• 제목/요약/키워드: Green emission

검색결과 1,028건 처리시간 0.029초

New Phosphorescent Cyclometalated Iridium(III) Complexes with Diphenyl-1,3-oxazolic and 2-(3-Thienyl)pyridine Ligands for LED Applications

  • Kirsyuk, V. V.;Turgambaeva, A. E.;Shim, Jung-Jin;Rhee, Shi-Woo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.174-177
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    • 2003
  • We report four new phosphorescent iridium(III} complexes with 2,4-diphenyl-1,3-oxazole [$Ir(24dpo)_3$], 2,5-diphenyl-1,3-oxazole [$Ir(25dpo)_3$], 2-(3-thienyl) pyridine [$Ir(3thpyh)_3$] and [Ir(3thpy)2(acac)]. Three of them demonstrate good photophysical properties to be used as dopants to organic polymer matrix or to be used "as is" without a host matrix to fabricate OLEDs. Green and yellow light emission was observed for the photoluminescence: 569/525, 549/498 nm and 557,604/533 (solid state/$CH_2Cl_2$ solution) for $Ir(24dpo)_3$, $Ir(3thpyh)_3$ and $Ir(3thpyh)_2$acac respectively. Room temperature luminescent lifetimes are 2.5 and 1.8 ${\mu}s$ and quantum efficiencies 37 and 53%for $Ir(24dpo)_3$ and $Ir(3thpyh)_3$. The complexes are stable in air and sublimable at low pressure without considerable decomposition. Comparison of physicochemical properties of the reported iridium(III) cyclometalated compounds with that known from literature is carried out.

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$ZnGa_2O_4$:Mn,X 형광체의 부활성제에 따른 발광 효과 (Effect of Luminescence with Coactivator of $ZnGa_2O_4$:Mn,X phosphor)

  • 박용규;한정인;주성후
    • 한국전기전자재료학회논문지
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    • 제11권3호
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    • pp.242-247
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    • 1998
  • In this study, we have synthesized $ZnGa_2O_4$:Mn,X powder doped with Mn, MnO, $MnF_2$ and $MnCl_2$, low voltage green emitting phosphor, in vacuum atmosphere. From PL spectra, the intensity of the emission peak, the brightness with coactivator show that $ZnGa_2O_4$:Mn,Cl > $ZnGa_2O_4$:Mn,F > $ZnGa_2O_4$:Mn,O > $ZnGa_2O_4$:Mn. These improvement of the brightness are caused by the increase of the concentration of $Mn^{2+}$ ion. In case of $ZnGa_2O_4$:Mn,Cl and ZnGa$_2$O$_4$:Mn,F, the brightness is enhanced much more, which is owed to the decrease of defect of host material. For $ZnGa_2O_4$:Mn,Cl phosphor fabricated with optimized condition, the decay time becomes short from 30 ms of the $ZnGa_2O_4$:Mn and $ZnGa_2O_4$:Mn,O to 6 ms and the brightness of CL at 1 kV, 1 mA is 60 cd/$m^2$.

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녹색발광 β-SiAlON:Eu 세라믹 플레이트 형광체의 치밀화 소결 (The High Density Sintering of Green-emitting β-SiAlON:Eu Ceramic Plate Phosphor)

  • 박영조;이성훈;장욱경;윤창번;윤철수
    • 한국세라믹학회지
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    • 제47권6호
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    • pp.503-508
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    • 2010
  • $Eu^{2+}$-doped $\beta$-SiAlONs ($Si_{6-z}Al_zO_zN_{8-z}:Eu_y$) are recognized as promising phosphor materials to build an white LED for lighting application due to its excellent absorption/emission efficiency in the long wave length region. In this research, the fabrication of $\beta$-SiAlON:Eu plate phosphor by sintering was investigated with fixed Eu content(y) and varied composition of the host lattice(z). The addition of the activator $Eu_2O_3$ lead to enhanced densification by forming the transient liquid phase. The refinement of a composition by the calculated lattice parameter indicated that the measured composition of the fabricated specimens is nearly same to that of designed one. The single phase $\beta$-SiAlON:Eu plate with relative density of 96.4% was achieved by addition of 2 wt% CaO, which implies the possibility of full densification by adjusting the processing variables.

LTCC 기판을 이용한 PZT 압력 센서의 제작 및 특성 연구

  • 허원영;황현석;이태용;이경천;송준태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 춘계학술대회 논문집
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    • pp.13-13
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    • 2010
  • Piezoelectric sensors are extensively used to measure force because of their high sensitivity and low cost. however, the development of device with reduced size but with improved sensitivity is highly important. Low-temperature co-fired ceramic (LTCC) is one of promising materials for this application than a silicon substrate because it has very good electrical and mechanical properties as well as possibility of making various three dimensional (3D) structures. In this work, piezoelectric pressure sensors based on hybrid LTCC technology were presented. The LTCC diaphragms with thickness of $400\;{\mu}m$ were fabricated by laminating 12 green tapes which consist of alumina and glass particle in an organic binder. The piezoelectric sensing layer consists of PZT thin film deposited by RF magnetron sputtering method on between top and bottom Au electrodes. The PZT films deposited on LTCC diaphragms were successfully grown and were analyzed by using X-ray diffraction method (XRD) and field emission scanning electron microscope (FESEM).

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LTCC 기판위에 성장시킨 PZT 박막의 열처리시 $O_2$가 미치는 영향 (Effects of annealing under oxygen atmosphere of PZT thin films on LTCC substrates)

  • 이경천;허원영;황현석;이태용;이종덕;송준태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.205-205
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    • 2010
  • Recently, low temperature co-fired ceramic (LTCC) technology is widely used in sensors, actuators and microsystem fields because of its very good electrical and mechanical properties, high stability as well as possibility of making 3D micro structures. In this study, we investigated the effects of on $O_2$ annealing treatment on the electrical properties of Pb(ZrTi)$O_3$ (PZT) thin films deposited on LTCC substrate. The LTCC substrates with thickness of $400\;{\mu}m$ were fabricated by laminating 4 green tapes which consist of alumina and glass particle in an organic binder. The PZT thin films were deposited on Au / LTCC substrates by RF magnetron sputtering method. The change of the crystallization of the films were investigated under various atmosphere. The structural variation of the films were analyzed by using X-Ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) and secondary ion mass spectrometry (SIMS).

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The Effects of Drought on Forest and Forecast of Drought by Climate Change in Gangwon Region

  • Chae, Hee-Mun;Lee, Sang-Sin;Um, Gi-Jeung
    • Journal of Forest and Environmental Science
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    • 제28권2호
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    • pp.97-105
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    • 2012
  • A Gangwon region consisting of over 80% of forest area has industries that have been developed by utilizing its clean region image. However, the recent climate change has increased the forest disease & insect pest as well as the forest fire and the major cause is known to be the increase in the frequency of a drought occurrence. From the aspect of climate change, it can be said that drought and forest are important in every aspect of the adaptation and mitigation of climate change measure as they increase forest disease & insect pest that leads to desolation of usable forest resource. In addition, the increase of forest fire reduces resources that can absorb greenhouse gas, which leads to increase in green house emission. The purpose of this study is to provide a motive for concentrating administrative power for protecting forest in a Gangwon region by selecting a drought management needed local government through a drought forecast according to the climate change scenario of a Gangwon region.

유사경유 및 정상경유 미립화특성과 배출가스 환경성평가 (The Characteristics of Spray and Exhaust Emissions Environmental Assessment of Adulteration and Convention Diesel)

  • 이종태;문선희;김정수;김선문;박규태;임윤성
    • 한국분무공학회지
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    • 제18권2호
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    • pp.106-111
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    • 2013
  • Adulterations fuel have been using in the vehicle in these days. Because gasoline, diesel prices are rising every day. so people find more cheap price fuel. Adulterations fuel caused a serious air pollution problems. Adulteration fuel were made from waste engine oil, waste paint. According to Government regulations permit to be used recycle fuel(adulteration fuel) only in industrial boiler. Unburned fuel pollutants are effected to human health. In this paper, the hazardous air pollutants characteristics in the diesel vehicles according to adulterations of vehicle fuels were carried out in the NEDC test mode in chassis dynamometer. It is revealed that the all of the regulation pollutants (THC, NOx, CO and PM) emission in the adulterations of vehicle fuels was increased also the green house gas, $CO_2$ was increased. In the hazardous air pollutants characteristics, the VOCs(Volitile Organic Compounds) BTEX(Benzene, Toluene, Ethylbenzene, Xylene) emissions in the adulterations of vehicle fuels showed higher level than these in the diesel fuels.

갈륨인 단결정 성장으로 이룩한 적색 발광 다이오드의 제작 (The Fabrication of Gallium Phosphide Red Light Emitting Diode by Liquid Phase Epitaxy)

  • 김종국;민석기
    • 대한전자공학회논문지
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    • 제10권3호
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    • pp.1-9
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    • 1973
  • 파일롯트 램프와 숫자표시를 목적으로 국내에서 처음으로 화합물반도체인 갈륨 인을 사용해서 발광다이오드를 만들었다. 이같이 만든 다이오드는 밝고 선명한 붉은 빛을 냈으며 발광하는데 필요한 순방향 바이아스 전류는 5mA 이하였다. 다이오드의 p-n 접합면은 n형 GaP 단결정 기판에 liquid phase epitaxy방법으로 성장시켰고 이때의 Ga 용액의 온도는 약 1300°K정도를 유지했다. 이렇게 하여 제조된 p-n 접합체에 wire bonding으로 ohmic contact시켜 다이오드를 제조했다. 칼륨인 발광다이오드는 매우 적은 전류로 발광되는 장점과 성장 반웅시 질소를 불순물로 doping시키면 녹색으로 발광되는 장점을 갖고 있으므로 앞으로 양산화의 전망이 매우 밝다.

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RGB Light Emissions from ZnSe Based Nanocrystals: ZnSe, ZnSe:Cu, and ZnSe:Mn

  • Song, Byungkwan;Heo, Jeongho;Hwang, Cheong-Soo
    • Bulletin of the Korean Chemical Society
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    • 제35권12호
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    • pp.3601-3608
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    • 2014
  • RGB light emitting ZnSe based nanocrystals: ZnSe (blue), ZnSe:Cu (green) and ZnSe:Mn (red) were synthesized by capping the surface of the nanocrystals with oleic acid. The obtained nanocrystal powders were characterized by using XRD, HR-TEM, ICP-AES, FT-IR, and FT-Raman spectroscopies. The optical properties were also measured by UV/Vis and photoluminescence (PL) spectroscopies. The PL spectra showed broad emission peaks at 471 nm (ZnSe), 530 nm (ZnSe:Cu) and 665 nm (ZnSe:Mn), with relative PL efficiencies in the range of 0.7% to 5.1% compared to a reference organic dye standard. The measured average particle sizes from the HR-TEM images for those three nanocrystals were 4.5 nm on average, which were also supported well by the Debye-Scherrer calculations. The elemental compositions of the ZnSe based nanocrystals were determined by ICP-AES analyses. Finally, the drawn CIE diagram showed the color coordinates of (0.15, 0.16) for ZnSe, (0.22, 0.57) for ZnSe:Cu, and (0.62, 0.35) for ZnSe:Mn respectively, which were fairly well matched to that of the RGB color standards.

Key air pollution problems in the early 21st century

  • Brlmblecombe, Peter
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 International Symposium on Clean Environment
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    • pp.5-10
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    • 2003
  • This paper explores not only emerging scientific problems but also the difficulties communicating air quality issues into an increasingly sensitive the public and policy arena. The public understanding and trust in air pollution information and indices may be very different to the notions of validity or accuracy that are important for a scientist. We operate in a world where openness requires us to reveal both the difficulties and disagreements in our understanding of the polluted atmosphere. Yet this can be confusing and increase complexity in situations where clear political and social decisions are required. I am going to examine these issues, starting with questions of what substances we regard as pollutants and the difficulties of getting the correct balance of concern given the broadening the base of chemicals emitted to the environment. There are also questions of exposure particularly in terms of vulnerable populations, who may spend large amounts of time indoors, where air is rarely monitored. In contemporary society there are pollution problems that extend far beyond urban areas and we have to consider regional issues such as windblown dusts, smoke from forest fires along with issues of the emission of green house gases and ozone depleting substances. Finally I will discuss the issues of communicating with a concerned public and sceptical politicians and the troubling interface between technological and sociological control. Such complexity is often missed in a maze of seemingly stronger political and social needs.

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