• 제목/요약/키워드: Gravimetric

검색결과 529건 처리시간 0.024초

PM10 연속자동측정기(β-ray) 등가성평가 및 비교관측 연구 (PM10 β-ray attenuation samplers (β-ray absorption method) equivalence evaluation and comparatively observed study)

  • 정원석;고희정;서원익;정지영;오상민;부경온
    • 한국입자에어로졸학회지
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    • 제19권1호
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    • pp.13-20
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    • 2023
  • The Asian dust observation network operates β-ray attenuation samplers to measure PM10 concentrations. In addition, equivalence evaluation and accuracy inspection(Precision Tests) are conducted every year for the reliability of data. β-ray attenuation samplers(16 units) were comparatively observed from May to June 2020 and from July to December 2021. During the observation period, the average daily temperature was the lowest at 6.4℃ in December and the highest at 27.3℃ in August. The average daily humidity ranged from 60% to 100%, but the average daily humidity was over 75% from July to September. The minimum value of the PM10 Gravimetric method was 5.0 ㎍/m3, the maximum value was 53.4 ㎍/m3, and the average value was 17.8 ㎍/m3. The equivalence evaluation results of the PM10 Gravimetric method and β-ray attenuation samplers satisfied the criteria (slope: 1±0.1, intercept: 0±0.5). A relative error analysis between the PM10 Gravimetric method and β-ray attenuation samplers equipment showed that the relative error increased when the concentration was low and the temperature and humidity were high. In addition, in the β-ray attenuation samplers 5-minute interval observation data in May 2020, a relatively large Standard devication was shown as an average maximum ±23.4 ㎍/m3 and a minimum ±15.2 ㎍/m3. At standard deviations of 10% and 90%, equipment with high variability (deviation) was measured at 6 ㎍/m3and 61 ㎍/m3, and equipment with low variability was measured at 12 ㎍/m3 and 47 ㎍/m3. It was confirmed that concentration differences occurred due to differences in variability for each equipment.

The influence of EAF dust on resistivity of concrete and corrosion of steel bars embedded in concrete

  • Almutlaq, Fahad M.
    • Advances in concrete construction
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    • 제2권3호
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    • pp.163-176
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    • 2014
  • Essentially, when electrical current flows easily in concrete that has large pores filled with highly connective pore water, this is an indication of a low resistivity concrete. In concrete, the flow of current between anodic and cathodic sites on a steel reinforcing bar surface is regulated by the concrete electrical resistance. Therefore, deterioration of any existing reinforced concrete structure due to corrosion of reinforcement steel bar is governed, to some extent, by resistivity of concrete. Resistivity of concrete can be improved by using SCMs and thus increases the concrete electrical resistance and the ability of concrete to resist chloride ingress and/or oxygen penetration resulting in prolonging the onset of corrosion. After depassivation it may slow down the corrosion rate of the steel bar. This indicates the need for further study of the effect of electric arc furnace dust (EAFD) addition on the concrete resistivity. In this study, concrete specimens rather than mortars were cast with different additions of EAFD to verify the electrochemical results obtained and to try to understand the role of EAFD addition in influencing the corrosion behaviour of reinforcing steel bar embedded in concrete and its relation to the resistivity of concrete. The results of these investigations indicated that the corrosion resistance of steel bars embedded in concrete containing EAFD was improved, which may link to the high resistivity found in EAFD-concrete. In this paper, potential measurements, corrosion rates, gravimetric corrosion weight results and resistivity measurements will be presented and their relationships will also be discussed in details.

연구로 해체시 발생되는 흑연폐기물의 열적 거동 (Thermal Behavior of the Nuclear Graphite Waste Generated from the Decommissioning of the Nuclear Research Reactor)

  • 양희철;은희철;이동규;조용준;강영애;이근우;오원진
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 학술논문집
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    • pp.105-114
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    • 2004
  • This study investigated the thermal behavior of the nuclear graphite waste generated from the decommissioning of the Korean nuclear research reactor, The first part study investigated the decomposition rate of the nuclear graphite waste up to $1000^{\circ}C$ under various oxygen partial pressures using a thermo-gravimetric analyzer (TGA). Tested graphite waste sample not easily destroyed in the oxygen-deficient condition. However, the gas-solid oxidation reaction was found to be very effective in the presence of oxygen. No significant amount of the product of incomplete combustion was formed even in the limited oxygen concentration of 4% $O_2$. The influence of temperature and oxygen partial pressure was evaluated by the theoretical model analysis of the thermo-gravimetric data. The activation energy and the reaction order of graphite oxidation were evaluated as 128 kJ/mole and 1.1, respectively. The second part of this study investigated the behavior of radioactive elements under graphite oxidation atmosphere using thermodynamic equilibrium model. $^{22}Na$, $^{134}Cs$ and $^{137}Cs$ were found be the semi-volatile elements. Since volatile uranium species can be formulated at high temperatures above $1050^{\circ}C$, the temperature of incinerator furnace should be minimized. Other corrosion/activation products, fission products and uranium were found to be the non-volatile species.

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FFT에 의한 한반도 일원에서의 중력지오이드 결정 (Gravimetric Geoid Determination by Fast Fourier Transform in and Around Korean Peninsula)

  • 이석배;윤홍식;최재화
    • 한국측량학회지
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    • 제14권1호
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    • pp.49-58
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    • 1996
  • 본 연구에서는 FFT 방법에 의하여 한반도 일원에서의 중력지오이드를 계산하였으며, GRS80 타원체상에서 OSU91A 지오포텐셜모델을 구면조화분석을 하여 기준면으로 사용하였다. 중파장효과를 계산하기 위하여 remove and restore technique이 사용되었으며, 지상의 중력이상값에 FFT 방법을 적용하였다. 또한 계산된 결과를 GPS/Levelling 데이터로부터 계산한 지오이드고와 비교, 평가하였다. 본 연구에서 계산한 중력지오이드와 GPS/Levelling방법에 의한 지오이드의 비교 결과 교차의 평균값과 RMSE가 각각 0.3819m와 0.4695m로 나타났다.

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대기 중 TSP와 PM10 농도의 관련성 (Relationships between TSP and PM10 Concentrations in the Ambient Atmosphere)

  • 최진수;백성옥
    • 한국대기환경학회지
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    • 제14권1호
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    • pp.1-10
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    • 1998
  • Relationships between TSP and PM10 concentrations were evaluated using their respective data sets collected from Taegu and Kyeungsan areas during the period of December 1993 to November 1994. The collection of data was made using the gravimetric and $\beta$-ray absorption ($\beta$-MPM) methods for 7 days of every month from three urban sites in Taegu and one suburban site in Kyeungsan. Correlation coefficients between TSP and PM10 concentrations for these four sampling sites were found in the range of 0.85 $\sim$ 0.96. Correlation analysis was also conducted for $\beta$-PM concentration data that were measured only from the residential and commercial sites. The correlation coefficients between TSP and $\beta$-PM concentrations were 0.9 in the residential site and 0.8 in the commercial site. By contrast, the correlation coefficients between PM10 $\beta$-PM concentrations were almost identical for both the residential and commercial sites with a value of 0.88. The mean ratio for PM10 to TSP concentrations for all sites was appeared to be 0.68. The analysis of seasonal trends in PM10/TSP ratios showed that the contribution of PM10 to TSP concentrations was more significant during winter (0.70 $\sim$ 0.75) than during summer (0.61 $\sim$ 0.68). The results of this study may provide empirical informations on the compatability of aerosol data measured by different sampling methods.

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선박용 4행정 디젤엔진의 정속 부하변동 운전시 매연배출특성에 대한 실험연구 (An Experimental Study on the Emission Characteristics of Smoke from the Marine Four-Stroke Diesel Engines Operated in Constant Speed and Various Load Steps)

  • 오상훈;김재민;김현규;유봉환
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2006년도 전기학술대회논문집
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    • pp.19-20
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    • 2006
  • The emission of particulate matter from marine diesel engines is already restricted by regional regulations in some countries, and IMO has been preparing the regulation for particulate matter from 53rd MEPC. But confusingly, the gravimetric PM measurement methods and procedures are not established clearly yet. On the other hand, smoke measurement method is set clearly, and it can also indicate PM, though it is not direct gravimetric method. As the preparing step for regulations about PM, we measured the smote density of exhaust emission from the marine four-stroke diesel engines operated in constant speed and various load steps on the test-bed, using the filter-type smoke measuring instrument. As a result, we understood the omission characteristics of smoke from the engines. Additionally, to obtain the objective reliability of our measurement data, we carried out experimental studies about various measuring parameters that could affect the smoke density.

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The effect of phosphate corrosion inhibitor on steel in synthetic concrete solutions

  • Sail, L.;Ghomari, F.;Khelidj, A.;Bezzar, A.;Benali, O.
    • Advances in materials Research
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    • 제2권3호
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    • pp.155-172
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    • 2013
  • The study of the corrosion inhibition of armatures made of steel conceived for reinforced concrete by sodium phosphate is the aim object of our experimental tests. Gravimetric and electrochemical measurements were carried in three different Mediums contaminated by chlorides (3% NaCl) with addition of increasing concentrations of sodium phosphate. Inhibitory efficiency reached 80% at an optimal concentration of $7,5{\times}10^{-3}M$, the results obtained using the gravimetric measurements are in good agreement with those obtained by electrochemical methods. However, the monitoring of the pH evolution after 24h shows in the three studied environments, that the pH decreases slightly at 24 hours from the initial pH at $t_0$, due to the presence of corrosion products which change the state of the final solution. Also, scanning electron microscopy revealed the existence of layers of apatite on the metal surface previously treated with the sodium phosphate which confirms the formation of a protective film around the surface of the metal.

소형 코리올리 질량 유량계의 개발 (Development of Small Size Coriolis Mass Flowmeter)

  • 임기원;지정근
    • 대한기계학회논문집B
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    • 제30권6호
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    • pp.497-504
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    • 2006
  • A Coriolis mass flowmeter(CMF), which has U-Shaped unique measurins tube was developed fo. direct mass flow measurement. In order to convert the time difference between two measuring tubes motion into mass flowrate and flow quantity, a signal processing circuit, as a part of CMF, was also developed. The CMF was designed as the 15 mm nominal diameter of pipe connection and the 8 mm stainless steel(sus 316) pipe was used for measuring tube. To maximize the flow signal(time difference) from the measuring tubes, the natural frequency of measuring tube was adjusted as 220 Hz, which is same as the frequency of exciter. The maximum displacement at the end of the measuring tube was measured as 0.05 mm and the maximum time difference between two measuring tubes was observed as $20{\mu}s$, which was proper for discrimination and measuring range of CMF. The developed CMF was tested against the gravimetric flowmeter calibrator in the range of 3 kg/min and 30 kg/min. The results showed that the CMF has good linearity and repeatability in the tested flow range. Large size of CMF base on the current study experience will be developed.