electrode Interface Using the Phase-Shift Method and Correlation Constants (Ir 전극 계면에서 위상이동 방법 및 상관계수를 이용한 수소의 흡착동온식 결정)

  • Jeon, Sang-K.
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.132-140
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    • 2007
  • The phase-shift method and correlation constants for studying a linear relationship between the behavior ($-{\varphi}\;vs.\;E$) of the phase shift ($0^{\circ}{\leq}-{\varphi}{\leq}90^{\circ}$) for the optimum intermediate frequency and that (${\theta}\;vs.\;E$) of the fractional surface coverage ($1{\geq}\theta{\geq}0$) have been proposed and verified to determine the Langmuir, Frumkin, and Temkin adsorption isotherms (${\theta}\;vs.\;E$) at noble metal/aqueous electrolyte interfaces. At an Ir/0.1 M KOH aqueous electrolyte interface, the Langmuir and Temkin adsorption isotherms (${\theta}\;vs.\;E$), equilibrium constants ($K=3.3{\times}10^{-4}\;mol^{-1}$ for the Langmuir and $K=3.3{\times}10^{-3}{\exp}(-4.6{\theta})\;mol^{-1}$ for the Temkin adsorption isotherm), interaction parameter (g = 4.6 for the Temkin adsorption isotherm), and standard free energies (${\Delta}G_{ads}^0=19.9kJ\;mol^{-1}\;for\;K=3.3{\times}10^{-4}\;mol^{-1}$ and $16.5<{\Delta}G_{\theta}^0<23.3\;kJ\;mol^{-1}\;for\;K=3.3{\times}10^{-3}{\exp}(-4.6{\theta})\;mol^{-1}\;and\;0.2<\theta<0.8$) of H for the cathodic $H_2$ evolution reaction are determined using the phase-shift method and correlation constants. The inhomogeneous and lateral interaction effects on the adsorption of H are negligible. At the intermediate values of ${\theta},\;i.e,\;0.2<{\theta}<0.8$, the Temkin adsorption isotherm (${\theta}\;vs.\;E$) correlating with the Langmuir or the Frumkin adsorption isotherm (${\theta}\;vs.\;E$), and vice versa, is readily determined using the correlation constants. The phase-shift method and correlation constants are accurate and reliable techniques to determine the adsorption isotherms (${\theta}\;vs.\;E$) and related electrode kinetic and thermodynamic parameters(K, g, ${\Delta}G_{ads}^0, {\Delta}G_{\theta}^0$).

Studies on the Quick Ripening Process for Soysauce (속양(速釀)간장 제조(製造)에 관(關)한 연구(硏究))

  • Kim, Z.U.;Cho, M.J.
    • Applied Biological Chemistry
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    • v.14 no.1
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    • pp.19-27
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    • 1971
  • This experiment was conducted as a preliminary test to invent the quick ripening process for soysauces. The bran koji extract of 2 kinds of mold (Asp. niger and Asp. sojae) was used as enzyme sources in order to improve the rate of enzymatic conversion of raw materials and shorten the ripening period of soysauces. Soybean koji (inoculated Asp. sojae) and steamed soybean were enzymatically decomposed for 8 hours at $40^{\circ}C$, pH 4-6 with stirring at a rate of 1500 rpm. After the enzymatic treatment, soysauces were fermented by 4 kinds of processes with the above-mentioned salt tolerant microorganisms inoculated. After 4 weeks, sensory evolution for these soysauces products and analysis of chemical components were carried out. The results obtained were summarized as follows. 1. Soysauces prepared from decomposed koji by Asp. niger enzyme complex showed higher extractables, such as total nitrogen, amino nitrogen, pure extract and reducing sugar, than any other procedure. Extracted amounts of each components of soysauces prepared from this process during 1 month were similar to those of soysauces made from general procedure (control) for 5 to 6 months. 2. According to sensory evaluation, soysauce prepared from decomposed koji also showed best taste and were similar to that of soysauces prepared by general method for 6 months.

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