• Title/Summary/Keyword: Grubbs 방법

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Outlier Detection of the Coastal Water Temperature Monitoring Data Using the Approximate and Detail Components (어림과 나머지 성분을 이용한 연안 수온자료의 이상자료 감지)

  • Cho, Hong-Yeon;Oh, Ji-Hee
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.2
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    • pp.156-162
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    • 2012
  • Outlier detection and treatment process is highly required as the first step for the statistical analysis of the monitoring data having many outliers frequently occurred in the coastal environmental monitoring projects. In this study, the outlier detection method using the approximate and detail (or residual) components of the (raw) data is suggested. The approximate and detail components of the data can be separated by the diverse filtering and smoothing methods. The decomposition of the data is carried out by the harmonic analysis and local regression curve, respectively. Then, the Grubbs' test and modified z-score method widely used to detect outliers in the data are applied to the detail components of the water temperature data. The new data set is reconstructed after removed the outliers detected by these methods. It can be shown that the suggested process is successfully applied to the outlier detection of the coastal water temperature monitoring data provided by the Real-time Information System for Aquaculture Environment, National Fisheries Research and Development Institute (NFRDI).

Estimation of Probability Rainfall considering Test for Outliers in Korea (이상치검정을 고려한 국내 확률강우량 산정)

  • Lee, Jung Sik;Shin, Chang Dong;Kang, Mi Soon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.309-314
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    • 2016
  • 본 연구에서는 확률강우량 산정을 위한 빈도해석 시 보다 타당하고, 신뢰도 높은 강우자료를 선정하여 수공구조물 설계 및 재난방재계획에 합리적인 기준을 제시하고자 이상치 적용에 따른 확률강우량을 산정 비교하였다. 이상치검정의 비교를 위하여 Grubbs and Beck 방법과 미국 수자원평의회 방법을 적용하였으며, 적용결과에 따라 강우자료를 조정하여 확률강우량을 산정 비교하여 타당성을 검토하였다. 본 연구의 수행으로 이상치검정에 따라 강우자료 년수에 변화가 있었으며, 기존의 방법과 확률강우량을 비교하였을 때, 증감이 나타났다.

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Organic Synthesis Based on Ruthenium Carbene Catalyzed Metathesis Reactions and Pyridinium Salt Photochemistry (루테늄 카벤 촉매 복분해 상호교환 반응과 피리듐 염 광화학반응을 이용한 유기 합성)

  • Cho, Dae-Won;Mariano, Patrick S.
    • Journal of the Korean Chemical Society
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    • v.54 no.3
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    • pp.261-268
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    • 2010
  • In this account, three synthetic methodologies that serve as the basis for new strategies for the preparation of selected natural products are briefly introduced. One process, involving ruthenium carbene catalyzed ring rearrangement metathesis developed by Grubbs and his coworkers, transforms alkene-tethered cycloalkenes to thermodynamically more favored alkene-tethered cycloalkenes. Another ruthenium carbene promoted reaction, referred to as dienyne metathesis, was uncovered in early studies by Grubbs and his collaborators. This process converts dienynes to fused bicyclic conjugated dienes. Finally, a novel photo-electrocyclization reaction of pyridinium salts, which leads to the formation of 4-aminocyclopenten-3,5-diol derivatives, is discussed. Examples are provided to show the utility of these methodologies in natural product synthesis. Emphasis is given to studies in which pyridinium salt photochemistry is coupled with ring rearrangement and dienyne metathesis in routes for the synthesis of polyhydroxyalted indolizidine alkaloids and the construction of the tricyclic core of the lepadiformine and cylindricine alkaloids.

A Round Robin Study of Solid Content Test and Applicability Estimation of FT-IR Analysis for Chemical Admixtures (다자비교시험을 통한 화학혼화제 고형분량 시험법의 신뢰성 및 FT-IR 분석에 대한 효용성 평가)

  • Kim, Jin-Cheol;Yoo, Hyeok-Jin;Kim, Hong-Sam;Park, Ko-Eun
    • Journal of the Korea Concrete Institute
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    • v.27 no.6
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    • pp.695-703
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    • 2015
  • Acceptance criteria for chemical admixtures of cement concrete were investigated in domestic and international specifications. The reliability was verified for solid content test method of chemical admixture examined statistical analysis by round robin test. The applicability of FT-IR spectroscopy for qualitative measurement of multi-compound chemical admixtures verified. From solid content experimental results, outlier analysed using Cochran, Grubbs and Dickson's Q test. Repeatability and reproducibility standard deviation for solid content results showed 0.25 and 0.098% respectively according to KS A ISO 5725-2 procedure, it can be confirmed reliability of test methods. FT-IR spectrum of liquefied or oven-dried chemical admixtures condition showed big differences. It is needed that the FT-IR analysis is performed on dry material. However there's no difference with the applicability of FT-IR spectroscopy for multi-compound chemical admixtures. So the utility of method analysis could not identify.

Verification on the Measurement Uncertainty for Surface Roughness (표면거칠기측정에 대한 측정불확도 추정방법)

  • Kim, Chang-Soon;Park, Min-Won
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.4
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    • pp.40-45
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    • 2010
  • Evaluation of uncertainty is an ongoing process that can consume time and resources. It can also require the service of someone who is familiar with data analysis techniques. Therefore, it is important for laboratory personnel who are approaching uncertainty analysis for the first time to be aware of the resources required. International inclination of measurement filed to guarantee the traceability and confidence of measurement results discards the error concept and instead analyzes the measurement uncertainty. In this paper, we analyzed the elements of measurement uncertainty on surface roughness test which are the important things in mechanical parts test. Repeat the test by 3 men, the measurement uncertainty could be calculated.