• Title/Summary/Keyword: H143

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Photodissociation of C3H5Br and C4H7Br at 234 nm

  • Kim, Hyun-Kook;Paul, Dababrata;Hong, Ki-Ryong;Cho, Ha-Na;Lee, Kyoung-Seok;Kim, Tae-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.143-148
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    • 2012
  • The photodissociation dynamics of cyclopropyl bromide ($C_3H_5Br$) and cyclobutyl bromide ($C_4H_7Br$) at 234 nm was investigated. A two-dimensional photofragment ion-imaging technique coupled with a [2+1] resonanceenhanced multiphoton ionization scheme was utilized to obtain speed and angular distributions of the nascent $Br(^2P_{3/2})$ and $Br^*(^2P_{1/2})$ atoms. The recoil anisotropies for the Br and $Br^*$ channels were measured to be ${\beta}_{Br}=0.92{\pm}0.03$ and ${\beta}_{Br^*}=1.52{\pm}0.04$ for $C_3H_5Br$ and ${\beta}_{Br}=1.10{\pm}0.03$ and ${\beta}_{Br^*}=1.49{\pm}0.05$ for $C_4H_7Br$. The relative quantum yield for Br was found to be ${\Phi}_{Br}=0.13{\pm}0.03$ and for $C_3H_5Br$ and $C_4H_7Br$, respectively. The soft radical limit of the impulsive model adequately modeled the related energy partitioning. The nonadiabatic transition probability from the 3A' and 4A' potential energy surfaces was estimated and discussed.

Transcriptional activation of human GM3 synthase (hST3Gal V) gene by valproic acid in ARPE-19 human retinal pigment epithelial cells

  • Song, Na-Ree;Kim, Seok-Jo;Kwon, Haw-Young;Son, Sung-Wook;Kim, Kyoung-Sook;Ahn, Hee-Bae;Lee, Young-Choon
    • BMB Reports
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    • v.44 no.6
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    • pp.405-409
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    • 2011
  • The present study demonstrated that valproic acid (VPA) transcriptionally regulates human GM3 synthase (hST3Gal V), which catalyzes ganglioside GM3 biosynthesis in ARPE-19 human retinal pigment epithelial cells. For this, we characterized the promoter region of the hST3Gal V gene. Functional analysis of the 5'-flanking region of the hST3Gal V gene revealed that the -177 to -83 region functions as the VPA-inducible promoter and that the CREB/ATF binding site at -143 is crucial for VPA-induced expression of hST3Gal V in ARPE-19 cells. In addition, the transcriptional activity of hST3Gal V induced by VPA in ARPE-19 cells was inhibited by SP600125, a c-Jun N-terminal kinase (JNK) inhibitor. In summary, our results identified the core promoter region in the hST3Gal V promoter and for the first time demonstrated that ATF2 binding to the CREB/ATF binding site at -143 is essential for transcriptional activation of hST3Gal V in VPA-induced ARPE-19 cells.

Antioxidative and Nitrite Scavenging Activities of Polygonatum odoratum Root Extracts with Different Steaming and Roasting Conditions (둥굴레 근경의 증자 및 볶음조건에 따른 추출물의 항산화성 및 아질산염 소거능 변화)

  • Kim Kyung-Tae;Kim Jung-Ok;Lee Gee-Dong;Kwon Joong-Ho
    • Food Science and Preservation
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    • v.12 no.2
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    • pp.166-172
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    • 2005
  • Response surface methodology (RSM) was applied to monitor the effects of steaming and roasting conditions of Polygonatum odoratum roots an total phenolics content, electron donating ability (EDA) and nitrite-scavenging ability (NSA) of the extract. In steaming and roasting processes based on the central composite design. with variations in steaming time $(60\~180\;min)$, roasting temperature $(110\~150\;min)$ and roasting time $(10\~50\;min)$, coefficients of determinations $(R^2)$ were 0.9356 (p<0.01) in total phenolics, 0.9578 (p<0.01) in EDA and 0.9436 (p<0.01) in NSA (pH 3.0). The maximum value of total phenolics was $2847.67\;mg\%$ at 135.59 min of steaming time, $143.84^{\circ}C$ of roasting temperature and 43.47 min of roasting time. The maximum value of EDA was $75.00\%$ in 108.98 min, $135.56^{\circ}C$ and 48.86 min. The maximum value of NSA (pH 3.0) was $87.38\%$ in 162.80 min, $143.88^{\circ}C$ and 31.97 min, respectively. Total phenolics content of the extract was influenced by heating conditions in the order of roasting temperature, steaming time and roasting time. While EDA and NSA were appreciably influenced by roasting time, followed by roasting temperature and steaming time.

Electrophotographic properties of $\tau$-H$_2$Pc/oxadiazole photoreceptor (I) ($\tau$-H$_2$PC/oxadiazole 유기이층막의 감광특성 연구 (I))

  • 이덕출;박구범;조기선;오승현
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1993.11a
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    • pp.141-143
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    • 1993
  • A nontoxic organic photoreceptor for near infrared light has been developed. A double layered photoreceptor using $\tau$-H$_2$Pc as the CGL was made. The CTL was formed by oxadiazole derivative dispersed in two other host polymers. This photoreceptor has a charge acceptance of -900 V when a corona charge is used, and has residual potentials of -20 V for PC, and -10 V for PVB by light irradiation.

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Wireless Internet Standardization Platform WIPI 2.0 (무선 인터넷 표준 플랫폼 WIPI 2.0의 표준화 동향)

  • Lee, S.Y.;Lee, H.K.;Kim, W.S.;Lee, J.H.;Kim, S.J.;Kim, H.N.
    • Electronics and Telecommunications Trends
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    • v.19 no.5 s.89
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    • pp.143-149
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    • 2004
  • WIPI는 한국 무선인터넷 표준화 포럼에서 개발한 표준 모바일 플랫폼이다. 본 고에서는 WIPI의 탄생 배경과 WIPI 플랫폼의 특징들을 기술한다. 또한 WIPI의 표준화 범위와 표준화 항목들을 기술하고 WIPI 2.0에서 새롭게 추가되는 기능 및 표준화 항목들을 정리한 후 향후 WIPI가 나아가야 할 방향을 제시한다.

Functional Properties of Maillard Conjugates Made from Whey Protein Isolate and Inulin (분리유청단백질-이눌린 유래 마이야르 공액체의 기능적 특성 연구)

  • Kim, Yeon-Woo;Lee, Se-Hee;Lee, Won-Jae
    • Journal of Dairy Science and Biotechnology
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    • v.40 no.4
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    • pp.143-150
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    • 2022
  • Maillard conjugates are formed by covalent bonds between proteins and polysaccharides. Understanding the functional properties of Maillard conjugates, including emulsifying and antioxidant properties, can be crucial when Maillard conjugates are used in processed foods. This study aimed to manufacture whey protein isolate (WPI)/Inulin Maillard conjugates and investigate how manufacturing variables including heating temperature and pH affect the functional properties of Maillard conjugates. The surface properties, emulsifying properties, and antioxidant properties of Maillard conjugates were assessed by varying heating temperature and pH. The grafting degree of WPI/Inulin Maillard conjugates increased with increasing pH and heating temperature, indicating enhanced conjugation efficiency. Surface hydrophobicity, emulsifying properties (including emulsifying activity index and emulsifying stability index), and ABTS radical scavenging ability of WPI/Inulin Maillard conjugates increased as pH and heating temperature were increased. In conclusion, WPI/Inulin Maillard conjugates were successfully manufactured, and pH and heating temperature were critical factors in enhancing Maillard conjugate functional properties.

Biocontrol Activity of Volatile-Producing Bacillus megaterium and Pseudomonas protegens Against Aspergillus and Penicillium spp. Predominant in Stored Rice Grains: Study II

  • Mannaa, Mohamed;Kim, Ki Deok
    • Mycobiology
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    • v.46 no.1
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    • pp.52-63
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    • 2018
  • In our previous studies, Bacillus megaterium KU143, Microbacterium testaceum KU313, and Pseudomonas protegens AS15 have been shown to be antagonistic to Aspergillus flavus in stored rice grains. In this study, the biocontrol activities of these strains were evaluated against Aspergillus candidus, Aspergillus fumigatus, Penicillium fellutanum, and Penicillium islandicum, which are predominant in stored rice grains. In vitro and in vivo antifungal activities of the bacterial strains were evaluated against the fungi on media and rice grains, respectively. The antifungal activities of the volatiles produced by the strains against fungal development and population were also tested using I-plates. In in vitro tests, the strains produced secondary metabolites capable of reducing conidial germination, germ-tube elongation, and mycelial growth of all the tested fungi. In in vivo tests, the strains significantly inhibited the fungal growth in rice grains. Additionally, in I-plate tests, strains KU143 and AS15 produced volatiles that significantly inhibited not only mycelial growth, sporulation, and conidial germination of the fungi on media but also fungal populations on rice grains. GC-MS analysis of the volatiles by strains KU143 and AS15 identified 12 and 17 compounds, respectively. Among these, the antifungal compound, 5-methyl-2-phenyl-1H-indole, was produced by strain KU143 and the antimicrobial compounds, 2-butyl 1-octanal, dimethyl disulfide, 2-isopropyl-5-methyl-1-heptanol, and 4-trifluoroacetoxyhexadecane, were produced by strain AS15. These results suggest that the tested strains producing extracellular metabolites and/or volatiles may have a broad spectrum of antifungal activities against the grain fungi. In particular, B. megaterium KU143 and P. protegens AS15 may be potential biocontrol agents against Aspergillus and Penicillium spp. during rice grain storage.

Measurement of Spatial Dose Distribution for evaluation operator dose during Neuro-interventional Procedures (두경부 질환의 인터벤션 시술 시 시술자의 피폭선량평가를 위한 공간선량측정에 관한 연구)

  • Han, Su-Chul;Hong, Dong-Hee
    • Journal of radiological science and technology
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    • v.39 no.3
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    • pp.323-328
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    • 2016
  • The spatial dose distribution was measured with ionization chamber as preliminary study to evaluate operator dose and to study dose reduction during neuro-interventional procedures. The zone of operators was divided into four area (45, 135, 225, and 315 degree).We supposed that operator exist on the four area and indicated location of critical organs(eyes, breast, gonad). The spatial doses were measured depending on distance( 80, 100, 120, and 140 cm) and location of critical organs. The spatial doses of area of 225 degree were 114.5 mR/h (eyes location), 143.1 mR/h (breast location) and 147 mR/h (gonad location) in 80 cm. When changed location of x-ray generator, spatial dose increased in $18.1{\pm}10.5%$, averagely. We certified spatial dose in the operator locations, Using the results of this study, It is feasible to protect operator from radiation in neuro-interventional procedures.

Comparison of Elderly Male's Bodice Pattern -focused on 70's and 80's

  • Cha, Su-Joung
    • Journal of the Korea Society of Computer and Information
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    • v.25 no.6
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    • pp.143-154
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    • 2020
  • In this study, four types of bodice patterns of elderly males in their 70s and 80s were made, and appearance evaluation was conducted through 3D simulation. For objective evaluation, airgap, cross section, color distribution, etc. were analyzed to compare differences between patterns. The pattern shape of bodice for elderly males was a pattern without darts except for the L pattern. As a result of appearance evaluation for 3D simulation, the elderly males' pattern was found to have a significant difference among the patterns on the front, side, and back items, and the H pattern was analyzed as the best pattern in all items except the armhole shape on the side. As a result of evaluating the airgap, color distribution, and cross-section, the most suitable pattern for the elderly male's body type was analyzed as the H pattern. Based on the H pattern, it is thought that the development of a pattern suitable for the upper body shape of elderly male should be made.

O$_3/H_2O_2$를 이용한 1,4-dioxane의 산화에 미치는 $H_2O_2$ 농도의 영향

  • Seo, Myeong-Gyo;Gang, Dae-Jong;Park, Jin-Do;Lee, Hak-Seong;Seo, Jeong-Ho
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.11a
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    • pp.143-146
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    • 2005
  • O_$3/H_2O_2$를 이용하여 1,4-dioxane의 산화처리에 미치는 $H_2O_2$ 농도의 영향에 대하여 고찰하였다. 또한 1,4-dioxane의 생물학적 분해가능성도 파악하였다. 실험은 bubble column reactor를 이용하여 수행되었으며, 여러 pH 및 $H_2O_2$ 조건에서 수행되었다. $H_2O_2$ 농도가 40 - 120 mg/L 범위에서, 초기 $H_2O_2$ 농도가 높을수록 1,4-dioxane의 제거율 및 생물분해성도 증가하였다.

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