• 한국분무공학회지
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• 제2권4호
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• pp.47-53
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• 1997

By using a premixed laminar burner, the effect of mixture component on laminar burning velocity($S_L$) was investigated. The following was made clear ; (1)As the humidity$(H_2O)$, $CO_2$ and Ar in mixture is increased, $S_L$ decreased in proportion to quantity of those dilution gases. (2) The heat reaction theory says that mean thermal conductivity $(\lambda_m)$, specific heat $(C_{pm})$ of mixture and adiabatic flame temperatures $(T_b)$ affect $S_L$. As a result of theoretical analysis, the effect of $\lambda_m\;and\;C_{pm}$ on $S_L$ is less than 1/25 of the effect of $T_b$, so the effect of $\lambda_m\;and\;C_{pm}$ can be ignored. (3) From experimental results, it was confirmed that $\ln(S_L)$ is proportional to $(1/T_b)$, that is, the effect of $H_2O$ on $S_L$ is mainly caused by changes of $T_b$. This conclusion was verified by the fact increases of $H_2O,\;CO_2$ and Ar decrease the intensity of radiation typical $C_2$, CH, and OH in the same manner.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 2006년도 에너지.가스.기후변화학회 연합춘계학술대회 및 특별심포지움
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• pp.412-419
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• 2006

지구온난화의 주원인인 이산화탄소 배출 규제에 대응하기 위한 온실가스 감축 기술개발의 노력이 전 세계적으로 진행되고 있다. 따라서 본 연구에서는 배기가스 중에 $CO_{2}$를 고효율 저비용으로 회수할 수 있는 회수처리기술의 일환으로 효율성과 경제성에 맞추어, 산화제로 공기대신 순산소를 사용하는 $CO_{2}$ 재순환 산소연소 가열로시스템에 관한 실험을 수행하였다. 가재 가열용 연소로 시뮬레이터 및 화염 가변형 버너를 이용하여 $CO_{2}$ 재순환에 따른 로내 온도특성, 압력변화 그리고 배기가스특성을 비교 파악하였다. 실험결과, 배기가스의 대부분은 $CO_{2}$와 $H_{2}O$로 구성되었고, 반복재순환시 배기가스 중의 $H_{2}O$를 응축 분리시켜 고농도($90{\sim}95%$)의 $CO_{2}$를 얻을 수 있었다. 또한 온도를 제어할 수 있는 가능성을 보였고 NOx 배출도 100PPM 이하로 감소시킬 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제27권9호
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• pp.1293-1296
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• 2006

In this study, a solid phase extraction method has been developed for the preconcentration and separation of the elements Cr(III), Fe(III), Co(II) and Pb(II) at trace levels by using a column packed with Amberlite XAD-1180 resin loaded with 4-(2-pyridylazo)-resorcinol (PAR) reagent. After preconcentrating, the metals retained on the column were eluted with 20 mL of 3 mol/L $HNO_3$ and then determined by flame atomic absorption spectrometry (FAAS). The factors affecting the recovery of the elements, such as pH, type and concentration of eluent, volume of sample and elution solution, and matrix components, were also ascertained. The recoveries of Cr(III), Fe(III), Co(II) and Pb(II) were found to be $99\;{\pm}\;4,\;97\;{\pm}\;3,\;95\;{\pm}\;3$ and $98\;{\pm}\;4$%, respectively, under the optimum conditions at 95% confidence level and the relative standard deviations found by analyzing of nine replicates were $\leq4.4$%. The preconcentration factors for Cr(III), Fe(III), Co(II) and Pb(II) were found as 75, 125, 50 and 75 respectively. The detection limits (DL, 3s/b) were 3.0 $\mu g/L$ for Cr(III), 1.25 $\mu g/L$ for Fe(III), 3.3 $\mu g/L$ for Co(II), and 7.2 $\mu g/L$ for Pb(II). The recoveries achieved by adding of metals at known concentrations to samples and the analysis results of Buffalo river sediment (RM 8704) show that the described method has a good accuracy. The proposed method was applied to tap water, stream water, salt and street dust samples.

• International Journal of Automotive Technology
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• 제6권4호
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• pp.323-332
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• 2005

A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at the spark electrode gap and the combustion characteristics of a homogeneous charged methane-air mixture under various overall charge pressures, excess air ratios and ignition times. The flow characteristics, including the mean velocity and turbulence intensity, were analyzed with a hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer, a flame propagation image acquired by ICCD camera and exhaust emissions measured by 2-valve gas chromatography were used to investigate effects of initial pressures, excess air ratios and ignition times on the combustion characteristics. It was found that the mean velocity and turbulence intensity had the maximum value around 200-300 ms and then decreased gradually to a near-zero value after 3000 ms and that the combustion duration was shorten and the flame speed and laminar burning velocity had the highest value under the condition of an excess air ratio of 1.1, an overall charge pressure of 0.15 MPa and an ignition time of 300 ms in the present study. The $CO_2$ concentration was proportional to the ignition time and overall charge pressure, the $CO_2$ concentration was proportional to the excess air ratio, and the UHC concentration was inversely proportional to the ignition time and overall charge pressure.

• 청정기술
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• 제13권4호
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• pp.300-307
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• 2007

본 연구에서는 연료분출각의 변화에 따라 보염기(cylindrical stabilizer) 후류에 형성되는 확산화염의 화염 안정성, 재순환영역의 길이 및 온도, 보염기 후류의 난류강도 분포, 재순환영역의 연소가스 농도 등을 측정하고, 화염의 직접사진 및 슐리렌사진을 촬영하여 확산화염의 연소특성을 고찰하였다. 화염안정성은 연료분출각과 주류공기 유속의 영향을 받으며, 재순환영역의 길이와 온도는 연료분출각의 영향을 받았다. 재순환영역의 길이가 짧고 온도가 낮을수록 화염안정성이 양호하지만, 연료분출각의 변화에 따른 난류강도 분포에는 별로 차이가 없었다. 재순환영역 내 미연가스 농도가 높고 이산화탄소 농도가 낮은 경우, 화염안정성은 양호하지만 연소상태는 불량한 것으로 나타났다. 연소효율, 고부하 출력, 대기환경, 연료의 청정연소조건 등을 고려하여 적절한 연료분출각을 선정함으로써 양호한 연소조건을 유지할 수 있다.

• 대한기계학회논문집B
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• 제25권11호
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• pp.1594-1605
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• 2001

In this study, a numerical simulation was developed which was capable of predicting the characteristics of NO formation in pilot scale combustor adopting the air-staged burner flame. The numerical calculation was constructed by means of establishing the mathematical models fur turbulence, turbulent combustion, radiation and turbulent nitric oxide chemistry. Turbulence was solved with standard k-$\xi$ model and the turbulent combustion model was incorporated using a two step reaction scheme together with an eddy dissipation model. The radiative transfer equation was calculated by means of the discrete ordinates method with the weighted sum of gray gases model for CO$_2$and H$_2$O. In the NO chemistry model, the chemical reaction rates for thermal and prompt NO were statistically averaged using the $\beta$ probability density function. The results were validated by comparison with measurements. For the experiment, a 0.2 MW pilot multi-air staged burner has been designed and fabricated. Only when the radiation was taken into account, the predicted gas temperature was in good agreement with the experimental one, which meant that the inclusion of radiation was indispensable for modeling multi-air staged gas flame. This was also true of the prediction of the NO formation, since it heavily depended on temperature. Subsequently, it was found that the multi-air staged combustion technique might be used as a practical tool in reducing the NO formation by controlling the peak flame temperature.

• 한국해양학회지
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• 제15권1호
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• pp.66-70
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• 1980

A method for the determination of dissolved species of Cd, Co, Cu, Ni, Pb and Zn in sea water by flame atomic absorption spectrophotometry (AAS) is described. Prior to analysis by AAS, these elements are concentrated by coprecipitation with iron pyrrolidinedithiocarbamate at pH 3 because of matrix effects and their low concentration levels in sea water. The detection limits are 0.01, 0.04, 0.02, 0.05, 0.08, and 0.03$\mu\textrm{g}$/l, and the relative standard deviations are 1.0, 2.4, 1.3, 2.9, 2.0 and 2.9% for Cd, Co, Cu, Ni, Pb and Zn, respectively. The method is shown to be satisfactory in terms of recovery and precision for the determination of these metals in sea water.

• 한국세라믹학회지
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• 제25권5호
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• pp.495-501
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• 1988

Verneuil method uses oxyhydrogen flame for its heat source. This method was used to grow corundum monocrystals. Parametersof this method are feeding rate, gas pressure, lowering rate and growth axis. These parameters were examined. Crystals's qualities and shapes are affected by these parameters. Crystals having good qualities and shape were grown under the conditions that feeding rate, 0.2∼0.5g/min, lowering rate, 10∼20mm/hr ; gas pressure, 3∼4psi ; growth axis was shifted 60 degrees from c axis.

• 한국수소및신에너지학회논문집
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• 제17권4호
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• pp.362-370
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• 2006

The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the plasmatron assisted $CH_4$ reforming reaction for the hydrogen-rich gas production. Also, in order to increase the hydrogen production and the methane conversion rate, parametric screening studies were conducted, in which there were the variations of the $CH_4$ flow ratio, $CO_2$ flow ratio, vapor flow ratio, mixing flow ratio and catalyst addition in reactor. High temperature plasma flame was generated by air and arc discharge. The air flow rate and input electric power were fixed 5.1 l/min and 6.4 kW, respectively. When the $CH_4$ flow ratio was 38.5%, the production of hydrogen was maximized and optimal methane conversion rate was 99.2%. Under these optimal conditions, the following synthesis gas concentrations were determined: $H_2$, 45.4%; CO, 6.9%; $CO_2$, 1.5%; and $C_2H_2$, 1.1%. The $H_2/CO$ ratio was 6.6, hydrogen yield was 78.8% and energy conversion rate was 63.6%.

• 한국자동차공학회논문집
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• 제10권4호
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• pp.51-59
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• 2002

In this study, cycle simulation was performed to investigate the effect of EGR on combustion characteristics and emissions including NO and soot using a two-zone model in a DI diesel engine. The NO formation was well predicted for different EGR rate and temperature using a two-zone model. The oxygen in the inlet charge was replaced by CO$_2$ and H$_2$O with EGR. The reduction in the inlet charge oxygen resulted in very large reduction in NO level at the same inlet charge temperature. The effect of EGR was to reduce the burned gas temperature. When EGR was increased from 0% to 15%, the peak flame temperature was decreased by 50$\^{C}$ and it caused about 57% NO reduction. EGR caused increase of the overall inlet charge temperature which offset some of benefit of lower flame temperature resulting from O$_2$ displacement. Cooling the EGR was confirmed to provide additional benefits by lowering NO emission. It also reduced soot emission.