• 제목/요약/키워드: Green Materials

검색결과 2,316건 처리시간 0.03초

Gel-Casting으로 제조한 알루미나 성형체의 건조와 미세구조 (Microstructures and Drying of the Alumina Green Body by the Gel-Casting Method)

  • 오창준;이홍림
    • 한국세라믹학회지
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    • 제31권12호
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    • pp.1467-1474
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    • 1994
  • The effects of the dispersion, drying, and binder burning-out on the green-microstructures of gelcasted alumina were studied. The slip consisting of 55 vol% alumina powder and 5 wt% organic materials was well-dispersed by adding 0.28 wt% polyelectrolyte polymer. Green bodies were dried at >85% relative humidity at room temperature. Green-microstructures were observed to be depended on the heating rate during binder burnout. Constant drying rate was not observed in drying process of gelcasted alumina. Sintered body showed its relative density higher than 99% when it was sintered at 1$600^{\circ}C$ for 2 hours.

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Property improvement of natural fiber-reinforced green composites by water treatment

  • Cho, Dong-Hwan;Seo, Jeong-Min;Lee, Hyun-Seok;Cho, Chae-Wook;Han, Seong-Ok;Park, Won-Ho
    • Advanced Composite Materials
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    • 제16권4호
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    • pp.299-314
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    • 2007
  • In the present study, natural fibers (jute, kenaf and henequen) reinforced thermoplastic (poly(lactic acid) and polypropylene) and thermosetting (unsaturated polyester) matrix composites were well fabricated by a compression molding technique using all chopped natural fibers of about 10 mm long, respectively. Prior to green composite fabrication, natural fiber bundles were surface-treated with tap water by static soaking and dynamic ultrasonication methods, respectively. The interfacial shear strength, flexural properties, and dynamic mechanical properties of each green composite system were investigated by means of single fiber microbonding test, 3-point flexural test, and dynamic mechanical analysis, respectively. The result indicated that the properties of the polymeric resins were significantly improved by incorporating the natural fibers into the resin matrix and also the properties of untreated green composites were further improved by the water treatment done to the natural fibers used. Also, the property improvement of natural fiber-reinforced green composites strongly depended on the treatment method. The interfacial and mechanical results agreed with each other.

건조법, 파쇄법, 성형법에 따른 인공경량골재의 파쇄율 비교 (A comparison of fracture rate of artificial light-weight aggregates by various drying, breaking, and forming methods)

  • 박지윤;김유택;이기강;강승구;김정환
    • 한국결정성장학회지
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    • 제15권1호
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    • pp.39-44
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    • 2005
  • 적점토 60 wt%, 석탄회 20 wt%, 석분오니 20 wt%를 혼합하여 제작한 sheet 형태의 소지에 인덴트(indent)를 주고 건조방법, 파쇄방법, 성형방법을 변화시켜 1~5 mm 골재의 파쇄율을 알아보았다. 소지를 건조할 때 실내와 실외에서의 자연건조, 건조기건조, 마이크로웨이브(microwave)건조, 급속건조로 분류하여 비교실험 하였고, 파쇄방법은 볼밀 Ⅰ 파쇄, 볼밀 Ⅱ 파쇄, 낙하파쇄, 기계식 파쇄(롤러밀사용)법으로 변화를 주었다. 성형방법은 인덴트의 간격과 깊이를 변화시키면서 동시에 소지의 두께를 변화시켜 실험하였다. 건조방법에 의한 비교실험 결과는 210초까지 건조시킨 마이크로웨이브건조가 약 42%로. 파쇄방법에서는 볼밀 Ⅱ 파쇄법이 약 65 %로 가장 높은 파쇄율을 보였고, 성형방법에서는 인덴트의 깊이가 깊어질수록(3mm의 소지에서만), 소지의 두께가 증가할수록 크기가 Ф=5 mm보다 큰 골재의 수율은 감소했고 Ф=5 mm 이하인 골재의 수율은 증가했다. 각각의 실험 후 파쇄 된 1~5mm 골재의 aspect ratio를 비교해본 결과 3mm 두께의 소지를 급속건조법에 의해 건조하고 볼밀 Ⅱ법을 이용해 파쇄 한 경우 가장 균일한 골재의 모양으로 파쇄 되었음을 알 수 있었다.

Synthesis of the sulfide phosphors and white light generation based on InGaN chip

  • Kim, Kyung-Nam;Kim, Jae-Myung;Choi, Kyoung-Jae;Park, Joung-Kyu;Kim, Chang-Hae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2004년도 Asia Display / IMID 04
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    • pp.679-682
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    • 2004
  • $SrGa_2S_4$:Eu green phosphor and SrS:Eu red phosphor have been synthesized by co-precipitation method, respectively. Two sulfide phosphors were influenced by oxygen defect in host materials. Excitation spectra of these phosphors have high efficiency at the long wavelength region. And emission efficiency is increased under the excitation wavelength of 465nm. The combination of thiogallate green phosphor and sulfide red phosphor based on blue light InGaN chip has made it possible to emit white light.

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Luminescent properties of a $Zn_2SiO_4:Mn^{2+}$ film phosphor prepared by spray pyrolysis

  • Kim, Kyoun-Gun;Moon, Young-Min;Choi, Sung-Ho;Lee, Sun-Sook;Chung, Taek-Mo;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.1300-1302
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    • 2009
  • Transparent $Zn_2SiO_4:Mn^{2+}$ film has been synthesized by spray pyrolysis with various spraying conditions. It illuminates an efficient green emission with the relative emission intensity about 45% under 147nm excitation of a commercial powder phosphor. Additionally, the zinc precursors and additives play a key factor both controlling luminous efficiency and transparency.

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루테늄촉매 활성정도에 따른 유리섬유/폴리다이사이클로펜타다이엔 복합재료의 기계 및 계면물성 변화 (The Change in Interfacial and Mechanical Properties for Glass Fiber/p-DCPD Composites with Degree of Ruthenium Catalyst Activation)

  • 신평수;김종현;백영민;박하승;권동준;박종만
    • 접착 및 계면
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    • 제19권1호
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    • pp.13-18
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    • 2018
  • 루테늄촉매는 대기중에 노출되었을 때, 촉매활성정도가 떨어지게 된다. 루테늄 촉매의 촉매활성변화를 대기노출 일수에 따라 표면장력방법을 이용하여 정량적으로 확인하였다. 각 대기노출일수에 따른 루테늄 촉매를 이용하여 DCPD 중합 후 기계 및 계면물성변화를 확인하였다. 희석제와 10:1로 섞인 루테늄 촉매를 대기 중에 노출 시킨 후 각 일수에 따라 색깔 관찰하였다. 윌헴리 및 PTFE를 이용하여 표면장력을 구하고 이를 촉매활성 정도와 연관시켰다. 각 촉매를 이용하여 DCPD를 중합시키는 데 발열량을 실시간으로 측정하였다. 경화 후 p-DCPD에 대하여 인장강도를 측정하여 물성감소정도를 확인하였다. 또한, 유리섬유 간 마이크로드롭렛 풀 아웃 실험을 통하여 계면물성 또한 파악하였다. 표면장력방법을 통하여 촉매활성 정도를 확인하였을 때, 4일까지는 33 dyne/cm로 안정적이었지만, 6일 이후로 표면장력이 34 dyne/cm 이상 증가하는 것을 확인하였고, 이는 촉매의 산화와 연관시킬 수 있었다. 기계적 물성 확인하였을 때, 인장강도 및 계면강도 또한 6일 (인장강도: 38 MPa. 계면전단 강도: 26 MPa) 까지는 안정적이었지만 10일 (인장강도: 15 MP. 계면전단강도: 3 MPa) 이후로 물성이 급격하게 감소하는 것을 확인하였다.

학교건축에서의 친환경 기술요소 적용에 관한 연구 (A Study on the Green Building Technologies of Educational Facilities)

  • 박임호;정진주;윤성훈
    • 한국농촌건축학회논문집
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    • 제14권1호
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    • pp.75-82
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    • 2012
  • Today, educational facilities are considered to be one of the most important built environment. And the appropriate combinations and applications of technical elements related to green building on the education facilities are emphasized and demanded. These are must be compatible with the occupants' activities and their needs. The objective of this research is to identify and analyze of green building technologies, based on Green Educational Facilities' Case Study in Korea, USA, and Japan. As a result of the comparative analysis of this research, the green technological approaches, problem, and characteristics on educational facilities in different area, climate zone are identified and analyzed by external environment, energy, materials and resources, and indoor environment. It is useful as basic reference for future green educational facilities' planning and design in Korea.

1×1 mm2 대면적 녹색 LED의 전기 광학적 특성 분석 (Electro-Optical Characteristics and Analysis of 1×1 mm2 Large-Area InGaN/GaN Green LED)

  • 장이운;조동섭;전주원;안태영;박민주;안병준;송정훈;곽준섭;김진수;이인환;안행근
    • 한국진공학회지
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    • 제20권4호
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    • pp.288-293
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    • 2011
  • 본 논문은 InGaN/GaN 다중양자우물 구조를 가지는 녹색 발광다이오드의 활성층 내 인듐(In) 조성비와 piezoelectric field에 대한 전계 흡수 현상을 연구하였다. 활성층 내 결정학적 성질과 In 조성비는 double crystal X-ray diffraction 측정으로 분석하였으며, $1{\times}1\;mm^2$ 대면적 칩을 제작하여 발광특성을 조사하였다. 또한, 활성층 내 piezoelectric field는 electro-reflectance spectroscopy로부터 측정한 compensation voltage를 이용해 계산하였고, 인가전압에 따른 photocurrent의 변화를 측정함으로써 녹색 발광 소자의 전기 광학적 특성을 분석하였다.

Synthesis and Characterization of Biodegradable Thermo- and pH-Sensitive Hydrogels Based on Pluronic F127/Poly($\varepsilon$-caprolactone) Macromer and Acrylic Acid

  • Zhao, Sanping;Cao, Mengjie;Wu, Jun;Xu, Weilin
    • Macromolecular Research
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    • 제17권12호
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    • pp.1025-1031
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    • 2009
  • Several kinds of biodegradable hydrogels were prepared via in situ photopolymerization of Pluronic F127/poly($\varepsilon$-caprolactone) macromer and acrylic acid (AA) comonomer in aqueous medium. The swelling kinetics measurements showed that the resultant hydrogels exhibited both thermo- and pH-sensitive behaviors, and that this stimuli-responsiveness underwent a fast reversible process. With increasing pH of the local buffer solutions, the pH sensitivity of the hydrogels was increased, while the temperature sensitivity was decreased. In vitro hydrolytic degradation in the buffer solution (pH 7.4, $37^{\circ}C$), the degradation rate of the hydrogels was greatly improved due to the introduction of the AA comonomer. The in vitro release profiles of bovine serum albumin (BSA) in-situ embedded into the hydrogels were also investigated: the release mechanism of BSA based on the Peppas equation was followed Case II diffusion. Such biodegradable dual-sensitive hydrogel materials may have more advantages as a potentially interesting platform for smart drug delivery carriers and tissue engineering scaffolds.

Influence of para-orientating Methoxyl Units on the Electronic Structures and Light Absorption Properties of the Triphenylamine-based dyes by DFT Study

  • Liang, Guijie;Xu, Jie;Xu, Weilin;Wang, Luoxin;Shen, Xiaolin;Yao, Mu
    • Bulletin of the Korean Chemical Society
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    • 제32권7호
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    • pp.2279-2285
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    • 2011
  • The geometries, electronic structures and absorption spectra of the two organic triphenylamine-based dyes TA-St-CA and TA-DM-CA, containing identical electron donors and acceptors but the different conjugated bridges, were studied by density functional theory (DFT) at the B3LYP and PBE1PBE levels, respectively. The influence of para-orientating methoxyl units on the electronic structures and light absorption properties of the dyes and the consequent photovoltaic performance of the dye-sensitized solar cells (DSSCs) were investigated in detail. The results indicate that the introduction of the para-orientating methoxyl units into the conjugated bridge induces the increased absorption wavelength as well as the more negative EHOMO corresponding to the bigger driving force $(E_{I^-/I^-_3}-E_{HOMO})$ for dye reduction, which together improve the photovoltaic performance of TA-DM-CA, although there is a decline of the open circuit voltage caused by the more negative $E_{LUMO}$.