• Title/Summary/Keyword: Group condensation

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EFFECTS OF CONDENSATION TECHNIQUES AND CANAL SIZES ON THE MICROLEAKAGE OF ORTHOGRADE MTA APICAL PLUG IN SIMULATED CANALS (모조 근관의 크기와 충전 방법이 orthograde MTA apical plug의 미세누출에 미치는 영향)

  • Nam, Deuk-Lim;Park, Jeong-Kil;Hur, Bock;Kim, Hyeon-Cheol
    • Restorative Dentistry and Endodontics
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    • v.34 no.3
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    • pp.208-214
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    • 2009
  • The purpose of this study was to compare the dye leakage of MTA (mineral trioxide aggregate) apical plug produced by two orthograde placement techniques (hand condensation technique and ultrasonically assisted hand condensation technique). To simulate straight canal, 60 transparent acrylic blocks with straight canal were fabricated. These transparent acrylic blocks were divided into 2 groups (Group C; hand condensation technique (HC) and Group U; ultrasonically assisted hand condensation technique (UAHC)) of 30 blocks with each MTA application method. Each group was divided into 2 subgroups (n=15) with different canal size of #70 (subgroup C70 and subgroup U70) and #120 (subgroup C120 and subgroup U120). After apical plug was created, a wet paper point was placed over the MTA plug and specimen was kept in a humid condition at room temperature to allow MTA to set. After 24 hours, remaining canal space was backfilled using Obtura II. All specimens were transferred to floral form socked by 0.2% rhodamine B solution and stored in 100% humidity at room temperature. After 48 hours, resin block specimens were washed and scanned using a scanner. The maximum length of micro leakage was measured from the scanned images of four surfaces of each resin block using Photoshop 6.0. Statistical analysis was performed with Mann-Whitney U test. Group U of UAHC had significantly lower leakage than Group C of HC in #70-size canal (subgroup U70) (p<0.05).

Condensation Reduction Study of an Apartment Underground Elevator Hall with respect to Dehumidifier Locations (제습기 설치 위치에 따른 공동주택 지하 엘리베이터홀의 결로 저감 연구)

  • Park, Jong-Jun;Kim, Young-Il;Kim, Jong-Yeob;Kim, Gil Tae
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.26 no.4
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    • pp.169-174
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    • 2014
  • Computational fluid dynamics simulation of an apartment underground elevator hall has been carried out to study the effect of dehumidifier locations on condensation problem. In Case 1, horizontal position of humidifier is studied. It is installed at entrance, center or the inside of the elevator hall. In Case 2, installation height is studied, one at 0 m and the other at 1.6 m above the floor. In Case 3, exposed and embedded dehumidifiers are compared for performance. The study shows that the entrance, top and exposed locations are more effective in reducing condensation.

AN EXPERIMENTAL STUDY ON THE SEALING ABILITY OF DIFFERENT ROOT CANAL OBTURATION METHODS (각종 근관충전법의 치근단 폐쇄효과에 관한 연구)

  • Hur, Seung-Myun;Cho, Young-Gon
    • Restorative Dentistry and Endodontics
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    • v.16 no.2
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    • pp.143-154
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    • 1991
  • The purpose of this study was to evaluate the sealing ability of five obturation methods in conjunction with sealer. Fifty extracted upper and lower anterior teeth were selected and the access cavities were prepared lingually with a round bur. The working length was determined with a #15K file, and the root canals were instrumented with a #40K file 1mm short of the apical foramen. The apical third of root canal was flared by step-back technique and the coronal two thirds of root canal using #2 - 3 Gates Glidden drills. And then, the teeth were randomly assigned to five groups of 10 teeth each. A thin coat of Tubliseal was placed into the canal into the canal using the # 35 reamer and the canals were filled by lateral condensation, vertical condensation, ultrasonic activated lateral condensation, ULTRAFIL injecting, and McSpadden compaction methods. All teeth were stored in 100 % relative humidity at 31c for 48 hours. The roots were suspended in 2 % methylene blue solution for 48 hours, left to dry for 24 hours and then, half side of root was removed longitudinally using the fissure bur. A Boley gauge wes used to measure the distance, to the nearest 0.1mm, from the apical foramen to the most coronal level of dye penetration. The measurement of dye penetration was statistically compared by Duncan's multiple range test The results were as follows 1. Ultrasonic group showed the best sealing ability among the all experimental groups, but there were statistically no significant difference in the sealing ability between ultrasonic group and vertical condensation group. 2. There were no statistically significant difference in the sealing ability among the lateral, vertical, and ultrasonic groups. 3. McSpadden group showed the worst sealing ability among the all exprimental groups.

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Knoevenagel Condensation Reaction Using Amine-functionalized MCM-41 Base Catalysts (아민고정화 MCM-41 염기촉매를 이용한 Knoevenagel 축합반응)

  • Choi, Jung-Sik;Ahn, Wha-Seung
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.417-423
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    • 2006
  • A series of amine functionalized MCM-41 catalysts were prepared by aminopropyltrimethoxysilane grafting and their catalytic performance in Knoevenagel reaction of selected substrates was investigated. Water resistant and catalytically active amine grafted MCM-41 was prepared by post-synthetic silylation using methyltrimethoxysilane ; hydrogen bonding of the water molecules formed during the condensation reaction to the active N group was suppressed, which led to high TON of the reaction. Amine functionalized MCM-41 prepared by coating method produced high conversion, but the TON of the catalyst was much lower than that of the amine grafted MCM-41; pore volume of the functionalized MCM-41 decreased substantially and large portion of the immobilized amine is believed to be hydrogen bonded to each other, which can result in decrease in the basicity of the N group. A secondary amine group was prepared by room temperature condensation between aminopropylsilane and chloropropylsilane, and the MCM-41 grafted with the secondary amine group demonstrated the highest catalytic activity among the catalysts prepared.

Measurement of Porcelain Shrinkage After Firing Using the Phase-Shifting Profilometry (위상이동 형상측정법을 이용한 도재 소성시의 도재 수축률의 측정)

  • Lee, Cheong-Hee
    • The Journal of Korean Academy of Prosthodontics
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    • v.37 no.6
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    • pp.800-808
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    • 1999
  • To compare several porcelains made by various manufacturers in shrinkage after firing and investigate the effect of condensation on shrinkage, specimens were prepared and the volume of each body was measured by the phase-shifting profilometry. Baseplate wax was cut by $2.5cm{\times}2cm$ and cast in nonprecious metal(Verabond, U.S.A.), then any surfaces of specimens were abrased and polished on the SiC abrasing papers, preparing 120 specimens. Specimens were divided into six groups according to the porcelain used, and the porcelain used in each group were as follows. Group I : Ceramco dentin porcelain Group B : Creation dentin porcelain Group III : Creation margin porcelain Group IV : Vintage margin porcelain Group V : Vita dentin porcelain Group VI : Vintage dentin porcelain Porcelain was built up on the metal plates using a small spoon and then solution matching to each porcelain was added. The six groups are subdivided into a and b. In subgroup a, only excessive solution was absorbed with tissue and in subgroup b, porcelain was condensed sufficiently. When build-up was completed, the shape was measured using the phase-shifting profilometry. After that, specimens were fired in the furnace programed for each porcelain and then their changed shape were measured again. Using the difference between the two above measurements, the ratio of shrinkage was calculated. Obtained results were as follows ; 1. Regardless of condensation, the volume of fired specimens were not different significantly between the two subgroups a and b in the same group. 2. The ratios of shrinkage were significantly higher in the groups porcelain built-up was condensed than in the groups not condensed 3. The ratios of shrinkage were in the range of 36.81-27.19% in the groups porcelain built up was condensed and 44.52-37.54% in the other groups not condensed.

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AN EXPERIMENTAL STUDY ON THE APICAL MARGINAL LEAKAGE OF DIFFERENT OBTURATION METHODS (근관충전 방법에 따른 치근단부 근관의 변연 누출에 관한 연구)

  • Cho, Yong-Bum;Hong, Chan-Ui
    • Restorative Dentistry and Endodontics
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    • v.15 no.1
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    • pp.81-87
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    • 1990
  • The purpose of this study was to evaluate the apical seal produced by low temperature($70^{\circ}C$) injection gutta percha technique(ULTRAFIL) with & without sealer, warm latero-vertical cindensation technique (ENDOTEC) with & without sealer, and the lateral condensation technique with sealer. 100 extracted, single rooted human teeth were divided into 5 groups and root canals were enlarged & obturated according to the purpose of this study. Obturated teeth were immersed in 2.5% methylene blue for 48hrs. at $37^{\circ}C$ incubator and split. The apical sealing ability was evaluated by measuring the degree of dye penetration into the canal. The results were as follows: 1. All group showed varying depth of dye penetration. 2. There were no significant difference among Group I (lateral condensation), Group II (ULTRAFIL with sealer) & Group IV (ENDOTEC with sealer) (P>0.05). 3. There were less dye penetration when used in conjunction with sealer (P<0.001).

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Major factors determining the size distributions of atmospheric water-soluble aerosol particles at an urban site during winter (겨울철 도시지역 대기 수용성 에어로졸 입자의 크기 분포를 결정하는 주요 인자)

  • Park, Seungshik
    • Particle and aerosol research
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    • v.17 no.3
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    • pp.43-54
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    • 2021
  • Size distributions of atmospheric particulate matter (PM) and its water-soluble organic and inorganic components were measured between January and February 2021 at an urban site in Gwangju in order to identify the major factors that determine their size distributions. Their size distributions during the study period were mainly divided into two groups. In the first group, PM, NO3-, SO42-, NH4+ and water-soluble organic carbon (WSOC) exhibited bi-modal size distributions with a dominant condensation mode at a particle size of 0.32 ㎛. This group was dominated by local production of secondary water-soluble components under atmospheric stagnation and low relative humidity (RH) conditions, rather than long-range transportation of aerosol particles from China. On the other hand, in the second group, they showed tri-modal size distributions with a very pronounced droplet mode at a diameter of 1.0 ㎛. These size distributions were attributable to the local generation and accumulation of secondary aerosol particles under atmospheric conditions such as atmospheric stagnation and high RH, and an increase in the influx of atmospheric aerosol particles by long-distance transportation abroad. Contributions of droplet mode NO3-, SO42-, NH4+ and WSOC to fine particles in the second group were significantly higher than those in the first group period. However, their condensation mode contributions were about two-fold higher in the first group than in the second group. The significant difference in the size distribution of the accumulation mode of the WSOC and secondary ionic components between the two groups was due to the influx of aerosol particles with a long residence time by long-distance transport from China and local weather conditions (e.g., RH).

Silica Supported Ammonium Acetate: An Efficient and Recyclable Heterogeneous Catalyst for Knoevenagel Condensation between Adehydes or Ketones and Active Methylene Group in Liquid Phase

  • Gupta, Raman;Gupta, Monika;Paul, Satya;Gupta, Rajive
    • Bulletin of the Korean Chemical Society
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    • v.30 no.10
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    • pp.2419-2421
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    • 2009
  • A simple and efficient method has been developed for Knoevenagel condensation between aldehydes or ketones and active methylene group by stirring in methylene chloride at 60 ${^{\circ}C}$ under heterogeneous conditions using silica supported ammonium acetate. The products are obtained in excellent yields and are in a state of high purity. The structures of the products were confirmed by IR, $^1H$ NMR and mass spectral data and comparison with authentic samples available commercially.