• Title/Summary/Keyword: Green process engineering

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Chemiluminescence Determination of Balofloxacin Based on Europium (III)-Sensitized KBrO3-Na2S2O4 Reaction in Micellar Medium

  • Zhao, Fang;Qi, Yu;Xiong, Wei
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.204-208
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    • 2012
  • A novel chemiluminescence (CL) flow injection method for the determination of balofloxacin is described. The method is based on the weak CL signal arising from the reaction of $KBrO_3$ with $Na_2S_2O_4$ in acidic medium being significantly enhanced by balofloxacin in the presence of europium (III) ion and sodium dodecyl benzene sulfonate (SDBS). The experimental conditions that affected CL intensity were carefully optimized and the CL reaction mechanism was briefly discussed. Under the optimum conditions, the relative CL intensity was proportional to the concentration of balofloxacin in the range of $7.0{\times}10^{-11}$ to $3.0{\times}10^{-7}g\;mL^{-1}$. The detection limit was $2.7{\times}10^{-11}g\;mL^{-1}$ and the relative standard deviation was 2.1% for $7.0{\times}10^{-10}g\;mL^{-1}$ balofloxacin (n = 13). The proposed method was successfully applied to the determination of balofloxacin in pharmaceutical formulations and biological fluids.

Adsorption Characteristics of Malachite Green Employing Waste Garnet as Adsorbent (폐석류석을 흡착제로 이용한 말라카이트그린 흡착 특성)

  • Baek, Mi-Hwa;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.216-221
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    • 2007
  • The adsorption characteristics of malachite green on waste garnet have been investigated for its treatment from aqueous solution by employing waste garnet which is generated from the abrasive production process as an adsorbent. The influential factors examined were the initial concentration of malachite green in solution, reaction temperature, and the amount of adsorbent. Also, the effect of the modification of the surface of adsorbent on adsorption was examined. As the initial malachite green was increased with reaction temperature and the color removal of malachite green-containing solution was promoted with the amount of adsorbent. Finaly, increased adsorption of malachite green could be attained when the surface of glass was modified by hexamethyldisilazane.

R&D Project Selection Methodology for Green Technology : Focused on Developing Country-Oriented Technology Commercialization (녹색기술 유망 R&D 과제 선정 방법론 : 개도국향 기술사업화를 중심으로)

  • Park, Chulho;Han, Joon;Ku, Jisun;Lee, Sanghoon;Lee, Hakyeon
    • Journal of Korean Institute of Industrial Engineers
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    • v.43 no.1
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    • pp.49-61
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    • 2017
  • This paper proposes an R&D project selection methodology for green technology centered on developing country-oriented technology commercialization. Eight selection criteria are derived from the R&BD logic model : technology needs of developing countries, effectiveness of green technology, technological potentials, domestic technological capability, commercialization feasibility, economic benefits, business feasibility, and spillover effects of developing countries. 21 qualitative and quantitative indicators are then defined for each criterion. The analytic hierarchy process is conducted to produce relative importance of evaluation indicators and to set final priority scores of R&D project candidates. The working of the proposed methodology is provided with the help of a case study example of Green Technology Center. The proposed methodology is expected to be effectively utilized for policy practices of R&D project selection in the field of green technology.

Process Design and Economic Evaluation of Condensate Recycling Process for Steam Consumption Reduction (스팀 사용 저감을 위한 응축수 재활용 공정설계 및 경제성 평가)

  • Kim, Jinuk;Choi, Yeongryeol;Cho, Hyungtae;Kim, Junghwan
    • Applied Chemistry for Engineering
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    • v.31 no.6
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    • pp.660-667
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    • 2020
  • This study focused on the epoxy resin production process, which uses the steam of 155 ℃ or higher as a heat source, and discards all condensate generated. A part of the process is operated at low temperatures of 70 ℃ or below, thus there are opportunities to reduce the steam consumption by recycling wasted condensate as a heat source for the low temperature section of process. In this study, we developed process models that can reduce steam by recovering waste heat through recycling condensate and conducted a case study to find an optimal condensate recycling system. Three different process designs were proposed and economic evaluations were performed by comparing annual capital costs and steam savings in each case. Finally, an annual steam consumption of the low-temperature section could be reduced by up to 67.6%, which could also bring an additional economic benefit of 522.1 million won/yr.

Improved performance of polyamide nanofiltration membranes by incorporating reduced glutathione during interfacial polymerization

  • Jiao, Zhiwei;Zhou, Linjie;Wu, Mengyuan;Gao, Kang;Su, Yanlei;Jiang, Zhongyi
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2487-2495
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    • 2018
  • Inspired by the specific amino acid sequence Asn-Pro-Ala (NPA) of water channel aquaporins (AQPs), we fabricated polyamide (PA) nanofiltration (NF) membranes by introducing reduced glutathione (GSH) in interfacial polymerization (IP) method. Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectrometry (XPS), scanning electron microscope (SEM), atomic force microscopy (AFM), zeta potential and static water contact angle measurement were employed to characterize the chemical composition, morphology, electronegativity and hydrophilicity of the NF membranes. The water flux of GSH/PIP-TMC NF membrane reached $32.00L\;m^{-2}h^{-1}$ at 0.2 MPa, which was approximately twice than that of pristine PIP-TMC NF membrane when the ratio of GHS to piperazidine (PIP) was 40% during IP process. More water channels were built as GSH was embedded into PA layer. The fabricated NF membranes also took on potent rejection for dyes and $Na_2SO_4$. This study presents a simple and facile method to simulate water channels-based biological materials which may find potential application in water treatment.

Green Six Sigma for Green Growth Implementation (녹색성장 실행을 위한 그린 6시그마)

  • Kim, Dong-Chun;Hong, Sung-Hoon;Shin, Wan-Seon
    • Journal of Korean Society for Quality Management
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    • v.38 no.4
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    • pp.521-530
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    • 2010
  • Global regulatory pressures relating climate change and environmental responsibility are asking companies to find out the best way for sustaining their continuous business growths. It could be known that inadequate management for environmental issues are bad for business, negatively affecting brand image, causing unnecessary losses and costs for environmental preservation. For this reason, environmentally conscious green business growth has been recognized as an essential requirement for a company to stay in business. Many companies are looking for green business opportunities of improving their environmental and financial results, and struggling with how green fits into their business. In this paper, the Green Six Sigma, an environmentally conscious Six Sigma methodology, is presented as a way to find solutions for green growths. The Six Sigma is known as a disciplined, data-driven approach and methodology for achieving world-class performance in any process from manufacturing to transactional. In chronological order, the Six Sigma has been evolved from Motorola's quality-oriented methodology to GE's cost-oriented lean approach, and is being evolved and developed as an environment-oriented green growth approach. There is no doubt that the Green Six Sigma, as an engine of green growth, is a power tool for achieving competitive business performance and reducing the impact on the environment.

Physical Properties of ALC with Various Fineness of Quartzite (규석 분말도에 따른 ALC의 물리적 특성 변화)

  • Chu, Yong-Sik;Jung, Ui-Jong;Song, Hun;Lee, Jong-Kyu;Kim, Young-Gon;Kang, Dae-Gu
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.407-411
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    • 2010
  • ALC was fabricated using cement, lime and quartzite by hydrothermal reaction. ALC has low strength and brittleness on account of inner pores. The studies for resolving these problems were driven by many researchers. Among these researches, the controls of quartzite fineness have been studied for unsuitable properties of ALC. This study experimented with variation of 90 ${\mu}m$ residue for obtain good physical properties. It was found that 90 ${\mu}m$ residue influenced on physical properties of ALC. The lower amount of 90 ${\mu}m$ residue, the higher compressive and bending strength. But the continuing decrease of 90 ${\mu}m$ residue did not cause the increase of strength. In order to application of these results in process, the states of process and hydrothermal products will be considered.

Multistage Operation of Airlift Photobioreactor for Increased Production of Astaxanthin from Haematococcus pluvialis

  • Choi, Yoon-E;Yun, Yeoung-Sang;Park, Jong-Moon;Yang, Ji-Won
    • Journal of Microbiology and Biotechnology
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    • v.21 no.10
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    • pp.1081-1087
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    • 2011
  • An internally radiating photobioreactor was applied for the production of astaxanthin using the unicellular green alga Haematococcus pluvialis. The cellular morphology of H. pluvialis was significantly affected by the intensity of irradiance of the photobioreactor. Small green cells were widespread under lower light intensity, whereas big reddish cells were predominant under high light intensity. For these reasons, growth reflected by cell number or dry weight varied markedly with light conditions. Even under internal illumination of the photobioreactor, light penetration was significantly decreased as algal cells grew. Therefore, we employed a multistage process by gradually increasing the internal illuminations for astaxanthin production. Our results revealed that a multistage process might be essential to the successful operation of a photobioreactor for astaxnthin production using H. pluvialis.