• Title/Summary/Keyword: Ground state

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A Study on the Removal of Taste and Odor Compounds by Activated Carbon Adsorption (활성탄(活性炭) 흡착(吸着)에 의한 취기유발물질(臭氣誘發物質) 제거(除去)에 관(關)한 연구(硏究) -GEOSMIN, 2-MIB를 중심으로-)

  • Kim, Han Seung;Kwon, Bong Kee;Park, Chung Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.8 no.2
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    • pp.12-24
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    • 1994
  • The occurrence of objectionable tastes and odors in drinking water is a common and widespread problem. The most troublesome odors are usually those described as muddy or earthy-musty. Two organic compounds which have been implicated as the cause of earthy-musty odor problems in water are geosmin and 2-Methylisoborneol. These earthy-musty organics have been shown to be metabolites of actinomycetes and blue green algae. The purpose of this paper is to describe adsorbability in removing these two oder causing compounds(geosmin and 2-MIB) upon various conditions like pH variation, adding humic acid and different activated carbon. The conclusion of this study are as followings. In batch test, carbon dosage is 10mg/100ml for geosmin and 15mg/100ml for 2-MIB. Both were in equilibrium state after 60 hours. In model simulation, F-P model described experiment data and modelling data appropriately in geosmin but F-S model not. In case of 2-MIB, models didn't describe relation between experiment and modelling data well. Two causative agents of earthy-musty odor compounds, geosmin and 2-MIB, are strongly adsorbed by activated carbon either coconut or brown. There appears to be no effect of pH (3,7,9) on adsorption of these two organics. Activated carbon proved to be more effective for removing geosmin than for removing 2-MIB. When activated carbon is. used in removing these two organics, the removal of these appeared to be adversely affected by back ground organic compounds, such as humic substances, due to competitive adsorption.

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A Comparative Study of the Draping Pattern based on Setting Waist Base Line of Dress Form (인대의 허리 기준선 설정에 따른 입체 패턴 비교 연구)

  • Yang, Chung-Eun;Kim, Yang-Weon;Lee, Eun-Kyung;Lee, Hae-Young
    • Korean Journal of Human Ecology
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    • v.16 no.5
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    • pp.969-977
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    • 2007
  • The research thesis has been intended to make a comparative analysis on the basic bodice pattern and basic skirt pattern changing on the basis of setting waist line of dress form in an effort to set reasonable standards in selecting the standard lines of drees form. The thesis has made the wearing evaluation by producing the sample of upper and lower dress based on A pattern and B pattern. In details, A pattern functions to keep waist line flatly down from lateral waist-right to posterior waist in a little curved state, paralleling bust line and hipline with waistline. And, B pattern functions to keep waistline, bust line and hipline horizontal paralleling with ground surface. SPSS win 10.1 program was used for the analysis of evaluation and t-test. The result is as follows: For basic bodice-front of upper dress, A and B patterns have made little significant difference. With regard to basic bodice-back, B pattern has got the higher evaluation than A pattern, in the pattern stability and appearance. For basic skirt pattern, A pattern has got the lower evaluation in the aspect of total back appearance, back dart, hip line, and waist line, and front drape. Basic bodice pattern of A pattern, which takes on the different horizontal standard lines of dress form depending on the selection of waistline, and basic skirt pattern has scored less in terms of pattern stability and appearance.

Rheological Evaluation of Petroleum Jelly as a Base Material in Ointment and Cream Formulations : Linear Viscoelastic Behavior

  • Park, Eun-Kyoung;Song, Ki-Won
    • Journal of Pharmaceutical Investigation
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    • v.41 no.3
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    • pp.161-171
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    • 2011
  • The objective of the present study is to systematically characterize a linear viscoelastic behavior of petroleum jelly in small amplitude oscillatory shear flow fields correspondent to the rheological ground state. With this aim, using a strain-controlled rheometer, the dynamic viscoelastic properties of commercially available petroleum jelly have been measured at $37^{\circ}C$ (body temperature) over a wide range of angular frequencies at an extremely small strain amplitude of 0.1 %. In this article, the linear viscoelastic behavior was reported in detail and then explained from a structural view-point of petroleum jelly and discussed in depth with respect to the consumer's requirements. Main findings obtained from this study can be summarized as follows : (1) The storage modulus is always greater than the loss modulus over an entire range of angular frequencies studied, meaning that the linear viscoelastic behavior of petroleum jelly is dominated by an elastic nature rather than a viscous nature. (2) Petroleum jelly shows a desirable linear viscoelastic behavior with respect to the consumer's requirements because it is undesirable for the product to flow down from the skin at an initial stage upon contact with the human skin. (3) A fractional derivative model shows an excellent applicability to describe a linear viscoelastic behavior of petroleum jelly. However, this model should be used with a special caution because there exists no physical meaning for the model parameters. (4) A modified form of the Cox-Merz rule gives a good ability to predict the relationship between steady shear flow properties (nonlinear behavior) and dynamic viscoelastic properties (linear behavior) for petroleum jelly.

Semiempirical Calculations of Hyperpolarizabilities for Quinoline Derivatives (Quinoline계 분자의 초분극률에 관한 반경험적 계산)

  • Ryu Ungsik;Choi Donghoon;Kim Nakjoong;Lee Yoon Sup
    • Journal of the Korean Chemical Society
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    • v.37 no.1
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    • pp.62-67
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    • 1993
  • The microscopic origin of nonlinear optical properties of quinoline derivatives have been investigated theoretically using MOPAC-AM1 method. In order to prepare promising nonlinear optical active polymers of polyquinoline derivatives, the optimized positions of strong electron donor and electron acceptor are determined in the heterocyclic ring for the energetically favorable structures. For each compound, the effect of the substituted positions on the microscopic nonlinear coefficients were investigated. Polyquinoline was already evaluated to have outstanding physical and mechanical properties so that its monomeric analogues were designed and synthesized for developing new second and third order nonlinear optical main chain polymers. Using the MOPAC-AM1 method, properties calculated include the intrinsic ground-state dipole moments, the polarizabilities, first and second hyperpolarizabilities under the condition of finite-field $(\omega$ = 0).

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Ab Initio Studies on Hydrogen-Bonded Trimers Formed between Hydrogen Cyanide and Hydrogen Fluorides (시안화수소와 플루오르화수소와의 수소결합 삼합체들에 관한 Ab Initio 연구)

  • Rhee, Soon Ki;Lee, Hyun Jin
    • Journal of the Korean Chemical Society
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    • v.40 no.3
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    • pp.187-195
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    • 1996
  • Ab initio SCF calculations have been carried out for the five conceivable trimers formed between one hydrogen cyanide and two hydrogen fluorides using a basis set of TZ+P quality. Several ground state properties of these trimeric complexes have been evaluated, and compared with those of isolated monomers and appropriate dimers. Computed equilibrium geometries, stabilization energies, and dipole moments are given in order to suppliment the available experimental data. At this level of approximation, intramolecular bond distances are consistently shorter than experimental ones. However, intermolecular distances upon complex formation, and dipole moments are overestimated compared with experimental ones. HCN$(HF)_2$ trimer appears to be the most favourable among the five kinds of trimer complex, and also more stable than $(HCN)_2HF$. The typical features of the non-additivity of intermolecular interaction are relatively strong in the HCN$(HF)_2$ trimer.

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Dynamic Rapid Synthesis of Bis(2,2'-bipyridine)nitrato Zinc (II) Nitrate Using a Microwave Method and its Application to Dye-Sensitized Solar Cells (DSSC)

  • Kim, Young-Mi;Kim, Su-Jung;Nahm, Kee-Pyung;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2923-2928
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    • 2010
  • This study examined the synthesis of the crystal structure of bis(2,2'-bipyridine)nitrato zinc (II) nitrate, $[Zn(bipy)_2(NO_3)]^+NO_3^-$ using a microwave treatment at 300 W and 60 Hz for the application to dye-sensitized solar cells. The simulated complex structure of the complex was optimized with the density functional theory calculations for the UV-vis spectrum of the ground state using Gaussian 03 at the B3LYP/LANL2DZ level. The structure of the acquired complex was expected a penta-coordination with four nitrogen atoms of bipyridine and the oxygen bond of the $NO_3^-$ ion. The reflectance UV-vis absorption spectra exhibited two absorptions (L-L transfers) that were assigned to the transfers from the ligand ($\sigma$, $\pi$) of $NO_3$ to the ligand ($\sigma^*$, $\pi^*$) of pyridine at around 200 - 350 nm, and from the non-bonding orbital (n) of O in $NO_3$ to the p-orbital of pyridine at around 450 - 550 nm, respectively. The photoelectric efficiency was approximately 0.397% in the dye-sensitized solar cells with the nanometer-sized $TiO_2$ at an open-circuit voltage (Voc) of 0.39 V, a short-circuit current density (Jsc) of $1.79\;mA/cm^2$, and an incident light intensity of $100\;mW/cm^2$.

Development of PBD Method for Concrete Mix Proportion Design Using Bayesian Probabilistic Method (Bayesian 통계법을 활용한 성능기반형 콘크리트 배합설계방법 개발)

  • Kim, Jang-Ho Jay;Phan, Duc-Hung;Lee, Keun-Sung;Yi, Na-Hyun;Kim, Sung-Bae
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.171-177
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    • 2010
  • Recently, Performance Based Design (PBD) method has been studied as a next generation structural design method, which enables a designed structure to satisfy the required performance during its service life. One method of deciding whether the required performance has been satisfied is Bayesian method, which has been commonly used in seismic analysis. Generally, it is presented as a conditional probability of exceeding some limit state (i.e., collapse) for a given ground motion. In PBD of concrete mixture design, the same methodology can be applied to assess concrete material performance based on some conditional parameters (i.e. strength, workability, carbonation, etc). In this paper, a detailed explanation of the procedure of drawing satisfaction curve by using Bayesian method based on various material parameters is shown. Also, a discussion of using the developed satisfaction curves for PBD for concrete mixture design is presented.

A Numerical Study of Mesoscale Model Initialization with Data Assimilation

  • Min, Ki-Hong
    • Journal of the Korean earth science society
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    • v.35 no.5
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    • pp.342-353
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    • 2014
  • Data for model analysis derived from the finite volume (fv) GCM (Goddard Earth Observing System Ver. 4, GEOS-4) and the Land Data Assimilation System (LDAS) have been utilized in a mesoscale model. These data are tested to provide initial conditions and lateral boundary forcings to the Purdue Mesoscale Model (PMM) for a case study of the Midwestern flood that took place from 21-23 May 1998. The simulated results with fvGCM and LDAS soil moisture and temperature data are compared with that of ECMWF reanalysis. The initial conditions of the land surface provided by fvGCM/LDAS show significant differences in both soil moisture and ground temperature when compared to ECMWF control run, which results in a much different atmospheric state in the Planetary Boundary Layer (PBL). The simulation result shows that significant changes to the forecasted weather system occur due to the surface initial conditions, especially for the precipitation and temperature over the land. In comparing precipitation, moisture budgets, and surface energy, not only do the intensity and the location of precipitation over the Midwestern U.S. coincide better when running fvGCM/LDAS, but also the temperature forecast agrees better when compared to ECMWF reanalysis data. However, the precipitation over the Rocky Mountains is too large due to the cumulus parameterization scheme used in the PMM. The RMS errors and biases of fvGCM/LDAS are smaller than the control run and show statistical significance supporting the conclusion that the use of LDAS improves the precipitation and temperature forecast in the case of the Midwestern flood. The same method can be applied to Korea and simulations will be carried out as more LDAS data becomes available.

Verification on Cold-Tolerance of Some Fruit Trees as Species for Urban Greening Plants

  • Lee, Jin-Hee;Oh, Hee-Young;Kwon, O-Man
    • Journal of Environmental Science International
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    • v.26 no.10
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    • pp.1155-1166
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    • 2017
  • This study selected commonly known species of fruit trees, and re-selected the species that endure the stress of extreme cold weather and physiologically restore themselves to the previous state until the following year. Then we could go ahead to propose the species that were appropriate as urban greening plants in weather condition of any part of the country. To do this, we conducted an experiments for six species of fruit trees based on the preference of the general public and recommendation of the experts; Morus alba (English name: mulberries), Diospyros kaki (English name: Persimmon), Prunus persia (English name: Peach), Elaeagnus umbellata var. coreana (English name: Korean Autumn Olive), Malus domestica 'Alps Otome' (English name: Alps Otome), and Prunus mume (English name: Blue Plum). The experiment verifies whether the trees survive without any stress from the cold weather under the national climate conditions (one in the suburbs of Seoul: Yongin city, one in the central Chungcheong region: Daejeon city, and in the southern Gyeongsang region: Jinju city in Korea). The experiment lasted for a year from August 2016 to August 2017. The levels of electrolytic efflux, chlorophyll content, plant height, fresh weight, and dry weight were measured four times (on August of 2016, January, February, and August of 2017) for each tree planted bare ground outdoors. Results showed that Diospyros kaki, Prunus persia, and Malus domestica 'Alps Otome' were proven durable and resistant to winters of all three areas (one in the suburbs of Seoul: Yongin city, one in the central Chungcheong region: Daejeon city, and in the southern Gyeongsang region: Jinju city in Korea). Especially, the increase of chlorophyll content and the reduction of electrolytic efflux were noticeable in Prunus persia than in the other two species, proving itself as the most cold-tolerant among the six species used in the experiment. In addition, interpreting from the physiological restoration data of one-year span before and after getting through winterer, Prunus persia was proven to be the most cold-tolerant species.

A Vehicle Classification Method in Thermal Video Sequences using both Shape and Local Features (형태특징과 지역특징 융합기법을 활용한 열영상 기반의 차량 분류 방법)

  • Yang, Dong Won
    • Journal of IKEEE
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    • v.24 no.1
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    • pp.97-105
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    • 2020
  • A thermal imaging sensor receives the radiating energy from the target and the background, so it has been widely used for detection, tracking, and classification of targets at night for military purpose. In recognizing the target automatically using thermal images, if the correct edges of object are used then it can generate the classification results with high accuracy. However since the thermal images have lower spatial resolution and more blurred edges than color images, the accuracy of the classification using thermal images can be decreased. In this paper, to overcome this problem, a new hierarchical classifier using both shape and local features based on the segmentation reliabilities, and the class/pose updating method for vehicle classification are proposed. The proposed classification method was validated using thermal video sequences of more than 20,000 images which include four types of military vehicles - main battle tank, armored personnel carrier, military truck, and estate car. The experiment results showed that the proposed method outperformed the state-of-the-arts methods in classification accuracy.