• Title/Summary/Keyword: Green Materials

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UVU characteristics of $YBO_{3}$:Tb green phosphor prepared by spray pyrolysis

  • Jung, Kyeong-Youl;Kim, Eun-Joung;Kang, Yun-Chan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1001-1004
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    • 2003
  • We applied the spray pyrolysis technique to prepare fine $YBO_{3}$:Tb particles with high photoluminescence, which could be used in the plasma display device as a green phosphor. Several preparation conditions were investigated in order to tail the vacuum ultraviolet characteristics of $YBO_{3}$:Tb particles when they were prepared by the spray pyrolysis. As a result, the optimized $YBO_{3}$:Tb particles showed the high photoluminescence intensity as well as fine size in comparison with the commercial one.

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Synthesis of Blue-green Naphthoxy, Chloro Derivative Zinc-phthalocyanines with LCD Requirements

  • Kumar, Rangaraju Satish;Min, Kyeong Su;Son, Young-A
    • Textile Coloration and Finishing
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    • v.30 no.3
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    • pp.159-167
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    • 2018
  • Here we designed and synthesized new zinc phthalocyanines and structures were fully confirmed by spectral and elemental analysis. All phthalocyanines have a very good solubility in industrial solvents like chloroform, dichloromethane, dimethyl sulfoxide, N,N-dimethyl formamide, propylene glycol monomethyl ether acetate (PGMEA), acetone, tetrahydrofuran and acetonitrile. UV-Visible absorption and transmittance in PGMEA showed that these dyes have suitable spectral properties for LCD color filters. By Triton X surfactant study, we confirmed that these dyes are not showing any aggregation in PGMEA. We dissolved the all phthalocyanines in LCD fabricating solvent (PGMEA), and all phthalocyanines showed more than 8 wt% of solubility. Finally, all of these results concluded that PCK1, PCK2 and PCK3 are fit for LCD green color filter.

Effect of viscosity of paste and speed of printing on green transparent dielectric during screen printing process in PDP

  • Cha, Gun-Young;Huh, Jeung-Soo;Park, Jun-Hyun;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.1085-1087
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    • 2002
  • To have cost down and get improved image quality and performance of plasma display panel, several factors have been developed including development of low price material and improvement in production for PDP front plate. In this work, viscosity and surface characteristics of transparent dielectric were investigated to find the optimum and low price materials fabrication condition of transparent dielectric paste. It was found that uniformity and transmissivity of green and fired dielectrics had some relationship with the kinds and content of binder, and solvent as well.

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Modified-Polyol Synthesis of Nanocrystalline $LaPO_4:Ce^{3+}$, $Tb^{3+}$ Phosphors for Transparent Display

  • Song, Woo-Seuk;Byun, Ho-June;Yang, Hee-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1290-1292
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    • 2009
  • Modified-polyol protocol was utilized for synthesis of green-emitting ($^5D_4-^7F_j$ transitions of $Tb^{3+}$ ion) nanocrystalline $LaPO_4:Ce^{3+}$, $Tb^{3+}$ phosphors. Experimental parameters including chemical composition and annealing temperature were optimized to produce highly efficient, uniformly sized nanophosphors. Spin-deposited layer of $LaPO_4:Ce^{3+}$, $Tb^{3+}$ nanophosphors on glass substrate exhibited a transmittance of more than 80 %, indicating their efficacy for transparent display.

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Properties of compacted iron powder core coated with organic materials (코팅제 및 코팅 함량에 따른 철 분말 성형체의 특성)

  • Min, Bok-Ki;Kim, In-Sung;Kim, Jong-Ryung;Choi, Sung-Jo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.264-267
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    • 2005
  • Soft magnetic iron powders have been coated with polyester or phenol resin. And the coated powder (soft magnetic composite) have been pressed into ring type core over the pressure of 870 MPa. Green density, magnetic flux density, permeability, core loss of the samples were measured to look at the effect of the coating materials and the amount of them. Green density is increased with the amount of coating materials and shows the maximum value, 6.5 $g/cm^3$ at 5 w/o, but decreased over it. And lowest value of the core loss is showed for the 5 w/o coated samples.

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Adsorptive Removal of Hazardous Organics from Water with Metal-organic Frameworks (금속-유기 골격체(Metal-organic Frameworks)를 활용한 물로부터의 유해 유기물의 흡착 제거)

  • Seo, Pill Won;Song, Ji Yoon;Jhung, Sung Hwa
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.358-365
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    • 2016
  • Removing hazardous materials from water resources is very important for efficient utilization of the resources, and adsorptive removal is regarded as a competitive technology when good adsorbents with high capacity/selectivity are available. Metal-organic framework (MOF), composed of both organic and inorganic (metallic) species, have been tried for various adsorptions because of huge surface area/pore volume, well-defined pore structure, and facile functionalization. In this review, we summarized technologies on adsorptive removal of hazardous organics from water mainly using MOFs as adsorbents. Instead of reporting high adsorption capacity or rate, we summarized mechanisms of interaction between adsorbates (organics) and adsorbents (MOFs) and methods to modify or functionalize MOFs for effective adsorptions. We expect for readers of this review to understand needed characteristics of adsorbents for the adsorptive removal, functionalization of MOFs for effective adsorption and so on. Moreover, they might have an idea on storage and delivery of organics via understanding of the mechanism of adsorption and interaction.

The Properties of Passivation Films on Al2O3/SiNX Stack Layer in Crystalline Silicon Solar Cells (결정질 실리콘 태양전지의 Al2O3/SiNX 패시베이션 특성 분석)

  • Hyun, Ji Yeon;Song, In Seol;Kim, Jae Eun;Bae, Soohyun;Kang, Yoonmook;Lee, Hae-Seok;Kim, Donghwan
    • Current Photovoltaic Research
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    • v.5 no.2
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    • pp.63-67
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    • 2017
  • Aluminum oxide ($Al_2O_3$) film deposited by atomic layer deposition (ALD) is known to supply excellent surface passivation properties on crystalline Si surface. The quality of passivation layer is important for high-efficiency silicon solar cell. double-layer structures have many advantages over single-layer materials. $Al_2O_3/SiN_X$ passivation stacks have been widely adopted for high- efficiency silicon solar cells. The first layer, $Al_2O_3$, passivates the surface, while $SiN_X$ acts as a hydrogen source that saturates silicon dangling bonds during annealing treatment. We explored the properties on passivation film of $Al_2O_3/SiN_X$ stack layer with changing the conditions. For the post annealing temperature, it was found that $500^{\circ}C$ is the most suitable temperature to improvement surface passivation.

Microalga Scenedesmus sp.: A Potential Low-Cost Green Machine for Silver Nanoparticle Synthesis

  • Jena, Jayashree;Pradhan, Nilotpala;Nayak, Rati Ranjan;Dash, Bishnu P.;Sukla, Lala Behari;Panda, Prasanna K.;Mishra, Barada K.
    • Journal of Microbiology and Biotechnology
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    • v.24 no.4
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    • pp.522-533
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    • 2014
  • Bionanotechnology has revolutionized nanomaterial synthesis by providing a green synthetic platform using biological systems. Among such biological systems, microalgae have tremendous potential to take up metal ions and produce nanoparticles by a detoxification process. The present study explores the intracellular and extracellular biogenic syntheses of silver nanoparticles (SNPs) using the unicellular green microalga Scenedesmus sp. Biosynthesized SNPs were characterized by AAS, UV-Vis spectroscopy, TEM, XRD, FTIR, DLS, and TGA studies and finally checked for antibacterial activity. Intracellular nanoparticle biosynthesis was initiated by a high rate of $Ag^+$ ion accumulation in the microalgal biomass and subsequent formation of spherical crystalline SNPs (average size, 15-20 nm) due to the biochemical reduction of $Ag^+$ ions. The synthesized nanoparticles were intracellular, as confirmed by the UV-Vis spectra of the outside medium. Furthermore, extracellular synthesis using boiled extract showed the formation of well scattered, highly stable, spherical SNPs with an average size of 5-10 nm. The size and morphology of the nanoparticles were confirmed by TEM. The crystalline nature of the SNPs was evident from the diffraction peaks of XRD and bright circular ring pattern of SAED. FTIR and UV-Vis spectra showed that biomolecules, proteins and peptides, are mainly responsible for the formation and stabilization of SNPs. Furthermore, the synthesized nanoparticles exhibited high antimicrobial activity against pathogenic gram-negative and gram-positive bacteria. Use of such a microalgal system provides a simple, cost-effective alternative template for the biosynthesis of nanomaterials in a large-scale system that could be of great use in biomedical applications.

An Effect of Fe2O3 Additive on a Seebeck Coefficient and a Power Factor for SmCoO3 Perovskite System (SmCoO3 페롭스카이트 계 열전소재에서 Fe2O3 첨가제가 출력인자에 미치는 영향)

  • Jung, Kwang-Hee;Choi, Soon-Mok;Seo, Won-Seon;Park, Hyung-Ho
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.457-460
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    • 2010
  • $SmCoO_3$ system was investigated for their application to themoelectric materials. All specimens showed p-type semiconducting behavior and their electrical conductivity ($\sigma$), Seebeck coefficient (S) and power factor were measured at high temperature. And the effect of dopant ions on their thermoelectrical properties were also investigated. $Fe^{3+}$ ion doped into $Co^{3+}$ site enhanced the Seebeck coefficient and decreased the electrical conductivity simultaneously. The maximum Seebeck coefficient value for 60% doping case reached to 780 ${\mu}V$/K at $240^{\circ}C$. However $Fe^{3+}$ doped system cause an negative effect on power factor value. In case of the pure phase, the maximum Seebeck coefficient value reached to 290 ${\mu}V$/K at $240^{\circ}C$ and the maximum electrical conductivity was obtained 748 1/(ohm$\times$cm) at $960^{\circ}C$. As a result, the maximum power factor was obtained $1.49\times10^{-4}$ W/$mK^2$ at $550^{\circ}C$.

Green Synthesis of Multifunctional Carbon Nanodots and Their Applications as a Smart Nanothermometer and Cr(VI) Ions Sensor

  • Li, Lu;Shao, Congying;Wu, Qian;Wang, Yunjian;Liu, Mingzhu
    • Nano
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    • v.13 no.12
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    • pp.1850147.1-1850147.14
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    • 2018
  • In this work, water-soluble and blue-emitting carbon nanodots (CDs) were synthesized from apple peels for the first time via one-step hydrothermal method. The synthetic route is facile, green, economical and viable. The as-prepared CDs were characterized thoroughly by transmission electron microscopy (TEM), X-ray diffraction (XRD), Raman, Fourier transform infrared (FT-IR), X-ray photoelectron (XPS), fluorescence and UV-Vis absorption spectroscopy in terms of their morphology, surface functional groups and optical properties. The results show that these CDs possessed ultrasmall size, good dispersivity, and high tolerance to pH, ionic strength and continuous UV irradiation. Significantly, the CDs had fast and reversible response towards temperature, and the accurate linear relationship between fluorescence intensity and temperature was used to design a novel nanothermometer in a broad temperature range from 5 to $65^{\circ}C$ facilely. In addition, the fluorescence intensity of CDs was observed to be quenched immediately by Cr(VI) ions based on the inner filter effect. A low-cost Cr(VI) ions sensor was proposed employing CDs as fluorescent probe, and it displayed a wide linear range from 0.5 to $200{\mu}M$ with a detection limit of $0.73{\mu}M$. The practicability of the developed Cr(VI) sensor for real water sample assay was also validated with satisfactory recoveries.