• Title/Summary/Keyword: Group technology

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Development and Application of Group IV Transition Metal Oxide Precursors

  • Kim, Da Hye;Park, Bo Keun;Jeone, Dong Ju;Kim, Chang Gyoun;Son, Seung Uk;Chung, Taek-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.303.2-303.2
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    • 2014
  • The oxides of group IV transition metals such as titanium, zirconium, hafnium have many important current and future application, including protective coatings, sensors and dielectric layers in thin film electroluminescent (TFEL) devices. Recently, group IV transition metal oxide films have been intensively investigated as replacements for SiO2. Due to high permittivities (k~14-25) compared with SiO2 (k~3.9), large band-gaps, large band offsets and high thermodynamic stability on silicon. Herein, we report the synthesis of new group IV transition metal complexes as useful precursors to deposit their oxide thin films using chemical vapor deposition technique. The complexes were characterized by FT-IR, 1H NMR, 13C NMR and thermogravimetric analysis (TGA). Newly synthesised compounds show high volatility and thermal stability, so we are trying to deposit metal oxide thin films using the complexes by Atomic Layer Deposition (ALD).

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Adaptive energy group division in the few-group cross-section generation for full spectrum reactor modeling with deterministic method

  • Yichen Yang;Youqi Zheng;Xianan Du;Hongchun Wu
    • Nuclear Engineering and Technology
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    • v.56 no.6
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    • pp.2019-2028
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    • 2024
  • Advanced nuclear reactors, especially the newly developed small and micro-reactors have complex neutron spectrum, which makes the deterministic reactor core calculations sensitive to the energy group structure of few-group cross-sections. To avoid significantly increasing the cost of energy discretization in the core calculation, two energy group structures with 31 groups and 33 groups were adopted for typical thermal and fast reactor cores, respectively. Then, an adaptive scheme of group division for reactor cores with a medium neutron spectrum was proposed. The works were based on the full spectrum nuclear reactor analysis code SARAX/TULIP. An equivalent one-dimensional model of the core was proposed to capture the key neutron spectrum features of the reactor core. Such features were used to adaptively determine a few-group structure for the following reactor core calculations. Then, the neutron spectrum in different zones with more details was calculated. With this spectrum, the cross-sections were condensed into the determined energy groups. Three tests based on different neutron spectrum were calculated to verify the schemes. The results show that using the adaptive energy group division scheme, the following core calculation can meet the accuracy requirement of different reactors with different neutron spectra.

Blazed $GxL^{TM}$ Device for Laser Dream Theatre at the Aichi Expo 2005

  • Ito, Yasuyuki;Saruta, Kunihiko;Kasai, Hiroto;Nshida, Masato;Yamaguchi, Masanari;Yamashita, Keitaro;Taguchi, Ayumu;Oniki, Kazunao;Tamada, Hitoshi
    • Journal of Information Display
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    • v.8 no.2
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    • pp.10-14
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    • 2007
  • A blazed $GxL^{TM}$ device is described as having high optical efficiency (> 70% for RGB lasers), and high contrast ratio (> 10,000:1), and that is highly reliable when used in a large-area laser projection system. It has a robust design and precise stress control technology to maintain a uniform shape (bow and tilt) of more than 6,000 ribbons, a $0.25-{\mu}m$ CMOS compatible fabrication processing and planarization techniques to reduce fluctuation of the ribbons, and a reliable Al-Cu reflective film that provided protection against a high-power laser. No degradation in characteristics of the GxL device is observed after operating a 5,000- lumen projector for 2,000 hours and conducting 2,000 temperature cycling tests at $-20^{\circ}C$ and $+80^{\circ}C$. At the 2005 World Exposition in Aichi, Japan the world's largest laser projection screen with a size of 2005 inches (10 m ${\times}$ 50 m) and 6 million pixels (1,080 ${\times}$ 5,760) was demonstrated.