• Journal of Korea Foundry Society
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• v.23 no.4
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• pp.187-194
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• 2003

The effect of rare earth elements (R.E)(from 0.0 to 0.04%) on the microstructure formation and mechanical properties of thin-wall ductile iron castings were investigated. Tensile strength and hardness were decreased with an addition of up to 0.03% rare-earth elements. After addition of more than 0.03%, those were increased. Graphite nodule sizes were the finest, nodule count was the highst regardless of thickness and volume fraction of ferrite was the largest when that was 0.02%. However, the nodule count was decreased with increasing R.E. Futhermore. nodule size increased with increasing thickness and the volume fraction of ferrite decreased as that was increased. Nodularity was increased regardless of the thickness as that was increased. The castings of minium thickness up to 3 mm was possible without the formation of chill.

• Journal of Mechanical Science and Technology
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• v.14 no.10
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• pp.1021-1027
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• 2000

In this study, fatigue tests were performed to examine the effects of micro drill hole on fatigue limit of as cast and austempered ductile cast iron (ADI) using the rotary bending fatigue tester. As results, micro drill holes ($diameter{\leq}0.4mm$) did not influence the fatigue limit of ADI, compared to annealed ductile cast iron; the critical defect size of crack initiation, in ADI was larger than as cast. If the ${\sqrt{area}}$ of micro drill hole and graphite nodule in ADI are comparable, crack initiates at the graphite nodule. When the ruggedness developes through austempering treatment process, microstructure on crack initiation at micro drill hole is tougher than that of as cast ductile cast iron.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.23 no.11 s.170
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• pp.1922-1928
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• 1999

Rotary bending fatigue tests were carried out to investigate the influence of artificial defects on fatigue limit in annealed and austempered ductile iron. Obtained main results are as follows : (1) Artificial defect(micro hole type, dia.<0.4 mm) on specimen surface did not bring about a obvious reduction of fatigue limit in austempered ductile iron(ADI) as compared with annealed ductile iron. (2) According to the investigation of $\sqrt{area}_c$ which is the critical defect size to crack initiation at artificial defect, $\sqrt{area}_c$ of ADI is larger than that of annealed ductile iron. This shows that the situation of crack initiation at artificial defect in ADI is more difficult in comparison with annealed ductile iron. (3) One of the reasons for the low rate of crack initiation from artificial defect in ADI is that the resistance of matrix to crack initiation is higher than that of annealed ductile iron. (4) In case that the $\sqrt{area}$ of artificial defect and graphite nodule is the same, the rate of crack initiation from graphite nodule is higher than that from artificial defect. This reason is that the serious ruggedness around graphite nodule is formed by austempering treatment.

• Journal of the Korean Society for Heat Treatment
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• v.12 no.3
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• pp.215-220
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• 1999

Rotary bending fatigue tests were carried out to investigate the artificial defect sensitivity of fatigue limit in annealed and austempered ductile irons. Artificial defect(hole, diameter${\leq}0.4mm$) machined on specimen surface did not bring about an obvious reduction of fatigue limit in austempered ductile iron as compared with annealed. As a result of investigation on $\sqrt{area}$ c which is the critical artificial defect size. $\sqrt{area}$ c of austempered ductile iron is larger than that of annealed. This means that the crack initiation at artificial defect in austempered ductile iron is more difficult in comparison with annealed. In case that the $\sqrt{area}$ c of artificial defect and graphite nodule are same, the rate of crack initiation for graphite nodule is higher than that of artificial defect.

• Economic and Environmental Geology
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• v.19 no.2
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• pp.133-146
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• 1986

Primary uraninite and secondary uranium minerals such as torbernite, metatorbernite, tyuyamunite, metatyuyamunite, autunite and metaautunite have been identified from various types of uranium ores. Uranium minerals occur as accessory minerals in both the primary and secondary ores. Low·grade uranium ores consist of various kinds of primary and secondary minerals. Major constituent minerals of primary uranium ores are graphite. quartz. Ba-feldspar and sericite/muscovite, and accessories are calcite, chlorite, fluorapatite, barite, diopside, sphene, rutile, biotite, laumontite, heulandite, pyrite, sphalerite and chalcopyrite, and secondary minerals consist of kaolinite, gypsum and goethite. Uraninite grains occur as microscopic very fine-grained anhedral to euhedral disseminated particles in the graphitic matrix, showing well·stratified or zonal distribution of uranium on auto-radiographs of low-grade uranium ores. Some uraninite grains are closely associated with very fine-grained pyrite aggregates, showing an elliptical form parallel to the schistosity. Some uraninite grains include extremely fine-grained pyrite particle. Sphalerite and pyrite are often associated with uraninite in graphite-fluorapatite nodule. The size of uraninite is $2{\mu}m$ to $20{\mu}m$ in diameter. Low-grade uranium ores are classified into 5 types on the basis of geometrical pattern of mineralization. They are massive, banded, nodular, quartz or sulfide veinlet-rich and cavity filling types. Well-developed alternation of uranium-rich and uranium-poor layers, concentric distribution of uranium in graphite-fluorapatite nodule and geopetal fabrics due to the load cast of the nodule suggest that the uranium was originally deposited syngenetically. Uraninite crystals might have been formed from organo-uranium complex during diagenesis and recrystallized by metamorphism. Secondary uranium minerals such as torbernite, tyuyamunite and autunite have been formed by supergene leaching of primary ores and subsequent crystallization in cavities.

• Applied Microscopy
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• v.48 no.3
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• pp.73-80
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• 2018

Ductile cast iron is widely used for many automotive components due to its high wear resistance and fatigue resistance in addition to the low cost of fabrication. The improvement of wear resistance and fatigue properties is key to the life time extension and performance increase of the automobile parts. Surface nanocrystallization is a very efficient way of improving the performance of materials including the wear- and fatigue-resistance. Shot peening treatment, as one of the popular and economic surface modification methods, has been widely applied to various materials. In this study, ductile cast iron specimens were ultrasonic shot peening (USP) treated for 5 to 30 min using different ball size. The microstructures were then microscopically analyzed for determination of the microstructural evolution. After the USP treatment, the hardness of pearlite and ferrite increased, in which ball size is more effective than treatment time. With USP treatment, the graphite nodule count near the surface was decreased with grain refinement. The lager balls resulted in an increased deformation, whereas the smaller balls induced more homogenously refined grains in the deformation layer. In addition, formation of nanoparticles was formed in the surface layer upon USP.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.11
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• pp.2742-2748
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• 2000

In this study, the quantitative evaluation was performed by examination for gatigue crack origin in two prepared ductile irons specimens which have different microstructures using rotary bending fatigue tester, Series A has mixed microstructure. ferrite plus pearlite, and series B has bainitic microstructure. Obtained main results are as follows. The scatterings of fatigue strength were observed on σ(sub)α-Ν diagram of both specimen series, and it is observed that scatterings of series A were more serious. It is reasonable to evaluate the size of mesocrack range by means of √A(원문참조), where A means the area of mesocrack range including globular graphite nodule. As a result of reconsideration for the fatigue data by introduction of K(sub)α-Ν diagram, the scattrings of fatigue life were, remarkably. reduced. Therefore, it is more reasonable to evaluate of mesocrack range on fatigue life by parameter K(sub)α rather than σ(sub)α.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.4 no.4
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• pp.395-404
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• 1994

Ni-graphite composite powders were prepared by reduction of $Ni^{++}$ from ammoniacal nickel sulfate solution on graphite core by hydrogen gas. Effect of reaction factors on the reduction rate and the properties of nickel layer were investigated by SEM, Optical Microscopy, size and chemical analysis. Induction period, a time lag between the injection of hydrogen gas and the start of the reduction, was 20~110 mins and affected by the reaction temperature and stirring speed. The reduction rate of $Ni^{++}$ was $4.5g/{\ell}/min$ at optimum condition and increased with increasing reaction temperature and stirring speed.

• Korean Journal of Materials Research
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• v.3 no.5
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• pp.521-528
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• 1993

Ni-graphi~e composite powders were prepared by reduct ion of $Ni^{++}$ from arnmoniacal nickel sulfate solution on graphite core by hydrogen gas at elevated temperature and pressure. Effect of coating catalyst. Anthraquinone $(C_6H_4COC_6H_4 CO)$, on the reduction rate and the properties of nickel layer were investigated by SEM, X-ray, size and chemical analysis. 1nduct.ion period, a time lag between the ~njection of hydrogen gas and the start of the reduction, was 22 to 70 mins and was affected by the size and amount of Anthraquinone. Kickel layer deposited on the surface of graphite core material was composed of nickel nodules whose sizes were different with vari~ ous reduction conditions. Minimum diameter of nickel nodules was about 2-3$\mu \textrm m$.