• Title/Summary/Keyword: H1-H2 measure

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The Thermodynamics of the Formation of Pyridine-Halogen and Interhalogens Charge Transfer Complexes (피리딘과 할로겐 또는 할로겐간 화합물 사이의 전하이동 착물생성에 관한 열역학적 연구)

  • Oh Cheun Kwun;Jin Burm Kyong;Kee Joon Choi
    • Journal of the Korean Chemical Society
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    • v.26 no.6
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    • pp.363-368
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    • 1982
  • Ultraviolet spectrophotometric investigations were carried out on the systems of pyridine with iodine, iodine monobromide and iodine monochloride in carbon tetrachloride. The results reveal the formation of the one to one molecular complexes of the type, $C_5H_5N{\cdot}I_2$, $ C_5H_5$N{\cdot}IBr and $ C_5H_5N{\cdot}ICl$. Considering ${\lambda}_max$ according to the formation of charge transfer complexes has the blue shift with the increasing temperatures$25, 40, 60^{\circ}C$ the equilibrium constants K and molar absorptivities $\varepsilon$ of complexes were obtained. From these values, the thermodynamic parameters ${\Delta}H$, ${\Delta}G$ and ${\Delta}S$ for the formation of the above charge transfer complexes were obtained. These results indicate that the relative stabilities of iodine, iodine monobromide and iodine monochloride complexes with pyridine increase in the order, $ C_5H_5N{\cdot}I_2$ < $ C_5H_5N{\cdot}IBr$ <$ C_5H_5N{\cdot}ICl$. This may be a measure of relative acidity of halogen and interhalogen toward pyridine and can be explained by the polarizabilities of electron acceptors and the difference of electronegativities of halogen atoms.

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The Effect of Digestive Medicine on Enamel Erosion (액상소화제가 법랑질 부식에 미치는 영향)

  • Lee, Hye-Jin;Oh, Han-Na
    • Journal of dental hygiene science
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    • v.17 no.4
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    • pp.352-357
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    • 2017
  • Consumption of liquid digestive medicine has continually grown in recent years. This present study was designed to evaluate the capability of liquid digestive medicine to erode dental enamel, relating the pH and titratable acidity of liquid digestive medicine. Three commercially available liquid digestive medicines were chosen these were Gashwalmyeungsu, Saengrokchun and Wicheongsu. The liquid digestive medicines were evaluated in respect to pH, titratable acidity and concentrations of calcium and phosphate, respectively. This measure was carried out three times for each digestive medicine and was recorded the data as mean (standard deviation). Bovine enamel specimens measured microhardness at base line and then were randomly assigned to 4 groups of 10 each. The specimens were immersed into each liquid digestive medicine for 1, 3, 5, 10, 15, and 30 minutes and then evaluated each time by VHN. All digestive medicines had a pH of less than 3.7. Wicheongsu had the lowest pH 2.93 and Gashwalmyeungsu had highest pH 3.63. In pH 5.5, titratable acidity of Wicheongsu was 1.27 ml. Gashwalmyeungsu was 0.63 ml. Saengrokchun was 0.60 ml. All liquid digestive medicines showed low concentration of calcium and phosphate. The microhardness of specimens after immersion into liquid digestive medicines was continuously reduced in all digestive medicines. After 30-minute treatment in liquid digestive medicines, Wicheongsu containing low pH and high tiratable acidity was shown to be lowest microhardness value ($207.80{\pm}15.52$). The three liquid digestive medicines caused surface softening of enamel erosion. We conclude that drinks, commonly consumed by functional dyspepsia patient can cause erosion of enamel.

The Effect of Glucose Deprivation on the Oxygen Deprivation-induced Changes of [[$^3H$]-5-hydroxytryptamine Release in Rat Hippocampal Slices (흰쥐 해마 절편에서 산소고갈에 의한 [$^3H$-5-hydroxytryptamine 유리변동에 미치는 포도당고갈의 영향)

  • 이경은
    • Toxicological Research
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    • v.14 no.4
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    • pp.483-488
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    • 1998
  • During cerebral ischemia two important factors such as hypoxia and reduction of glucose can act as modulating stressor affecting the release of amine neurotransmitters including 5-hydroxytryptamine (5-HT). This study was performed to investigate the effect of glucose deprivation on the oxygen deprivation-induced changes of [3H]-5-HT release in the rat hippocampal slices. Experimental groups were divided into 4 groups for this study: normoxic/normoglycemic group, oxygen-deprived group, glucose-deprived group, and oxygen/glucose-deprived group. The hippocampus of rat brain was sliced by 400 $\mu\textrm{m}$ thickness with manual chopper. After 30 minutes preincubation in the normal buffer, the slices were incubated for 20 min in buffer containing [3H]-5-HT (0.1 M, 74 $\mu\textrm$Ci) for uptake. To measure the release of [3H]-5-HT into the buffer, the incubation medium was drained of and refilled with fresh buffer every ten minutes through a sequence of 14 tubes. Oxygen deprivation by gassing with 95% $N_2$/5% $CO_2$ and/or glucose deprivation was done in the 6th and 7th tube. The radioactivities in each buffer and the tissue were counted using scintillation counter. The results were expressed as fractional release. When slices were exposed to oxygen-deprived media for 20 min, the diminution followed by the rebound release of [3H]-5-HT was observed during the post-oxygen deprived period. However, glucose deprivation or oxygen/glucose deprivation markedly increased the release of [3H]-5-HT. which was opposite to the pattern observed in oxygen-deprived group. These results suggested that oxygen deprivation itself inhibits [3H]-5-HT release in rat hippocampal slices during oxygen-deprived period, but additional glucose deprivation convert the inhibitory response to increase of [3H]-5-HT release.

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A Study of Design of $H_2O_2$/Kerosene Ignition Injector and Spray Characteristics (과산화수소/케로신 점화용 분사기 설계 및 분무특성에 관한 연구)

  • Kim, Bo-Yeon;Hwang, Oh-Sik;Lee, Yang-Suk;Ko, Young-Seong;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.37-40
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    • 2009
  • This study was performed to design of $H_2O_2$/Kerosene catalyst ignition injector and cold flow test to measure the mass flow rate and spray angle. Mass flow rate and spray angle were measured by designed injector through cold flow test. Result of test kerosene mass flow rate was measured 12.88 g/s and 40 deg of spray angle at pressure drop 3 bar as same as design point. And hydrogen peroxide was measured 94.39 g/s at pressure drop 1 bar smaller than design point.

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Effects of the Wire-screen Rib on Heat Transfer and Friction Factors (와이어 스크린 리브이 열전달과 마찰계수에 미치는 효과)

  • Oh, Se-Kyung;Ahn, Soo-Whan;Lee, Dae-Hee
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.2
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    • pp.196-203
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    • 2011
  • Experiments to determine heat transfer coefficients and friction factors are conducted on a stationary transverse parallel wire-screen rib roughened rectangular channel. The test section consists of 198 mm (W) x 40 mm (H) x 712 mm (L). The channel has the aspect ratio of 4.95 and hydraulic diameter of $D_h$=6.66 cm. Four wire screen ribs and a solid rib are used. 0.1 mm-thick-stainless steel foil heaters and thermocouples (T type) are used to measure the heat transfer coefficients. Reynolds numbers studied range from 20,000 to 60,000. The wire-screen rib height (e) to hydraulic diameter ($D_h$) ratio ($e/D_h$) is 0.075; spacing (p) to height ratio (p/e) is 10. Results indicate that the solid rib produces the greatest Nusselt number and friction factor.

Synthesis and Surface Properties of Hierarchical SiO2 Coating Layers by Forming Au Nanoparticles (금 나노입자 형성을 이용한 계층구조 SiO2 코팅층의 제조 및 표면 특성)

  • Kim, Ji Yeong;Kim, Eun-Kyeong;Kim, Sang Sub
    • Korean Journal of Materials Research
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    • v.23 no.1
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    • pp.53-58
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    • 2013
  • Superhydrophobic $SiO_2$ layers with a micro-nano hierarchical surface structure were prepared. $SiO_2$ layers deposited via an electrospray method combined with a sol-gel chemical route were rough on the microscale. Au particles were decorated on the surface of the microscale-rough $SiO_2$ layers by use of the photo-reduction process with different intensities ($0.11-1.9mW/cm^2$) and illumination times (60-240 sec) of ultraviolet light. With the aid of nanoscale Au nanoparticles, this consequently resulted in a micro-nano hierarchical surface structure. Subsequent fluorination treatment with a solution containing trichloro(1H,2H,2H,2H-perfluorooctyl)silane fluorinated the hierarchical $SiO_2$ layers. The change in surface roughness factor was in good agreement with that observed for the water contact angle, where the surface roughness factor developed as a measure needed to evaluate the degree of surface roughness. The resulting $SiO_2$ layers revealed excellent repellency toward various liquid droplets with different surface tensions ranging from 46 to 72.3 mN/m. Especially, the micro-nano hierarchical surface created at an illumination intensity of $0.11mW/cm^2$ and illumination time of 60 sec showed the largest water contact angle of $170^{\circ}$. Based on the Cassie-Baxter and Young-Dupre equations, the surface fraction and work of adhesion for the micronano hierarchical $SiO_2$ layers were evaluated. The work of adhesion was estimated to be less than $3{\times}10^{-3}N/m$ for all the liquid droplets. This exceptionally small work of adhesion is likely to be responsible for the strong repellency of the liquids to the micro-nano hierarchical $SiO_2$ layers.

DISCOVERY OF A STRONG LENSING GALAXY EMBEDDED IN A CLUSTER AT z = 1.62

  • WONG, KENNETH C.;TRAN, KIM-VY H.;SUYU, SHERRY H.;MOMCHEVA, IVELINA G.;BRAMMER, GABRIEL B.;BRODWIN, MARK;GONZALEZ, ANTHONY H.;HALKOLA, ALEKSI;KACPRZAK, GLENN G.;KOEKEMOER, ANTON M.;PAPOVICH, CASEY J.;RUDNICK, GREGORY H.
    • Publications of The Korean Astronomical Society
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    • v.30 no.2
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    • pp.389-392
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    • 2015
  • We identify a strong lensing galaxy in the cluster IRC 0218 that is spectroscopically confirmed to be at z = 1.62, making it the highest-redshift strong lens galaxy known. The lens is one of the two brightest cluster galaxies and lenses a background source galaxy into an arc and a counterimage. With Hubble Space Telescope (HST) grism and Keck/LRIS spectroscopy, we measure the source redshift to be $z_S=2.26$. Using HST imaging, we model the lens mass distribution with an elliptical power-law profile and account for the effects of the cluster halo and nearby galaxies. The Einstein radius is $^{\theta}E=0.38^{+0.02{\prime}{\prime}}_{-0.01}$ ($3.2^{+0.2}_{-0.1}kpc$) and the total enclosed mass is $M_{tot}(<^{\theta}_E)=1.8^{+0.2}_{-0.1}{\times}10^{11}M_{\odot}$. We estimate that the cluster environment contributes ~ 10% of this total mass. Assuming a Chabrier IMF, the dark matter fraction within $^{\theta}E$ is $f^{Chab}_{DM}=0.3^{+0.1}_{-0.3}$, while a Salpeter IMF is marginally inconsistent with the enclosed mass ($f^{Salp}_{DM}=-0.3^{+0.2}_{-0.5}$).

ERROR HOUNDS OF TRAPEZOIDAL RULE

  • Meehyea Yang;Hong, Bum-Il;Yang, Hyun-Suk
    • Journal of applied mathematics & informatics
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    • v.13 no.1_2
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    • pp.353-363
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    • 2003
  • In [2], if ${\gamma}$ $\leq$ 2, the average error of the composite Trapezoidal rule on two consecutive intervals turned out to be proportional to h$\^$2r+3/ where ${\gamma}$ is the number of differentiablity and h is the length of each uniform subinterval of the interval [0, 1] In this paper, we show that if ${\gamma}$ $\geq$ 3, the average error of the composite Trapezoidal rule on two consecutive intervals is bounded by Ch$\^$8/.

Double-Excitation Type Single Sheet Tester for the Measurement of the Magnetic Characteristics of the Electrical Steel Sheets (전기강판의 자기특성 측정을 위한 2방향 여자 형 Single Sheet tester 개발)

  • Kim, Hong Jung;Koh, Chang Seop;Hong, Sun-Ki;Shin, Pan Seok
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.54 no.10
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    • pp.461-469
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    • 2005
  • In this paper, a double-excitation type single sheet tester is developed to measure the magnetic characteristics of the electrical steel sheets. The developed system has the uniform magnetic field area of 20$\times$20mm$^{2}$, and can be applied to the measurement of the magnetic characteristics of the Non-oriented and Grain oriented electrical steel sheets. In the developed system, the magnetic flux density and magnetic field intensity are measured by using B-coil and H-coil, respectively. The B-coil has 1 turn search coil for each direction, and H-coil has 640 and 640 turns for rolling direction and transverse direction on the Im thickness Glass-Epoxy basement, respectively. Through experiments, it Is shown that the system can measure the magnetic characteristics up to 1.87 of magnetic flux density in the rolling direction in case of the Grain oriented electrical steel sheet. The measured results are compared with those measured in Okayama university, .Japan.

Prediction of non-exercise activity thermogenesis (NEAT) using multiple linear regression in healthy Korean adults: a preliminary study

  • Jung, Won-Sang;Park, Hun-Young;Kim, Sung-Woo;Kim, Jisu;Hwang, Hyejung;Lim, Kiwon
    • Korean Journal of Exercise Nutrition
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    • v.25 no.1
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    • pp.23-29
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    • 2021
  • [Purpose] This preliminary study aimed to develop a regression model to estimate the non-exercise activity thermogenesis (NEAT) of Korean adults using various easy-to-measure dependent variables. [Methods] NEAT was measured in 71 healthy adults (male n = 29; female n = 42). Statistical analysis was performed to develop a NEAT estimation regression model using the stepwise regression method. [Results] We confirmed that ageA, weightB, heart rate (HR)_averageC, weight × HR_averageD, weight × HR_sumE, systolic blood pressure (SBP) × HR_restF, fat mass ÷ height2G, gender × HR_averageH, and gender × weight × HR_sumI were important variables in various NEAT activity regression models. There was no significant difference between the measured NEAT values obtained using a metabolic gas analyzer and the predicted NEAT. [Conclusion] This preliminary study developed a regression model to estimate the NEAT in healthy Korean adults. The regression model was as follows: sitting = 1.431 - 0.013 × (A) + 0.00014 × (D) - 0.00005 × (F) + 0.006 × (H); leg jiggling = 1.102 - 0.011 × (A) + 0.013 × (B) + 0.005 × (H); standing = 1.713 - 0.013 × (A) + 0.0000017 × (I); 4.5 km/h walking = 0.864 + 0.035 × (B) + 0.0000041 × (E); 6.0 km/h walking = 4.029 - 0.024 × (C) + 0.00071 × (D); climbing up 1 stair = 1.308 - 0.016 × (A) + 0.00035 × (D) - 0.000085 × (F) - 0.098 × (G); and climbing up 2 stairs = 1.442 - 0.023 × (A) - 0.000093 × (F) - 0.121 × (G) + 0.0000624 × (E).