• Title/Summary/Keyword: Green Materials

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A Study on Electrical Characteristics of a Capacitive Pressure Sensor Element to Measure the Pressure of Refrigerant of Air-Conditioner (에어컨 냉매압 측정용 정전용량형 압력센서 소자의 전기적 특성 연구)

  • Choi, Ga-Hyun;Chung, Woo-Young;Choi, Jung-Woon;Kim, Si-Dong;Min, Joon-Won
    • Journal of Sensor Science and Technology
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    • v.24 no.3
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    • pp.208-213
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    • 2015
  • The purpose of this study is to optimize the design of a capacitive pressure sensor element using the simulation of electrical characteristics. The simulation of the ceramic sensor diaphragm ($Al_2O_3$) was performed by permitting pressure to change the curvature of the diaphragm. The pressure capacitance ($C_P$) was increased from 19.63 pF to 15.26 pF by applying pressure because the distance between the electrodes has been changed from $30{\mu}m$ to $15{\mu}m$. When the thickness of the diaphragm was changed to 0.46~0.52 mm, a larger capacitance change showed in accordance with the reduced thickness, which means an increase of sensitivity. However, considering the viewpoint of the signal linearity, it was selected for the optimum thickness of the diaphragm to 0.50 mm. The designed sensor element based on simulated results was tested to measure the output characteristics. Comparing of simulated and measured results, there was a margin of error of approximately 2%.

Effect of Multi-Sized Powder Mixture on Solid Casting and Sintering of Alumina

  • Cho, Kyeong-Sik;Lee, Hyun-Kwuon;Min, Jae-Hong
    • Journal of the Korean Ceramic Society
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    • v.55 no.4
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    • pp.352-357
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    • 2018
  • The slip casting process is widely used to make green bodies from ceramic slips into dense compacts with homogeneous microstructure. However, stress may be generated inside the green body during drying, and can lead to cracking and bending during sintering. When starting from the spherical powders with mono-size distribution to make the close packed body, interstitial voids on octahedral and tetrahedral sites are formed. In this research, experiments were carried out with powders of three size types (host powder (H), octahedral void filling powder (O) and tetrahedral void filling powder (T)) controlled for average particle size by milling from two commercial alumina powders. Slips were prepared using three different powder batches from H only, H+O or H+O+T mixed powders. After manufacturing green compacts by solid-casting, compacts were dried at constant temperature and humidity and sintered at $1650^{\circ}C$. Alumina samples fabricated from the multi-sized powder mixture had improved compacted and sintered densities.

Multi-step Metals Additive Manufacturing Technologies

  • Oh, Ji-Won;Park, Jinsu;Choi, Hanshin
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.256-267
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    • 2020
  • Metal additive manufacturing (AM) technologies are classified into two groups according to the consolidation mechanisms and densification degrees of the as-built parts. Densified parts are obtained via a single-step process such as powder bed fusion, directed energy deposition, and sheet lamination AM technologies. Conversely, green bodies are consolidated with the aid of binder phases in multi-step processes such as binder jetting and material extrusion AM. Green-body part shapes are sustained by binder phases, which are removed for the debinding process. Chemical and/or thermal debinding processes are usually devised to enhance debinding kinetics. The pathways to final densification of the green parts are sintering and/or molten metal infiltration. With respect to innovation types, the multi-step metal AM process allows conventional powder metallurgy manufacturing to be innovated continuously. Eliminating cost/time-consuming molds, enlarged 3D design freedom, and wide material selectivity create opportunities for the industrial adoption of multi-step AM technologies. In addition, knowledge of powders and powder metallurgy fuel advances of multi-step AM technologies. In the present study, multi-step AM technologies are briefly introduced from the viewpoint of the entire manufacturing lifecycle.

Optimization of Barium Titanate Slip for Tape Casting Using Design of Experiments

  • Kwon, Sung-Wook;Darsono, Nono;Yoon, Dang-Hyok
    • Journal of the Korean Ceramic Society
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    • v.43 no.9 s.292
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    • pp.519-526
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    • 2006
  • A full-factorial design of experiments with three input factors and two levels for each factor including center points was utilized for the preparation and characterization of twelve types of $BaTiO_3$ slips for tape casting. Ceramic powders with different particle sizes, different milling methods such as high energy milling and conventional ball milling, and two types of dispersant with different polymeric species were chosen as input factors in order to investigate their effects on slip and on green tape properties. Tape casting, a small rectangular-shaped K-square preparation, characterization and quantitative data analysis using statistical software were followed. Ceramic powder was the most significant among three input factors for the output responses of slip viscosity and green tape density, showing more favorable results with large particles than with very fine ones. In addition, high energy milling for only 30 min was more efficient than 24h of conventional ball milling in terms of powder dispersion and milling. The optimum condition based on the experimental results was a slip exposed to high energy milling with large ceramic particles along with a methylethyl acetate dispersant.

$EU^{2+}$ Activated Green Phosphor $Ba_{2}CaMgSi_{2}O_{8}:Eu^{2+}$

  • Kim, Jeong-Seog;Piao, Ji-Zhe;Choi, Jin-Ho;Cheon, Chae-Il;Park, Joo-Suk
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2004.05a
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    • pp.97-100
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    • 2004
  • We report $EU^{2+}$ activated green phosphor $Ba_{2}CaMgSi_{2}O_{8}:Eu^{2+}$. The phosphor absorbs ultroviolet radation and emits a green visible light. The phosphors were synthesized by conventional solid state reaction method. The high purity $BaCO_3$, $CaCO_3$, MgO, $SiO_2$, $Eu_{2}O_{3}$ were used as raw materials. The raw materials were mixed thoroughly with an appropriate amount of ethanol in an agate mortar and then dried at $90^{\circ}C$ for 2 hours. The mixture was sintered at $900^{\circ}C$ for 2 hours and reheated at the mild reducing atmosphere 5% $H_2$ gas mixed with 95% $N_2$ gas at about $900^{\circ}C$ to $1200^{\circ}C$ for 2 hours. The photoluminescence spectra of the phosphor powders were measured by a fluorescent spectrophotometer. The crystal structure of phosphor powders were investigated by X -ray diffractometer.

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A Study on Development of High Strength Al-Zn Based Alloy for Die Casting II: Evaluation of Fluidity and Gravity Casting (고강도 Al-Zn기 다이캐스팅 합금개발에 관한 연구 II: 중력주조, 유동성평가)

  • Shin, Sang-Soo;Lim, Young-Hoon;Kim, Eok-Soo;Lim, Kyung-Mook
    • Korean Journal of Metals and Materials
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    • v.50 no.7
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    • pp.531-538
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    • 2012
  • In this study, we evaluated the fluidity of the Al-Zn based alloys which exhibit excellent mechanical properties. We conducted computer simulations of fluid flow using the results of DSC, DTA analysis and Java-based Materials Properties software (J. Mat. Pro). Such computer simulations were then compared with the results obtained from experimental observations. The computer simulation results and the experimental results were very similar in fluidity length. It was found that the fluidity length of Al-Zn alloys is improved by increasing the Zn content while decreasing the solidus temperature of an alloy. In addition, we elucidate the effect of Zn addition on variations in different mechanical properties and the microstructure characteristics of (Al-xZn3Cu0.4Si0.3Fe) x=20, 30, 40, and 45 wt% alloys fabricated by gravity casting.

Mechanically Workable High-strength Cu-Zr Composite (소성가공이 가능한 고강도 Cu-Zr 복합재료)

  • Shin, Sang-Soo;Lim, Kyung-Mook;Kim, Eok-Soo;Lee, Jae-Chul
    • Korean Journal of Metals and Materials
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    • v.50 no.4
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    • pp.293-299
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    • 2012
  • Ultrafine-grained or nanostructured alloys usually lack the strain hardening capability needed to sustain uniform tensile deformation under high stresses. To circumvent this problem, we fabricated the Cu-based composite reinforced with the 3-dimensionally interconnected $Cu_5Zr$ phase using the combined technique of rapid quenching and subsequent hot-rolling. The alloy exhibited a tensile ductility of ~2.5% together with a strength of 1.57 GPa, which exceeds the values of most commercially available Cu-Be alloys. In this study, we elucidated the structural origin of the high strength and tensile ductility of the developed alloy by examining the thermal stability of the $Cu_5Zr$ reinforcing phase and the energy (work) absorption capability of the Cu matrix.

Effect of Area Ratio on Galvanic Corrosion Between Metallic Materials and GECM in 3.5% NaCl Solution (3.5% NaCl 수용액 중에서의 금속과 GECM의 갈바닉 부식에 미치는 면적비의 영향)

  • Kim, Y.S.;Lim, H.K.;Sohn, Y.I.;Yoo, Y.R.;Chang, H.Y.
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.39-47
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    • 2010
  • Galvanic coupling between GECM(graphite epoxy composite material) and metallic materials can facilitate corrosion of metals and alloys because GECM is noble and electrically conductive. Galvanic corrosion is affected by many factors including metallic materials, area ratio, surface condition, and corrosivity. This work aims to evaluate the effect of area ratio on galvanic corrosion between GECM and several metals. In the case of glavanic coupling of carbon steel and Al to GECM, corrosion rate increased with increasing area ratio. Corrosion rate of sensitized STS 316S stainless steel decreased a little at an area ratio 1:1 but increased at an area ratio 30:1. It is considered to be due to that area ratio affects galvanic corrosion more in less corrosion resistant alloys. However, in case of STS 316 and Ti, galvanic coupling reduces corrosion rate by the formation of passive film.

Influences of Anodizing and Thermal Oxidation on the Galvanic Corrosion between Aluminium and Titanium and GECM (GECM과 Al 및 Ti 간의 갈바닉 부식에 미치는 양극산화 및 열산화의 영향)

  • Kim, Young-Sik;Lim, Hyun-Kwon;Sohn, Young-Il;Yoo, Young-Ran;Chang, Hyun-Young
    • Korean Journal of Metals and Materials
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    • v.48 no.6
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    • pp.514-522
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    • 2010
  • Graphite epoxy composite material (GECM) shows high specific strength and its application in the aerospace industry is gradually increasing. However, its application would induce galvanic corrosion between GECM and metallic materials. This work focused on the effects of anodizing and thermal oxidation on galvanic corrosion in a 3.5% NaCl solution between GECM and aluminium and titanium. In the case of anodized aluminium, galvanic corrosion resistance to the GECM was greatly improved by the anodizing treatment regardless of area ratio. In the case of anodized titanium, the anodizing by a formation voltage of 50V increased corrosion resistance of titanium in galvanic tests. Thermal oxidation of titanium also improved corrosion resistance of Ti to GECM.

Microstructure Evolution and Dielectric Characteristics of CaCu3Ti4O12 Ceramics with Sn-Substitution

  • Kim, Cheong-Han;Oh, Kyung-Sik;Paek, Yeong-Kyeun
    • Journal of the Korean Ceramic Society
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    • v.50 no.1
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    • pp.87-91
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    • 2013
  • The doping effect of Sn on the microstructure evolution and dielectric properties was studied in $CaCu_3Ti_{4-x}Sn_xO_{12}$ polycrystals. Samples were produced by a conventional solid-state reaction method. Sintering was carried out at $1115^{\circ}C$ for 2-16 h in air. The dielectric constant and loss were examined at room temperature over a frequency range between $10^2$ and $10^6$ Hz. The microstructure was found to evolve into three stages. Addition of $SnO_2$ led to an increase in density and advanced formation of abnormal grains. The formation of coarse grains with a reduced thickness of the boundary brought about an enhanced dielectric constant and a lower dielectric loss below ~1 kHz. EDS data showed the Cu-rich phase along the grain boundary, which should contribute to the improved dielectric constant according to the internal barrier layer capacitor model. After all, $SnO_2$ was an effective dopant to elevate the dielectric characteristics of $CaCu_3Ti_{4-x}Sn_xO_{12}$ polycrystals as a promoter for abnormal grain growth.