• Title/Summary/Keyword: Growth rate Constant

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Characteristics of $TiN/TiSi_2$ bilayer by $BF_2$ dopant at Si substrate (기판 실리콘의 $BF_2$ 불순물 원자에 의한 $TiN/TiSi_2$ bilayer의 특성)

  • Lee, C.J.;Park, J.S.;You, H.S.;Sung, Y.K.
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.835-838
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    • 1992
  • The $TiN/TiSi_2$ bilayer has been studied for contact barrier layer at ULSI recently. The $TiN/TiSi_2$ bilayer was formed by RTA in $NH_3$ ambient simultaneously after the Ti film was deposited on silicon substrate. In this paper, properties of $TiN/TiSi_2$ bilayer was evaluated according to $BF_2$ dopant concentration and dopant redistribution in $TiN/TiSi_2$ bilayer was also analyzed. In this experiment, the composition and structure of $TiN/TiSi_2$ bilayer were constant even though dopant concentration increased but silicide growth rate decreased. Boron atoms were redistributed within TiN film and at $TiSi_2Si$ interface during the bilayer formation.

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The Influence of Marine Environmental Factor on the Corrosion Fatigue Fracture of SS41 Steel (SS41강의 부식피로파양에 미치는 해양환경인자의 영향)

  • 김원영;임종문
    • Journal of Advanced Marine Engineering and Technology
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    • v.15 no.1
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    • pp.51-58
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    • 1991
  • Corrosion fatigue test was performed by the use of plane bending fatigue tester in marine environment having various specific resistance from 25(natural sea water) to 5000.ohm.cm. It is in order to investigate the effects of marine environmental factor on the corrosion fatigue fracture of SS41 steel. The main results obtained are as follows; 1. The aspect ratio(b/a) of corner crack growing in natural sea water is lower than that in air. 2. The surface crack growth rate(da/dN) in marine environment is faster than that in air and da/dN delaies with the specific resistance increased. 3. The experimental constant m of paris rule [da/dN=C(${\delta}$K)$^m$] decrease with the specific resistance decreased and the effect of corrosion in proportion to the specific resistance is more sensitive than that of stress intensity factor range(${\delta}$K) under region II. 4. The accelerative factor(${\alpha}$) in marine environment is about 1.1-2.7 and .alpha. is increase under the low region of stress intensity factor range(${\delta}$K). 5. The electrode potential($E_0$) gets less noble potential with the specific resistance decreased.

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Studies on the Immobilization of Saccharomyces cerevisiae for Ethanol Production (효모의 Alginate 고정화에 관한 연구)

  • 한면수;하상도;정동효
    • Microbiology and Biotechnology Letters
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    • v.19 no.4
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    • pp.390-397
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    • 1991
  • Ethanol production by calcium alginate-immobilized baker's yeast (Saccharor/tyces cereviszae) was studied in the batch fermentation using glucose medium as a feed. Immobilied cells were stable between $30^{\circ}C$ and $40^{\circ}C$ whereas free cells were stable between $30^{\circ}C$ and $37^{\circ}C$ The beads were showed constant ethanol productivity during 720 hours (30 days) over. Fermentation characteristics of immobilized baker's yeast were examined changing the initial glucose concentration of broth in fermentation. Initial glucose concentrations employed were 50, 100, 150 and 200 g/l, respectively. In 15% gucose medium, maximum specific growth rate, maximum ethanol yield and ethanol concentration were observed as 0.092 $h^{-1}$, 0.45, 67.5 g/l, respectively.

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Measurement of Hydrogenation Characteristics of Pd Film by Using Electrical Resistivity Measurement Technique (전기저항 측정법을 이용한 Pd박막의 수소화 특성 측정)

  • Cho, Young-Sin;Lee, Ho-Jae;Lee, Jong-Suk
    • Transactions of the Korean hydrogen and new energy society
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    • v.7 no.2
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    • pp.173-180
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    • 1996
  • 4-probe resistivity measurement technique was used to study kinetics of hydrogen absorption-desorption on Pd film($520{\AA}$ thick) at room temperature upto 1 bar. Kinetics data are fitted well to 1st order kinetics equation in ${\alpha}$ and ${\alpha}^{\prime}$ phases. In ${\alpha}+{\alpha}^{\prime}$ phase, absorption kinetics was very complicated, but it could be explained partially with nucleation and growth process. Ln(dR/dt) vs. time plot gives rate constant k value(R is resistance of sample, t is time). k value for absorption is $4^{-6}{\times}10^{-4}/sec$ in ${\alpha}$ phase. k is increasing upto $4^{\times}10^{-2}/sec$ as hydrogen pressure increasing in ${\alpha}^{\prime}$ phase. k is proportional to ln(Pop/Peq), where Peq is equilibrium plateau pressure and Pop is the opposing pressure. In contrast to bulk sample k value was decreasing with increasing number of A-D cycling in ${\alpha}^{\prime}$ phase absorption.

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A Study on Failure Analysis of Low Pressure Trubine Blade Using AFM and FEM (AFM과 FEH을 이용한 저압 터빈 블레이드의 파손해석에 관한 연구)

  • Hong, Soon-Hyeok;Cho, Seok-Swoo;Joo, Won-Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.11
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    • pp.1705-1712
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    • 2001
  • Mechanical component has striation with constant width and SEM can estimate fracture type and loading condition. SEM has benefit to fatigue fracture analysis but striation can be observed according to the kind of material and range of crack growth rate and can't. In this case, it needs AFM that can measure 3-dimensional surface profile with resolution of atomic size. In this study. to find fracture reason of torsion-mounted blade in nuclear plant, we estimate the relation between stress intensity factor range and root mean square roughness in 12% Cr steel by AFM and predict in-service loading condition of turbine blade. failure analysis is performed by finite element method and Goodman diagram on torsion-mounted blade.

A Study on the Influence of Fiber Orientation on the Mode I Interlaminar Fracture Behavior of Carbon/Epoxy Composite materials (탄소섬유/에폭시 복합재료의 Mode I 층간파괴거동에 미치는 섬유배향각의 영향에 관한 연구)

  • 이택순;최영근
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.2
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    • pp.391-401
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    • 1995
  • Several tests of the Double Cantilever Beam(DCB) were carried out for influence of the fiber orientation on the Mode I of the interlaminar fracture behavior in the Carbon/Epoxy composites. The interlaminar fracture toughness of Mode I was estimated based on the energy release rate of Mode I, $G_{I}$. The fracture toughness at crack initiation, $G_{IC}$, increases from type A to type E. The fracture toughness, $G_{IR}$ , is almost constant macroscopically for type A and type E when crack propagates. $G_{IR}$ for types B, C, D increases rapidly at the beginning of the crack growth then it decreases gradually. The fracture surface observation by SEM was also obtained the same results. Consequently the influence of the fiber orientation on the Mode I Interlaminar fracture behavior was made clear.ear.

Respiratory Activity of Bacteria in Various Concentrations of Glucose (박테리아의 산소소비량에 관한 실험적 고찰)

  • Choi, Hyung-Ja
    • Journal of Preventive Medicine and Public Health
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    • v.10 no.1
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    • pp.134-137
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    • 1977
  • The most efficient method for reducing the organic content of dilute liquid waste is by aerobic-biological treatment. Basically, the organisms responsible for treatment possess the ability to decompose complex organic compounds and to use the energy so liberated for their bodily functions: reproduction, growth, locomotion and so on. That part of organic matter used to produce energy is converted to the essentially stable end products of carbon dioxide, water and ammonia, while the remainder is converted to new cells which can be settled and thus removed from the liquid before the waste is discharged to the receiving body water. Oxygen must be supplied continuously during the aerobic process. In the field of sewage treatment the Warburg respirometer is used mainly for the measurement of the oxygen uptake of samples. In this experiment the Warburg constant volume respirometer was used to determine the oxygen uptake by bacteria in the presence of various glucose concentrations. The rate of oxygen uptake by the bacteria was expressed as the respiratory quotient. The result indicated that the oxygen uptake was proportional to the glucose concentration. The expecting equation of the regression line was Y=7.7+0.12X where Y: respiratory quotient, ${\mu}l.\;O_2$ taken up/mg. dry wt. bacterium/hr. X: concentration of glucose, mg/l

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Double-Diffusive Convection Due to Heating from Below in a Rotating Cylindrical Cavity (회전하는 원통형밀폐용기내의 아랫면가열에 의한 이중확산대류에 관한 실험적 연구)

  • 강신형;이태홍;이진호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.7
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    • pp.1731-1740
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    • 1995
  • Experimental investigations have been made to study the double-diffusive nature of convection of an initially stratified salt-water solution due to heating from below in a rotating cylindrical cavity. The objective is to examine the flow phenomena and the heat transfer characteristics according to the changes in temperature gradient, concentration gradient and rotating velocity of cavity. Thermal and solutal boundary conditions at side wall are adiabatic and impermeable, respectively. The top and bottom plate are maintained each at constant temperature and concentration. The cavity is put into a state of solid body rotation. Like the stationary case, the types of initially-formed flow pattern are classified into three regimes depending on the effective Rayleigh number and Taylor number; stagnant flow regime, single mixed-layer flow regime and successively formed multi-mixed layer flow regime. At the same effective Rayleigh number, the number of initially-formed mixed layer and its growth rate decrease as the effect of rotation increases. The temperature and concentration profiles are both uniform in each layer due to convective mixing in the layered-flow regime, but look both liner in stagnant flow regime and single mixed-layer flow regime. At the interface between adjacent layers, the temperature changes smoothly but the concentration changes rapidly.

Characteristics of Fatigue Crack Propagation and Fatigue Life Prediction of Thin Sheet Al Alloy (박판 Al 합금재료의 피로균열전파특성과 피로수명예측)

  • Kim, Seung-Gwon;Lee, Ouk-Sub;Yang, Heang-Ryeal;Yeo, In-Cheol;Park, Sung-Wan
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.356-361
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    • 2008
  • In characteristics of fatigue crack propagation, it is important that fatigue life is affected by crack closure phenomenon in thin sheet Al alloy. The purpose of this paper is to analyze the characteristics of fatigue crack propagation in constant loading condition for sheet Al 2024-T3 alloy of two sort of thickness and identify the difference of fatigue life in thin sheet specimen comparing experimental results of thin sheet specimen and relatively thick sheet specimen under same fatigue loading condition. In applying fatigue related material constants from fatigue crack propagation analysis, we attempt to operate the fatigue life estimating process of thin sheet specimen by modified Paris‘ law considering crack closure phenomenon and analyze the experimental and prediction results of fatigue life in thin sheet Al alloy.

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Effect of High Temperature and Pressure Conditions on the Combustion Characteristics of n-butanol and n-heptane Fuel (고온, 고압의 분위기 변화가 n-butanol 및 n-heptane 연료의 연소 특성에 미치는 영향)

  • Lim, Young Chan;Suh, Hyun Kyu
    • Journal of ILASS-Korea
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    • v.21 no.1
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    • pp.29-36
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    • 2016
  • The effect of high ambient temperature and pressure conditions on the combustion performance of n-butanol, n-heptane and its mixing fuel (BH 20) were studied in this work. To reveal this, the closed homogeneous reactor model applied and 1000-1200 K of the initial temperature, 20-30 atm of initial pressure and 1.0 of equivalence ratio were set to numerical analysis. It was found that the results of combustion temperature was increased and the ignition delay was decreased when the ambient conditions were elevated since the combustion reactivity increased at the high ambient conditions. On the contrary, under the low combustion temperature condition, the combustion pressure was more influenced by the ambient temperature in the same ambient conditions. In addition, the total mass and the mass density of tested fuels were influenced by the ambient pressure and temperature. Also, soot generation of mixing fuel was decreased than n-heptane fuel due to the oxygen content of n-butanol fuel.