• Title/Summary/Keyword: Green emission

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Effects of sodium dodecyl sulfate surfactant on up-conversion luminescence of Er3+/Yb3+-codoped NaLa(MoO4)2 nanocolloidal phosphor prepared by pulsed laser ablation in water

  • Kang, SukHyun;Jung, Kyung-Hwan;Kim, Kang Min;Kim, Won Rae;Han, HyukSu;Mhin, Sungwook;Son, Yong;Shim, Kwang Bo;Lee, Jung-Il;Ryu, Jeong Ho
    • Journal of Ceramic Processing Research
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    • v.20 no.2
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    • pp.158-163
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    • 2019
  • Er3+/Yb3+-codoped NaLa(MoO4)2 colloidal nanocrystals were synthesized by pulsed laser ablations in de-ionized water and sodium dodecyl sulfate (NaC12H25SO4, SDS) aqueous solution for up-conversion (UC) luminescence bio-labeling applications. The influences of the SDS molecules on the crystallinities, crystal morphologies, crystallite sizes, and UC luminescence properties of the prepared Er3+/Yb3+-codoped NaLa(MoO4)2 colloidal nanocrystals were investigated in detail. Under a 980-nm excitation, the Er3+/Yb3+-codoped nanocolloidal NaLa(MoO4)2 suspension exhibited a weak red emission near 670 nm and strong green UC emissions at 530 and 550 nm, corresponding to the intra 4f transitions of Er3+ (4F9/2, 2H11/2, 4S3/2) → Er3+ (4I15/2). When the SDS solution was used, a smaller average crystallite size, narrower size distribution, and enhanced UC luminescence were observed. These characteristics were attributed to the amphoteric SDS molecules attached to the positively charged Er3+/Yb3+-codoped NaLa(MoO4)2 colloidal nanocrystals, effectively occupying the oxygen defect on their surfaces. The Er3+/Yb3+-codoped nanocrystalline NaLa(MoO4)2 suspension prepared in the SDS solution exhibited a remarkably strong green emission visible to the naked eyes.

An Analysis of Energy Consumption and GHG Emission per Unit of Rail and Road Transportation (철도와 도로 수송부문의 에너지 소비 및 온실가스 배출 원단위 분석)

  • Kim, Byung-Kwan;Lee, Jin-Sun;Kim, Hyoun-Ku;Lee, Jae-Young
    • Journal of the Korean Society for Railway
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    • v.17 no.3
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    • pp.216-222
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    • 2014
  • In general, the rail transportation recognized as a better transportation mode than road transportation in terms of the environment. However, due to a lack of quantitative analysis based on Korean data, foreign cases for environmental advantages of the railway have often been cited in Korea. To address this issue, we estimated the energy consumption of passenger and freight transportation using certified activity data from Korea Railroad Statistics and the Electrical Work Report for railway and the Energy Consumption Survey for road. We estimated the Green House Gas emission of passenger and freight transportation on a Tier 1 level by applying the IPCC 2006 Guideline. Finally, we calculated the energy consumption unit and GHG emission unit to determine the environmental impact of rail and road transportation. We also compared the analyzed results of high-speed rail and auto as typical means of rail and road transportation.

Emission Estimation for Airports in Korea Using AEIC Program (AEIC 프로그램을 사용한 국내 공항 항공 온실가스 배출량 산정)

  • Joo, Hee-jin;Hwang, Ho-yon;Lim, Dongwook
    • Journal of Advanced Navigation Technology
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    • v.20 no.4
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    • pp.275-284
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    • 2016
  • The potential impact of aircraft emissions on the current and projected climate of our planet is one of the more important environmental issues facing the aviation industry. Increasing concern over the potential negative effects of greenhouse gas emissions has motivated aircraft emission estimation and prediction as one of the ways to reduce aircraft emissions and mitigate the impact of aviation on climate. We obtained airline flight schedules for all the airports in Korea that are included in OAG data. Fuel burn and emission index of LTO flight which contains take off, climb and approach under 3000ft and Non LTO flight which contains climb, cruise and descent over 3000ft for all the airports in Korea in 2005 were estimated and analysed for each condition using AEIC software which has been developed by MIT Lab for Aviation and Environment.

Synthesis, photoluminescence and thermal properties of laponite-X (X = Eu, Tb) phosphors (라포나이트-X(X = Eu, Tb) 형광체의 합성 및 열적 안정성과 발광특성 연구)

  • Kim, Pyo-Ra;Son, Dong-Min;Lee, Han-Na;Kim, You-Hyuk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.4
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    • pp.196-201
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    • 2009
  • In order to give emission functionality for laponite the laponite-X (x = Eu, Tb) phosphors were prepared by calcination of cryogels which were prepared through Na ion exchange reaction with Eu and Tb ions. Thermal stability and emission properties of new laponite-X (X = Eu, Tb) phosphors were investigated by X-ray diffractormeter and UV/VUV spectrofluorometer. The phosphors were stable around up to $600^{\circ}C$ and new crystalline phases were observed at $700^{\circ}C$. Red and green emissions of phosphors under UV/VUV excitation were also identified at $300^{\circ}C$ and $500^{\circ}C$ as emission peaks of $Eu^{3+}$ and $Tb^{3+}$, respectively.

Climate Change Policy and Carbon Trading Scheme and in Japan: Features and Lessons (일본의 기후변화 정책과 배출권거래제도: 특징과 시사점)

  • Lee, Soo-Cheol
    • Journal of Environmental Policy
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    • v.9 no.4
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    • pp.77-102
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    • 2010
  • The purpose of this paper is to analyze the Japanese emission trading system and climate change policy thereby contributing to the instituting of similar systems that will be viable for the Korean context. In applying such analyses, it is important to include a careful consideration of cost sharing between stakeholders and firms, an enhancement of the trust worthiness of data concerning greenhouse gases, and an examination of related infrastructure such as emissions authentication agencies and their development. Moreover, it is important to minimize the outflow of domestic resources such as offset credit, green electricity certification system, and ecopoint, making compatible economic growth and carbon reduction thereby encouraging the production and dissemination of 'Environmental Value' as well as connecting 'Environmental Value' to a emission trading system.

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Luminescent Characteristics of $Mg_xZn_{1-x}SiN_2$ Based Phosphors for Thin Film Electroluminescent Device Applications ($Mg_xZn_{1-x}SiN_2$를 모체로 한 박막 전계발광소자용 형광체의 발광특성)

  • 이순석;임성규
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.2
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    • pp.27-37
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    • 1997
  • Photoluminescent and cathodoluminescent charcteristics of inorganic luminescent materials were investigated ot develop possible phosphors for thin film electroluminescent (TFEL) device applications. Mg, Zn, and Photoluminescent and cathodoluminescent charcteristics of inorganic luminescent materials were investigated ot develop possible phosphors for thin film electroluminescent (TFEL) device applications. Mg, Zn, and $Si_3N_4$ powders were used to synthesize $(Mg_xZn_{1-x})SiN_2$ host materials. $Tb_4O_7$ and $Eu_2O_3$ powdrs were added as luminescent centers. Very sharp emission spectra of $Tb^{3+}$ ions were observed from $Mg._5Zn._5SiN_2:Tb$ sampels sintered at $1400^{\circ}C$ for an hour and the maximum intensity of emission spectra occured at wavelength of 550nm (green light). Synthetic conditions of $(Mg_xZn_{1-x})SiN_2:Eu$ phosphors were optimized for the hghest luminescence. The Eu concentrations were varied from 0.2% to 1.6%. Before firing, the powders were mixed using ballmills, methanol, acetone, or D.I. water. The Mg/Zn ratio also were varied from x=0.3 to x=0.7. The maximum PL intensity was obtained from a sample with 1.2% Eu concentration and the powder was mixed with methanol and dried before firing. The maximum intensity of the emission spectra occurred t the wavelength of 470nm(blue light). TFEL devices fabricated by using sputter deposition of $(Mg._3Zn._7)SiN_2:Eu$ phosphor layer showed yellowish white emission at the phosphor field of 2MV/cm.

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The Evaluation of GHG Emissions in Railroad Construction Sector (철도건설의 온실가스 배출량 산정평가)

  • Lee, Jae-Young;Jung, Woo-Sung;Hwang, In-Hwan;Kim, Yong-Ki
    • Journal of the Korean Society for Railway
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    • v.14 no.3
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    • pp.271-275
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    • 2011
  • According to governmental policies for green growth, the increase in the traffic volume of railroad is a representative method to reduce total greenhouse gas (GHG) emitted from transport. Comprehensive assessment for the GHG emission of railroad has been studied to compare the difference of transport modes just in the operating step excluded the construction step. The purpose of this study was to evaluate GHG emissions in railroad construction sector. The targets were some construction works for civil, track, building, and electric system in A line. The GHG emission source of constructing railroad infrastructure was mainly the energy consumption of heavy equipments. As a result, the civil construction sector showed more than 96% of total GHG emissions and its specific GHG emission was 2.191 ton $CO_2e/m$. Also, the specific GHG emissions of civil construction works were of the order: earthworks > tunnels > bridges > station. In future, it will be required to calculate the overall GHG emission of railroad through life cycle approaches including operation, maintenance and disposal step.

3D-based Earthwork Planning and CO2 Emission Estimation for Automated Earthworks (자동화 토공을 위한 3D 토량배분과 탄소발생량 추정)

  • Kim, Sung-Keun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.3
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    • pp.1191-1202
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    • 2013
  • The former researches on earthwork automation were mainly focused on GPS and sensor application, environment modelling, equipment path planning, work information management, and remote control etc. Recently, reducing $CO_2$ emission becomes one of main focuses for an automation research. In the case of earthwork operations, many kinds of construction machines or robots are involved, which can cause high level of $CO_2$ in a construction site. An effective earthwork plan and construction machine operation can both increase productivity and safety and decrease $CO_2$ emission level. In this research, some automation concepts for green earthworks are suggested such as a 3D construction site model, a 3D earthwork distribution based on two different earthwork methods, and an earthwork package construction method. A excel-based simulator is developed to generate the 3D earthwork distribution and to estimate the level of $CO_2$ emission for the given earthwork.

"Dust, Ice, and Gas In Time" (DIGIT) Herschel Observations of GSS30-IRS1 in Ophiuchus

  • Je, Hyerin;Lee, Jeong-Eun;Green, Joel D.;Evans, Neal J. II
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.1
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    • pp.63.2-63.2
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    • 2014
  • As a part of the "Dust, Ice, and Gas In Time" (DIGIT) key program on Herschel, we observed GSS30-IRS1, a Class I protostar located in Ophiuchus (d =125 pc), with Herschel/Photodetector Array Camera and Spectrometer (PACS). More than 70 lines were detected within a wavelength range from 50 ${\mu}m$ to 200 ${\mu}m$: CO lines from J = 14-13 to 41-40, several $H_2O$ lines of Eup = 100 K to 1500 K, 16 transitions of OH rotational lines, and two atomic [O I] lines at 63 and 145 ${\mu}m$. The [C II] line, known as a tracer of externally heated gas by the interstellar radiation field, is also detected at 158 ${\mu}m$. All lines, except [O I] and [C II], are detected only at the central spaxel of $9^{\prime\prime}.4{\times}9^{\prime\prime}.4$. The [O I] emission is extended along a NE-SW orientation, which is consistent with the known outflow direction, while the [C II] line is detected over all spaxels. One possible explanation of the detection of the [C II] line and no correlation of its spatial distribution with any other molecular emission is the existence of the enhanced ISRF nearby GSS30-IRS1. One interesting feature of GSS30-IRS1 is that the continuum emission is extended beyond the point-spread function (PSF), unlike the molecular line emission, indicative of significant external heating. The best-fit continuum model of GSS30-IRS1 with the physical structure including flared disk, envelope, and outflow shows that the internal luminosity is 11 $L_{\odot}$, and the region is also externally heated by a radiation field enhanced by a factor of 25 compared to the local standard interstellar field.

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Performance Analysis of Low Power Paging Scheme using user's Property (사용자의 개별적 특성을 활용한 저전력 페이징 방안의 제안 및 분석)

  • Jeong, Ji-Won;Kim, Jeong-Ho
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.47 no.5
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    • pp.1-8
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    • 2010
  • Recently subscribers in mobile communication services increase gradually, and the new multifunctional portable terminals can provide various functionalities. However this trend may not be desirable in Green IT respect because the emission of carbon dioxides emitted during operations of base station and mobile stations can cause significant effect on the emissions of carbon dioxides. In this paper the power saving scheme which can adjust slot index while the system is in a paging phase has been proposed and its performance has been evaluated. The slot cycle index can be adjusted according to individual user's property, its effect on the system performance has been investigated. In order to mitigate its adverse effect, power ramping scheme is considered and evaluated thereafter.