• Carbon letters
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• 제11권4호
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• pp.343-346
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• 2010

The various expanded graphites (EGs) was prepared and applied as anode material for high power Li-ion secondary battery (LIB). By changing the processing conditions of EG, a series of EG with different structure were produced, showing the changed electrochemical properties. The charge-discharge test showed that the initial reversible capacity of EG anodes prepared at the suitable conditions was over 400 mAh/g and the charge capacity at 5 C-rate was 83.2 mAh/g. These values demonstrated the much improved electrochemical properties as compared with those for the graphite anode of 360 mAh/g and 19.4 mAh/g, respectively, showing the possibility of EG anode materials for high power LIB.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 2005년도 춘계학술발표회
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• pp.41-42
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• 2005

• Bulletin of the Korean Chemical Society
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• 제23권12호
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• pp.1801-1805
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• 2002

The graphite intercalation compounds(GIC) were prepared by a dry process that led to the intercalation from the direct reaction of gaseous $SO_3$ with flake type graphite. The basal spacing of the GIC was increased from 8.3 ${\AA}$ to 12 in the gallery height. The ejection of interlayer $SO_3$ molecules by the heating for 1 minute at $950^{\circ}C$ resulted in an exfoliated graphite (EG) with surprisingly high expansion in the direction of c-axis. The expansion ratios of the exfoliated graphites were increased greatly between 220 times and 400 times compared to the original graphite particles, and the bulk density was range of 0.0053 to 0.01 $g/cm^3$, depending on reaction time. The pore size distribution of exfoliated graphite was in the range of $10-170{\mu}m$, which exhibites both mesoporosity and macroporosities. This result indicates that the direct reaction of graphite paricles with gaseous $SO_3$ can be proposed as an another route for the exfoliated graphite having excellent physical properties.

• 한국공작기계학회논문집
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• 제10권6호
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• pp.42-47
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• 2001

In this study, fatigue limit of ductile cast iron is evaluated based on phenomena of the microscopic observation, such as matrix structure, spheroidal ratio, size of graphite and distribution. Three different ferrite-pearlite matrix structure, GCD 45-), GCD 50, GCD 60 series, all of which contain more than 70% spheroidal ratio of graphite, were used to obtain the correlation between maximum size of graphite and fatigue strength. It was concluded as fellows. (1) In Ductile cast iron of ferrite-pearlite matrix, the fatigue limit of GCD 60 series with 73% pearlite structure was the highest. (2) From observation of the starting point of crack of all specimens, it is noted that the crack initiates, in graphite, goes through ferrite and propagates into pearlite. (3) A good quality of Ductile cast iron used in this experiment can be checked from uniformly distributed graphite. The negligible interaction effect between graphites was verified by microscopic observation and fracture mechanics investigation in surface and interior of the specimen.

• 산업기술연구
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• 제18권
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• pp.203-208
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• 1998

Fatigue tests were performed to examine the 4 parameter method for specimens prepared by various heat treatment which resulted in different mechanical properties. Obtained main results are as follows. (1) Samples treated by austempering did not show the expected improvement of fatigue limit although hardness and strength increased. This is attributed to the fact that defect sensitivities of materials increase as increasing of hardness and tensile strength, it is also shown that the graphites acting as stress concentration place become larger by austempering heat treatment than by normal annealing. (2) It is very reasonable to predict the fatigue limit of ductile irons with 4 parameter method based on ${\sigma}_{TS}$, $H_v$, ${\Delta}K_{th}$ and ${\sqrt{area}}_{max}$. (3) The half-austempering treatment appeared to be more useful than the full-austempering method to improve the fatigue limit in the spheroidal graphite cast iron with multi defective material.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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• pp.38-38
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• 2000

저온유지장치에서 요구되는 도달압력은 초전도 코일의 냉각시스템과 저온유지장치의 벽 사이의 진공단열조건으로부터 결정될 수 있으며, 기체에 의한 열전도의 영향을 방지하기 위해서는 5$\times$105Torr 이하의 진공도가 요구된다. 저온유지장치 내에서 진공 단열재로 사용되는 Glass Fiber Reinforced Plastic(GFRP)과 Carbon Fiber Reinforced Plastic(CFRP)의 기체 방출률을 측정하였다. 고출력 토카막 방전동안 graphite limiter 표면의 온도는 200$0^{\circ}C$ 이상이며, 플라즈마로 유입되는 불순물의 양을 줄이기 위해 많은 시도를 하고 있다. 상온에서부터 약 100$0^{\circ}C$까지 승온에 따른 방출기체의 양 및 성분 분석, annealing 후 공기 중에 약 2주간 노출 후 기체 방출률과 성분을 분석하였다. 총 기체 방출량은 10$0^{\circ}C$ 근방에서 급격히 증가하여 $600^{\circ}C$부터는 graphite의 종류에 관계없이 거의 일정한 분포를 보이며, 최대 방출률은 약 20$0^{\circ}C$~30$0^{\circ}C$ 부근에서 나타났다.

• 한국수소및신에너지학회논문집
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• 제13권4호
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• pp.313-320
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• 2002

The characteristics of the AISI bipolar plates have been investigated to replace the expensive graphite bipolar plates. It was found from the contact resistance evaluation of graphites, composites, and AISI that the contact resistance of AISI was the lowest, but it could approach to that of composites at higher compression forces. The single cell operation using the AISI bipolar plates revealed that the lower performance of the AISI single cell compared to the graphite one was due to not only the higher contact resistance but the flooding effect caused by high wettability of AISI. The performance of the AISI single cell could be improved if the channels were modified appropriately. The large size AISI single cell was operated to investigated the size effect on the performance.

• 박물관보존과학
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• 제5권
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• pp.17-22
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• 2004

일제시대에 발굴되어 여러 편으로 분리되어 있던 철제용기를 보존처리하였다. 보존처리를 통하여 유물을 안정화시키고, 본래의 형상을 복원하였다. 보존처리 결과 철제용기는 굽이 있으며 구연부에 턱이 있고 안으로 오므라드는 유선형이었다. X-선 투과검사 결과 주조과정에서 기공이 많이 발생한 것이 관찰되었으며, 금속조직을 통해 재질이 초정흑연을 가진 과공정 백주철임을 알 수 있었다.

• Carbon letters
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• 제12권1호
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• pp.8-15
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• 2011

We study the relationships between the thermal emissivity of nuclear graphites (IG-110, PCEA, IG-430 and NBG-18) and their surface structural change by oxidation using scanning electron microscope and X-ray diffraction (XRD). The nonoxidized (0% weight loss) specimen had the surface covered with glassy materials and the 5% and 10% oxidized specimens, however, showed high roughness of the surface without glassy materials. During oxidation the binder materials were oxidized first and then graphitic filler particles were subsequently oxidized. The 002 interlayer spacings of the non-oxidized and the oxidized specimens were about $3.38{\sim}3.39{\AA}$. There was a slight change in crystallite size after oxidation compared to the nonoxidized specimens. It was difficult to find a relationship between the thermal emissivity and the structural parameters obtained from the XRD analysis.

• Carbon letters
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• 제10권3호
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• pp.225-229
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• 2009

Thermal emissivity of commercial nuclear graphites (IG-110, PCEA, IG-430 and NBG-18) following changes in oxidation degrees were examined. Specimens were oxidized to 0%, 5%, and 10% in air flow of 5l/min at $600^{\circ}C$ using a furnace, and the thermal emissivities were measured using an infrared spectrum analyzer. The measuring temperatures for the thermal emissivity were $100^{\circ}C$, $200^{\circ}C$, $300^{\circ}C$, $400^{\circ}C$ $500^{\circ}C$. Also density and porosity of the specimens were observed to compare with thermal emissivity. Results showed that emissivity increased with oxidation, and the 10% oxidized NBG-18 showed the highest emissivity (0.890) which value is larger for 24% than the value of as-received specimen. Investigation of factors affecting the emissivity revealed that increases in the surface roughness and porosity due to oxidation were responsible for the increase in emissivity after oxidation.