• 제목/요약/키워드: H-bonding

검색결과 897건 처리시간 0.034초

초음파를 이용한 Al/Al 하니캄 구조물의 Disbonding 검출에 관한 연구 (A Study on the Disbonding Detection of Al/Al Honeycomb Sandwich Structures by Ultrasonic Methods)

  • 조경식;이주석;장홍근;이승희
    • 비파괴검사학회지
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    • 제10권1호
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    • pp.29-37
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    • 1990
  • In this study the disbonding tests of adhesively bonded Al/Al honeycomb structures were performed by ultrasonic methods. Ultrasonic C-scan squiter method and ultrasonic surface wave attenuation measuring method were applied for the detection of skin/core disbonding. The bonding quality of Al/Al honeycomb structures could be well evaluated by properly controlled ultrasonic parameters.

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Assignment of the Redox Potentials of Cytochrome c₃of Desulfovibrio vulgaris Hildenborough by ¹H NMR

  • 박장수;강신원;신정휴
    • Bulletin of the Korean Chemical Society
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    • 제16권10호
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    • pp.968-971
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    • 1995
  • The heme assignment of the 1H NMR spectrum of cytochrome c3 of Desulfovibrio vulgaris Hildenborough within the X-ray structure were fully cross established according to their redox potential. The major reduction of the heme turned out to take place in the order of hemes Ⅳ,Ⅰ,Ⅱ and Ⅲ(the heme numbers indicating the order of bonding to the primary sequence). This assignment can provide the physicochemical basis for the elucidation of electron transfer of this protein.

Magnetostrictive Properties of Polymer-Bonded Fe-Co Based Alloy Composites

  • S. M. Na;S. J. Suh;K. H. Shin;Lee, Y. S.;S. H. Lim
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2002년도 동계연구발표회 논문개요집
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    • pp.138-139
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    • 2002
  • Polymer-bonded magnetostrictive composites have some distinct advantages over conventional type materials in being cost effective and suitable for high frequency applications due to high electrical resistivity. Composites of rare earth based alloys were reported to show good magnetostrictive characteristics both in static and dynamic conditions [1]. It was originally thought that the application of the polymer-bonding technique to transition metal alloys is straightforward. (omitted)

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모의 음향 방출 신호의 Peak Amplitude측정을 통한 복합 재료 접합부의 비파괴평가 (Nondestructive Evaluation of Adhesive Bonding Quality by Measurements of Peak Amplitude of Simulated Stress Wave)

  • 손영호;이종오;이승희
    • 비파괴검사학회지
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    • 제15권2호
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    • pp.357-363
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    • 1995
  • CFRP 복합 재료를 접착 접합한 single-lap 및 double-lap 접합 시험편의 disbond 크기를 초음파 C-scan 및 simulated stress wave를 이용하여 정량적으로 평가하고자 하였다. 초음파 C-scan 시험을 통해 인공 결함의 크기가 확인된 시험편을 사용하여, 접합부를 통과한 응력파의 주파수를 변화시키면서 peak amplitude를 측정하여 주파수 응답성을 구하였으며, 이를 분석한 결과 두 적층판의 두께 방향 기본 공진 및 3차 공진 주파수에서 peak amplitude가 극값을 보이며, 접합 면적에 비례함을 관측할 수 있었다. 이 결과로 표준시험편만 준비된다면 결함의 정량적 평가 및 현장 적용에도 이용할 수 있을 것으로 기대된다.

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황마섬유 보강 열경화성 복합재료의 기계적 특성 (Mechanical Properties of Jute Fiber Reinforced Thermosetting Composites)

  • 이창훈;송재은;남원상;변준형;김병선;황병선
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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    • pp.111-115
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    • 2005
  • Recently, natural fibers draw much interests in composite industry due to low cost, light weight, and environment-friendly characteristics compared with glass fibers. In this study, mechanical properties were evaluated for two extreme cases of jute fiber orientations, i.e. the unidirectional yarn composites and the felt fabric composites. Samples of jute fiber composites were fabricated by RTM process using epoxy resin, and tensile, compression, and shear tests were conducted. As can be expected, unidirectional fiber specimens in longitudinal direction showed the highest strength and modulus. Compared with glass/epoxy composites of the similar fabric architecture and fiber volume fraction, the tensile strength and modulus of jute felt/epoxy composites reached only 40% and 50% levels. However, the specific tensile strength and modulus increased to 80% and 90% of the glass/epoxy composites. The main reason for the poor mechanical properties of jute composites is associated with the weak interfacial bonding between fiber and matrix. The effect of surface treatment of jute fibers on the interfacial bonding will be examined in the future work.

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X-선 회절로 얻은 수소결합의 결합거리 보정 방법: 중성자 회절결과와 결합원자가 방법 이용 (Correction Method of the Hydrogen Bond-Distance from X-ray Diffraction: Use of Neutron Data and Bond Valence Method)

    • 한국광물학회지
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    • 제16권1호
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    • pp.65-73
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    • 2003
  • 이 연구에서는 X-선 회절법으로 측정한 수소결합의 거리를 보정하는 두 가지 방법을 제시하였다 O…O 거리가 2.5 $\AA$ 이상인 수소결합의 경우는 저온에서 측정한 중성자 회절에 의한 수소결합 데이터를 이용하여 얻은 최적화 곡선 식 d(O-H)=exp((2.173-d(O…O))/0.138)+0.958을 이용하여 수소결합 거리를 보정한다. O…O 거리가 2.5 $\AA$ 이하의 짧은 수소결합의 경우는 결합원자가 최적화 방법(valence-least-squares)을 이용하는 것이 효과적이다. X-선 회절분석으로 얻은 긴 O…O 거리를 갖는 분자간 수소결합의 경우는 수소결합의 거리보정을 해주어야 한다.

FDB 방식을 채용한 멀티 어레이 맥진 센서 설계 (Design of multi-array pulse diagnosis sensor with FDB process)

  • 전영주;이전;이유정;우영재;유현희;김종열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 학술대회 논문집 정보 및 제어부문
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    • pp.367-368
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    • 2008
  • 한의학의 주요 방법 중 하나인 맥진은 한의사가 환자의 손목 부위를 손가락으로 진맥하여 환자의 맥동을 감지하는 행위이다. 하지만 이러한 맥진은 주관적이고 형이학적 이어서 맥진의 발전을 위해서는 맥진의 객관화와 정량화가 요구된다. 본 연구는 기존의 와이어 본딩(wire bonding)을 이용한 맥진 센서의 단점인 내성을 극복하기 위하여 FDB(Face Down Bonding) 방식을 이용하였으며, $3{\times}3$ 멀티 어레이 센서간의 crosstalk를 극복하고자 센서들을 격리시킬 수 있는 댐(dam)을 형성하였다. 또한, 댐을 감싸고 상단 및 하단에 들기를 형성하는 패드를 이용하여 피부에 접촉하도록 제작하였다. 센서의 특성을 평가하기 위하여 각 센서 출력 단자의 저항 값을 측정하였으며 센서 스펙에서 제공하는 값과 동일함을 확인하였고, 실제 요골동맥 부위에서 맥파를 측정하여 전형적인 요골동맥 맥과 파형이 측정됨을 확인하였다.

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A Surface Modification of Hastelloy X by Sic Coating and Ion Beam Mixing for Application in Nuclear Hydrogen Production

  • Kim, Jaeun;Park, Jaewon;Kim, Minhwan;Kim, Yongwan
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.205.2-205.2
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    • 2014
  • The effects of ion beam mixing of a SiC film coated on super alloys (hastelloy X substrates) were studied, aiming at developing highly sustainable materials at above $900^{\circ}C$ in decomposed sulfuric acid gas (SO2/SO3/H2O) channels of a process heat exchanger. The bonding between two dissimilar materials is often problematic, particularly in coating metals with a ceramics protective layer. A strong bonding between SiC and hastelloy X was achieved by mixing the atoms at the interface by an ion-beam: The film was not peeled-off at ${\geq}900^{\circ}C$, confirming excellent adhesion, although the thermal expansion coefficient of hastelloy X is about three times higher than that of SiC. Instead, the SiC film was cracked along the grain boundary of the substrate at above $700^{\circ}C$. At ${\geq}900^{\circ}C$, the film was crystallized forming islands on the substrate so that a considerable part of the substrate surface could be exposed to the corrosive environment. To cover the exposed areas and cracks multiple coating/IBM processes have been developed. An immersion corrosion test in 80% sulfuric acid at $300^{\circ}C$ for 100 h showed that the weight retain rate was gradually increased when increasing the processing time.

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Backbone hydrogen bonding interaction of the inactive isoform of type III antifreeze proteins studied by 1H/15N-HSQC spectra

  • Seo-Ree, Choi;Sung Kuk, Kim;Jaewon, Choi;Joon-Hwa, Lee
    • 한국자기공명학회논문지
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    • 제26권4호
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    • pp.46-50
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    • 2022
  • Antifreeze proteins (AFPs) bind to the ice crystals and then are able to inhibit the freezing of body fluid at subzero temperatures. Type III AFPs are categorized into three subgroups, QAE1, QAE2, and SP isoforms, based on differences in their isoelectric points. We prepared the QAE2 (AFP11) and SP (AFP6) isoforms of the notched-fin eelpout AFP and their mutant constructs and determined their temperature gradients of amide proton chemical shifts (𝚫δ/𝚫T) using NMR. The nfeAFP11 (QAE2) has the distinct 𝚫δ/𝚫T pattern of the first 310 helix compared to the QAE1 isoforms. The nfeAFP6 (SP) has the deviated 𝚫δ/𝚫T values of many residues, indicating its backbone conformational distortion. The study suggests the distortion in the H-bonding interactions and backbone conformation that is important for TH activities.