• Resources Recycling
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• v.21 no.4
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• pp.44-52
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• 2012

The purpose of this study is to confirm the possibility of obtaining high grade coal from fixed carbon 20.68% coal. Also, the mineralogical, physical/chemical and liberation characteristics was found with the aim of decrease in ash amount, during the pre-processing of clean coal technology. In this study, batch flotation and microbubble column flotation that was appropriate for the processing of fine particles was used with the variation in kinds and quantity of frother, collector and depressant. Also grinding time, air flow rate and feeding rates were examined. As a result of batch flotation, using pulp density 20%, collector DMU-101+dodecyl amine(100 mL/ton), frother pine oil (200 mL/ton), depressant sodium silicate(1 kg/ton), obtained the result of ash rejection 81.55% and combustible recovery 70.23%. In result of microbubble column flotation, the result was ash rejection 83.85% and combustible recovery 70.42% under the condition of pulp density 5%, grinding time 5 min. collector DMU-101+DDA(100 mL/ton), frother AF65(5.4 L/ton), depressant SMP(3.5 kg/ton), wash water(360 mL/min.) and air flow rate(1,197 mL/min.).

• Journal of Korean Society of Environmental Engineers
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• v.38 no.7
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• pp.343-352
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• 2016

Effects of grinding time and chemicals dosage in arsenic removal from contaminated paddy soil in China were investigated using lab scale attrition and froth flotation combining process. Arsenic concentration in the field soil was 76.51 mg/kg, exceeding Korean and Chinese standards, and predominant arsenic compounds fraction in sequential extraction was "residual" (over 80%). After wet sieving, soil with >2 mm and < 0.038 mm showed concentration lower than 'Warning Level' in Korea. Soil with 0.038-0.075 mm, showing the highest concentration, was discarded since it occupied minor weight fraction (10.1%). Thus soil between 0.075 and 2 mm was only used in the combining process. The highest Arsenic concentration in progeny fragments smaller than 0.038 mm reached up to 981.66 mg/kg after 5 min of attrition. Optimal dosage of collector ($C_5H_{11}OCS_2K$) and modifier ($Na_2S$ and $CuSO_4$) in froth flotation process for the selective separation of the chipped progeny particles from the parent fragments were determined both as 200 g/ton. Arsenic removal efficiency in froth flotation process was 38.47% and it was increased to 72.74% in additional flotation process, scavenging. Average arsenic concentration after overall process - wet sieving, attrition and froth flotation - was estimated to 16.45 mg/kg.

• Restorative Dentistry and Endodontics
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• v.25 no.2
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• pp.243-253
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• 2000

The purpose of this in vitro study was to evaluate dentin bonding by two different dentin bonding systems(DBS) using acetone based primer or adhesive [All Bond 2(AB2), One Step(OS)] when they were applied by wet or dry bonding technique. Morphology of resin-dentin interface and hybrid layer thickness(HLT) were investigated using Confocal Laser Scanning Microscope(CLSM) and compared to shear bond strength(SBS). 72 extracted sound human molars were randomly divided into 4 groups of 18 teeth each - Group 1.(AW); AB2 by wet bonding. Group 2(AD); AB2 by dry bonding. Group 3.(OW); OS by wet bonding, Group 4.(OD); OS by dry bonding. In 6 teeth of each group, notch-shaped class V cavities(depth 2mm) were prepared on buccal and lingual surface at the cementoenamel juction(12 cavities per group). To obtain color contrast in CLSM observation, bonding resins of each DBS were mixed with rhodamine B and primer of AB2 was mixed with sodium fluorescein. Prepared teeth of each group were treated with AB2, OS, respectively according to the manufacturer's instructions except for dentin surface moisture treatment after acid etching. In group 1 and 3, after acid etching, excess water was removed with wet tissue(Kimwipes), leaving consistently shiny, visibly hydrated dentin surface. In group 2 and 4, dentin surface was dried for 10 seconds at 1 inch distance. The treated teeth were then packed with composite resin(${\AE}$litefil) and light-cured. 12 microscopic samples($60{\sim}80{\mu}m$ thickness) of each group were obtained after longitudinal section and grinding(Exakt cutting and grinding system). Morphological investigation of resin-dentin interface and HLT measurement using CLSM were done. For measurement of SBS, remaining 12 teeth of each group were flattened occlusally to remove all enamel and grinded to 500 grit SiC(Pedemet Specimen Preparation Equipment). After applying DBS on the exposed dentin surface, composite resin was applied in the shape of cylinder, which has 5mm diameter, 1.5mm thickness, and light cured. SBS was measured using Instron with a crosshead speed of 0.5mm/min. It was concluded as follows, 1. HLT of AW(mean: $2.59{\mu}m$) was thicker than any other group, and followed by AD, OW, OD in descending order(mean; 2.37, 2.28, $1.92{\mu}m$). Only OD had statistically significant differences(p<0.05) to AW and AD. 2. There were intimate contact of resin and dentin at the interface in wet bonding groups, but gaps or irregular interfaces were observed in dry bonding groups. 3. The length, diameter, density of resin tags were various even in the same group without significant differences between groups and lots of adhesive lateral branches were observed. 4. There were no statistically significant difference of SBS between AB2 and OS, but SBS of wet bonding groups were significantly higher(p<0.05) than dry bonding groups. 5. There were no consistent relationships between HLT and SBS.

• Conservation Science in Museum
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• v.25
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• pp.9-26
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• 2021

This paper describes the production methods that were originally used for an arrow bundle excavated from a Bronze Age residential area in Auraji in Jeongseon, Gangwon-do Province and the conservation treatment process that it subsequently underwent. An arrow conventionally consists of an arrowhead and a shaft. It is rare to excavate a shaft along with an arrowhead in a complete form since the shaft is made of organic materials. Notably, the arrow bundle from the Auraji site is of great significance as it shows traces of tangless stone arrowheads attached to charred shafts and offers an important case of the split end of a piece of a tree being inserted into an arrowhead. For a further examination of the characteristics of the arrows from Auraji, microscopic investigation was conducted and the type of wood used for the arrow shafts was examined. The sequence and direction of processing and the particle sizes of the grinding tools were revealed through the analysis of traces of grinding on the stone arrowheads. The shaft is presumed to have been made from a green length of three-year-old willow (Salix spp.). A curing agent with a high degree of waterproofing and reversibility was used during the on-site curing process according to demands of the surrounding environment, and a technique that the authors call the "Bridge" method was used for emergency collection of the relics. Once the bundle was transferred to the conservation treatment lab, reinforcing materials were carefully chosen as it was important not to damage the relics during the process of turning them for the repair of their reverse sides. For this purpose, artificial clay was selected since it can safely bear a load and has excellent physical properties. Finally, detached parts were rejoined, the relics and their surrounding materials were cleaned, and the bottom sides were finished with epoxy resin prior to the display of the relics at the museum.

• The Journal of Korean Academy of Prosthodontics
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• v.54 no.3
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• pp.253-258
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• 2016

The development of translucent zirconia enabled clinicians to choose a monolithic zirconia crown as one treatment modality in the posterior dentition. Careful occlusal adjustments are recommended for monolithic zirconia crowns because grinding zirconia inevitably causes phase transformation, which may deteriorate mechanical properties. intraoral scanners enable the clinician to scan and superimpose a complete tooth structure before preparation onto the prepared abutment. This technique helps to reproduce the original tooth form and occlusion of the patient. In this case report, prostheses were fabricated for patients with cracked or fractured tooth by applying intraoral scanner, Computer aided design-computer aided manufacturing (CAD-CAM) and monolithic zirconia crown to reproduce the occlusion of original tooth and to minimize occlusal adjustment. The clinical results were satisfactory in both esthetic and functional aspects.

• The Journal of Korean Academy of Prosthodontics
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• v.36 no.1
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• pp.120-132
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• 1998

This stusy was to investigate the marginal fitness of porcelain-fused-to- metal crown after succesive firing cycle. Main variables were the degree of marginal curvature of labiocervical margin and the type of alloy. The exaggerated marginal curvature(EMC) was created by additional reduction at the faciocervical wall of the normallized marginal curvature (NMC)-typed ivorine tooth by using milling machine. The difference in the shape was the mid facial margin was placed 2mm apical to cemento- enamel junction in labial surface. Three types of alloy were high noble, noble, and base metal alloy. Test specimens were divided into 8 groups and each group had 8 specimens. Sixty four ceramometal crowns were made totally. Measurement stages were following degassing, opaquing. body porcelain firing, and glazing, and measuring sites were 4. (midmesial, midfacial, middistal, and midlingual). Digital, travelling measuring microscope (0.5 um precision, Olympus. Japan) was used under ${\times}250$ magnification. Within the limitation of this investigation, it was concluded as belows: 1. The pattern of marginal distortion was varied. Degassing stage was not a specific, causative stage that induce most of total marginal distortion during whole procedure fabricating a ceramometal crown. Body firing stage induced discrepancy relatively more than other firing stages. 2. The specimens that were Ni-based alloy and had EMC were distorted persistently following successive fabricating procedures. But marginal openings were decreased after glazing. 3. The release of metal grinding-induced stress was presumed as a cause that induce marginal distortion. 4. The amount of discrepancies of the labial and lingual margins were greater than that of the mesial and distal margin in the specimen that had EMC. 5. Silver-plated die was not enough to resist abrasion during repeated seating of metal copings on the die-holding device.

• Advanced Composite Materials
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• v.18 no.2
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• pp.187-195
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• 2009

Much attention has been paid to the processing of inorganic whisker, especially calcium carbonate whisker, which can be used as reinforcement materials of polymer composite due to its low price. Unfortunately, the present synthesis technique of calcium carbonate whisker starts from calcinations of limestone, which involves high energy consumption and furthermore is a highly environment polluting reaction. In this report, needle-like aragonite was synthesized with a reversible solution reaction from limestone without calcination. Optical microscopy, scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques were used to characterize the morphology and crystal structure of intermediates as well as that of the product, aragonite. GCC (grinding calcium carbonate) powder was dissolved in an aqueous solution of magnesium sulfate with reflux and air flush. EDTA titration was used to evaluate reaction rate of the dissolution. A kinetics equation of the dissolution reaction was constructed, which displayed second-order kinetics with respect to the concentration of magnesium sulfate. A rate constant of $0.0015\;l^{-3}{\cdot}mol^{-1}{\cdot}h^{-1}$ was obtained. The dissolution reaction gave fiber-like magnesium hydroxide sulfate and gypsum crystal. Then needle-like aragonite with a length of $9.13\;{\pm}\;1.02\;{\mu}m$ and an aspect ratio of $5.64\;{\pm}\;1.37$ was synthesized from the dissolution product with $CO_2$ bubbling at $70^{\circ}C$.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.56 no.1
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• pp.88-93
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• 2011

This experiment was carried out to find suitable sample type for the more accurate prediction and non-destructive way in the application of near infrared reflectance spectroscopy (NIRS) technique for estimation the protein, total amino acids, and total isoflavone of soybean by comparing three different sample types, single seed, whole seeds, and milled seeds powder. The coefficient of determination in calibration ($R^2$) and coefficient of determination in cross-validation (1-VR) for three components analyzed using NIRS revealed that milled powder sample type yielded the highest, followed by single seed, and the whole seeds as the lowest. The coefficient of determination in calibration for single seed was moderately low($R^2$ 0.70-0.84), while the calibration equation developed with NIRS data scanned with whole seeds showed the lowest accuracy and reliability compared with other sample groups. The scatter plot for NIRS data versus the reference data of whole seeds showed the widest data cloud, in contrary with the milled powder type which showed flatter data cloud. By comparison of NIRS results for total isoflavone, total amino acids, and protein of soybean seeds with three sample types, the powder sample could be estimated for the most accurate prediction. However, based from the results, the use of single bean samples, without grinding the seeds and in consideration with NIRS application for more nondestructive and faster prediction, is proven to be a promising strategy for soybean component estimation using NIRS.

• Journal of the Korean Ceramic Society
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• v.44 no.7
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• pp.368-374
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• 2007

CVD-SiC coating has been introduced as a protective layer in TRISO nuclear fuel particle of high temperature gas cooled reactor (HTGR) due to its excellent mechanical stability at high temperature. In order to prevent the failure of the TRISO particles, it is important to evaluate the fracture strength of the SiC coating layer. It is needed to develop a new simple characterization technique to evaluate the mechanical properties of the coating layer as a pre-irradiation step. In present work, direct strength measurement method with the specimen of hem i-spherical shell configuration was suggested. The indentation experiment on a hemisphere shell with a plate indenter was conducted. The fracture strength of the coating layer is related with the critical load for radial cracking of the shell. The finite element analysis was used to drive the semi-empirical equation for the strength measurement. The SiC hemispherical shells were successfully recovered from the section-grinding of TRISO coated particle and successive heat treatment in air. The strength of CVD-SiC coating layer was evaluated from the experimentally measured critical load during the indentation on SiC hemisphere shell. Weibull diagram of fracture strength was also constructed. This study suggested a new strength equation and experimental method to measure the fracture strength of CVD-SiC coating of TRISO coated fuel particles.

• Restorative Dentistry and Endodontics
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• v.19 no.1
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• pp.231-254
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• 1994

Fracture of cusp, on posterior teeth, especially those carious or restored, is major cause of tooth loss. Inappropriate treatments, such as unnecessarily wide cavity preparations, increase the potential of further trauma and possible fracture of the remaining tooth structures. Fracture potential may be directly related to the stresses exerted upon the tooth during masticatory function. The purpose of this study is to evaluate the fracture resistance of tooth, restored with composite resin inlay. In this study, MOD inlay cavity prepared on maxillary first premolar and restored with composite resin inlay. Three dimensional finite element models with eight nodes isoparametric solid element, developed by serial grinding-photographing technique. These models have various occlusal isthmus and depth of cavity, 1/2, 1/3 and 1/4 of isthmus width and 0.7, 0.85 and 1.0 of depth of cavity. The magnitude of load was 474 N and 172 N as presented to maximal biting force and normal chewing force. These loads applied onto ridges of buccal and lingual cusp. These models analyzed with three dimensional finite element method. The results of this study were as follows : 1. There is no difference of displacement between width of occlusal isthmus and depth of cavity. 2. The stress concentrated at bucco-mesial comer, bucco-disal comer, pulpal line angle and the interface area between internal slopes of cusp and resin inlay. 3. The vector of stress direct to buccal and lingual side from center of cavity, to tooth surface going on to enamel. The magnitude of vector increase from occlusal surface to cervix. 4. The crack of tooth start interface area, between internal slop of buccal cusp and resin inlay. It progresses through buccopulpal line angle to cervix at buccomesial and buccodistal comer. 5. The influence with depth of cavity to fracture of tooth was more than width of isthmus. 6. It would be favorable to make the isthmus width narrower than a third of the intercuspal distance and depth of cavity is below 1 : 0.7.