• Title/Summary/Keyword: Grain-Size

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Sintering and Dielectric Characteristics of LaAlO3 Ceramics by Mechanochemical Treatment from La2O3-A12O3 and La2O3-Al(OH)3 (La2O3-Al2O3와 La2O3-Al(OH)3를 메카노케미칼로 처리한 LaAlO3세라믹스의 소결 및 유전특성)

  • 최상수;조정호;김강언;정수태;조상희
    • Journal of the Korean Ceramic Society
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    • v.39 no.1
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    • pp.68-73
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    • 2002
  • The dielectric properties and synthesis of $LaAlO_3$ ceramics from mixtures of $La_2O_3-Al_2O_3$ (LAO) and $La_2O_3-Al(OH)_3$(LAH) via grinding process were investigated. The single phase $LaA1O_3$of LAO and LAH powders were formed at $1300^{\circ}C$ and $1000^{\circ}C$, respectively. A non-reacted $La_2O_3$ existing in calcined powder was changed to La(OH)$_3$by moisture in the air, and their samples were worse than those of the samples made from a $LaA1O_3$single phase powder. The densities of LAO samples sintered at 150$0^{\circ}C$ for 4 h and LAH samples sintered at $1400^{\circ}C$ for 4 h were 97.3% and 98.3% of theory density, respectively. Grains of LAH sample showed uniformity and their sizes were 0.75 ${\mu}{\textrm}{m}$, and LAO samples showed non-uniformity and their sizes were 4-5 ${\mu}{\textrm}{m}$. Dielectric constant of LAO and LAH samples were the same value (≒22), however dielectric loss of LAH sample (0.0003) were lower than that of LAO sample(0.001)due to grain size.

The Effect of Residual H2Pressure on Gallium-doped ZnO Films Deposited by Magnetron Sputtering (마그네트론 스퍼터링에 의해 제작한 Gallium-doped ZnO 박막에 있어서 잔류 H2O 분압의 영향)

  • Song, Pung-Keun;Kwon, Young-Jun;Cha, Jae-Min;Lee, Byung-Chul;Ryu, Bong-Ki;Kim, Kwang-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.10
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    • pp.928-934
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    • 2002
  • Gallium doped Zinc Oxide(GZO) films were deposited by dc magnetron sputtering using a GZO ceramic target at various conditions such as substrate temperature (RT, 400), residual water pressure ($P_{H_2O}$; 1.61${\times}10^{-4}∼2.2{\times}10^{-3}$ Pa), introduction of $H_2$ gas (8.5%) and different magnetic field strengths(250, 1000G). GZO films deposited without substrate heating showed clear degradation in film crystallinity and electrical properties with increasing $P_{H_2O}$. The resistivity increased from 3.0${\times}10^{-3}$ to 3.1${\times}10^{-2}{\Omega}㎝$ and the grain size of the films decreased from 24 to 3 nm when PH2O was increased from 1.61${\times}10^{-4}$ to 2.2${\times}10^{-3}$ Pa. However, degradation in electrical properties with increasing $P_{H_2O}$ was not observed for the films deposited with introduction of 8.5% $H_2$. When magnetic field strength of the cathode increased from 250G to 1000G, crystallinity and electrical properties of GZO films improved remarkably about all the $P_{H_2O}$. This result could be attributed to the decrease in film damage caused by the decrease in plasma impedance.

The Effect of Titaniuml Surface Treatment on Osteoblast-Like Cell Attachment and Proliferation (Titanium 표면처리 방법이 Osteoblast-like Cells의부착 및 증식에 미치는 영향)

  • Kim, Do-Yung;Seol, Yang-Jo;Rhyu, In-Cheul;Hahm, Byung-Do;Chung, Chong-Pyoung;Choi, Sang-Mook;Kim, Woo-Jin;Baik, Hong-Koo;Heo, Seong-Joo;Han, Chong-Hyun;Kim, Myung-Ho;Choi, Yong-Chang;Chun, Heoung-Jae;Kwon, Soo-Kyoung
    • Journal of Periodontal and Implant Science
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    • v.30 no.3
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    • pp.491-504
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    • 2000
  • In clinical therapy, the current goal of dental implants is to enhance quantity and quality of osseointegration. Surface roughness and oxide structure are considered to influence the behavior of adherent cells. The purpose of this study is to evaluate the effect of different surface treatment on cellular response. The attachment and proliferation of osteoblast-like cell on sandblasted, sandblasted and etched, thermal oxidated surfaces have been compared. Sandblasting was done with $Al_2O_3$ particles(grain size of $50{\mu}m$), etching was processed with $NH_4OH$ : $H_2O_2$ : $H_2O(1:1:5)$ at $90^{\circ}C$ for 1 minute. Thermal oxidation was followed sandblasting and etching at $400^{\circ}C$, $600^{\circ}C$, $800^{\circ}C$ for 2 hours. Measurement of surface roughness after the different treatment did not show any differences of Ra value between terated surfaces. Cell attachment and proliferation were increased during experiment period, but no difference was observed. SEM evaluation revealed a similar pattern of osteoblast-like cells, well attached with dendritic extension and producing numerous matrix vesicles on cell surface. The results of this study showed that oxide layer alteration by thermal oxidation did not affect the attachment and proliferation of osteoblast-like cells. This suggests the possibility that the cellular responses are further influenced by surface roughness than titaniun oxide structure.

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A Study on the Physical Properties and Cytotoxicity of Tooth Ash and Dental Procelain (치아회분(齒牙灰粉)과 도재복합(陶材複合) 매식체(埋植體)의 물리적(物理的) 성질(性質) 및 세포배양(細胞培養)에 의(依)한 조직친화성(組織親和性)에 관(關)한 연구(硏究))

  • Hoh, Ki-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.22 no.1
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    • pp.51-68
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    • 1984
  • The purpose of this study is primarily to test the use value of tooth ash as an alternative material of the synthetic hydroxyapatite. For this purpose the author performed the experimental study to investigate the phsyical properties of sintered tooth ash and its histocompatibility in vitro. The tooth ash was made by incinerating procedure at $650^{\circ}C,\;750^{\circ}C,\;850^{\circ}C,\;950^{\circ}C\;and\;1050^{\circ}C$ respectively. The composition of tooth ash was analyzed and X-ray diffraction was done. The experimental specimens were molded to the cylinderical form 1 cm high, 1 cm in diameter under the pressure of $1000kg/cm^2$, which were divided into two groups; the one is sintered tooth ash at $1100^{\circ}C$ and the other is fired mixture of tooth ash and dental porcelain mixed to the weight ratio of 4:6, 5:5, 6:4 and 7:3. The physical propoerties of the sintered specimens were examined and their microstructure was observed under the Scanning Electron Microscope. The results obtained were as followings: 1. The difference of the tooth ash composition depending on incinerating temperature was of no significance, but the $CO_2$ disappeared from $950^{\circ}C$. 2. X-ray diffraction showed the tooth ash was mainly composed of hydroxyapatite and a small amount of - white lockite. But phase transformation was not disclosed. 3. The microstructure of the sintered specimens of the ashed tooth powder was of no difference in the structure and grain size accompanying the ashed temperature, but sintering ability seemed to be the best in the specimen incinerated at $950^{\circ}C$. 4. There was good wettability in the mixed sintered specimens of the ashed tooth powder and the porcelain powder. 5. The compressive strength of the sintered specimens of the tooth ash incinerated at $950^{\circ}C$ was the highest with $589.75kg/cm^2$ and the porosity and the absorption were the lowest as well. 6. The mixed sintered specimens of the tooth ash and porcelain powder was good in the physical properties in the case of mixed weight ratio of 6:4. 7. The animal fibroblast cultures with porcelain showed increase in the cell number, whereas the tooth ash showed a small degree of growth inhibition. But the difference of cell multiplication efficiency between control cultures and test cultures with tooth ash was not observed.

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Physicochemical Properties of Rice Cultivars with Different Amylose Contents (아밀로스 함량이 다른 쌀 품종의 이화학적 특성)

  • Choi, In-Duck
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.9
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    • pp.1313-1319
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    • 2010
  • Rice cultivars of Goami2 (G2), Baegjinju (BJJ), and Sulgaeng (SG) with different amylose contents were developed by mutation breeding via N-methyl-N-nitrosourea (MNU) treatment to Ilpumbyeo (IP), high japonica rice. They were identified by different appearances such as grain size, color, and shape. In this experiment, the compositional and physical qualities of those cultivars were examined. The G2 rice classified as a high-amylose rice cultivar was significantly higher in its non-digestable carbohydrates contents. Linoleic and oleic acid were composed of 70~75% of all fatty acids composition regardless of milled and brown rice, except G2 rice in which palmitic acid was the major fatty acid followed by linoleic acid and oleic acid in order. Major amino acids were aspartic acid, glutamic acid, and hydroxy lysine. It was found that cysteine contents were higher in the cultivars of endosperm mutant rice. The DSC analysis revealed that enthalpy was the highest in BJJ followed by SG, IP, and G2 rice. The lowest enthalpy of G2 might be attributable to the higher amylose content. Ilpumbyeo in its cooked rice form showed the highest in Toyo value and less in hardness, but G2 was vise versa. Results of gelatinization and cooked rice properties suggest that G2 was less suitable for cooked rice, but has a potential for functional ingredients from nutritional point of view. The BJJ and SG could be used for traditional cooking as well as for processed foods.

Variation of Meiobenthic Community in the Sediment of Coastal Area in Bangameori Daebudo, Korea (대부도 방아머리 연안 퇴적물에 서식하는 중형저서동물 군집 변동)

  • 김동성;민원기;이재학
    • Korean Journal of Environmental Biology
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    • v.22 no.2
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    • pp.308-320
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    • 2004
  • The Community structure of meiobenthos was studied seasonally at 5 stations of Bangameori tidal flat and 3 stations of subtidal area in Daebudo near the Shiwha dike in the west coast of Korea, from May 2000 to February 2001. Mean grain size of intertidal stations ranged from $3.16\;\varphi\;to\;3.73\varphi$ (sand), subtidal stations were $5.81~6.67\;\varphi$ (mud). Nematodes were the most dominant group among the representative 19 meiofaunal groups at all stations in both tidal flat and sub-tidal area. The subdominant groups were benthic harpacticoid copepods and Sarcomastigophorans. The density of meiobenthos ranged from 145 inds. $10cm^{-2}$ to 2,057 inds. $10cm^{-2}$ (0~1 cm) in the sediment of intertidal stations, and from 391 to 3,787 inds. $10cm^{-2}$ (0~5 cm) in the subtidal stations. The lowest meiofaunal density was recorded in winter, whereas the highest density was shown in spring. Comparing with another previous work at the same area, data from this study does not statistically shown differences with results before discharge of shiwha lake water.

Selecting Aquifer Artificial Recharge Methods Based on Characteristics of the Target Aquifer (주입대상 대수층의 특성을 고려한 인공함양 방법 선정 연구)

  • Lee, Yeoung-Dong;Shin, Dong-Min;Kim, Byeong-Jun;Kim, Gyoo-Bum
    • The Journal of Engineering Geology
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    • v.29 no.4
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    • pp.483-494
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    • 2019
  • This study aimed to determine the extent of artificial aquifer recharge and to evaluate appropriate recharge techniques based on field investigations and comparative analysis of each recharge method. Characteristics of the aquifer determine the target aquifer and the recharge method for artificial groundwater recharge. Electrical conductivity surveys, drilling, permeability tests, and grain-size analysis indicate that the hydraulic conductivity of weathered soil and weathered rock is higher than that of upper unconsolidated soil. Pumping tests indicate that the groundwater level was stable at a depth of 12 m until 9 hours of pumping, but after that it dropped again, indicating anisotropic aquifer characteristics. Three types of artificial recharge method were reviewed, including recharge wells, ditches, and ponds, and a combination of two methods is proposed: a recharge well system directly injecting into weathered soil and rock sections with good permeability, and an injection ditch that can increase the recharge effect by line-type injection in the upstream area. The extent of groundwater recharge by the selected methods will be evaluated through on-site tests and if their applicability is verified, they will contribute to securing water in areas of water shortage.

Distribution Pattern of dominant Benthic Diatoms on the Mangyung-Dongjin Tidal Flat, West Coast of Korea (서해 만경-동진 조간대의 주요 우점 저서 규조류의 분포)

  • 오상희;고철환
    • 한국해양학회지
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    • v.26 no.1
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    • pp.24-37
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    • 1991
  • Marine benthic diatoms and environmental factors were studied at 60 sites on the Mangyung-Dongjin tidal flat of the west coast of Korea. Sediment samples were taken quantitatively from the upper 5 mm layer to obtain a representative estimate of the epipelic and epipsammic cell concentration. Surface sediments taken simultaneously with the quantitative diatom samples were analysed for the grain size. Exposure duration of study sites were calculated by the tide data recorded at Kunsan Outer-Harbour. Coarse sediments dominated mainly on the offshore coastal and lower tidal flat, whereas fine sediments occurred on inner and higher tidal flat. Total 371 diatom taxa were collected and the genera represented by a great number were Navicula and Nizschia. The 16 abundant species occupying more than 1% of total cell number are of the following: Paralia sulcata, Navicula sp. 1, Navicula arenaria, Cymatosira belgica, Amplora holsatica, Amphora coffeaeformis, Achnanthes hauckiana, Rhaphoneis amphiceros, Thalassionema nitzschioides. Navicula sp. 2, Dimeregramma minor, Amphora sp. 1, Cyclotella atomus, C, striata, Nitzschia kuetzingiana, Stephanodiscus sp. 1. The distribution pattern of these dominant species are described in relation to the habitat condition. Most of these species showed high densities in fine sediments. However, they occurred even silty sand and sandy sediments in low abundance. The epipsammic forms belonging to the Araphidineae and Monoraphidineae were restricted on the lower tidal flat. The typical species found in coarse sediments were: Cocconeis sp. 1, Opephora martyi, Amphora sabyii, Dimeregramma minor var. nana, Fragilaria virescens var. oblongella, F. virescens, Cocconeis grata. The higher tidal flat consisting of fine sediments showed relatively higher cell numbers than the lower tidal flat. River mouth region was the highest in abundance.

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Physical Properties of Mudbelt Sediments in the Southeastern Inner Shelf of Korea (한국 남동해역 내대륙붕 이토대 퇴적물의 물리적 성질)

  • Kim, Gil-Young;Kim, Dae-Choul;Seo, Young-Kyo;Park, Soo-Chul;Choi, Jin-Hyuk;Kim, Jeong-Chang
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.4 no.4
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    • pp.338-348
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    • 1999
  • Physical properties of mudbelt sediments in the southeastern inner shelf of Korea are studied from 14 cores. Physical properties, compressional wave velocity, and sediment texture for core sediments are analyzed. The major source of sediment in the study area is the Nakdong River. Fine-grained sediments from the river are transported northeastward by coastal circulation and the Tsushima Current, resulting in a gradual northeastward increase in porosity and a decrease in wet bulk density and velocity. The trend matches well with the bathymetry. The mean grain size appears to be the most important variable to determine the physical properties and velocity. The variations of physical properties with burial depth are dependent more strongly on sediment texture than compaction and/or consolidation. Correlations between the physical properties and the sediment texture show slight deviations from those of the continental terrace sediment in the North Pacific and inner shelf sediment in the South Sea of Korea. The velocity is higher than that of the North Pacific and the South Sea sediments between these areas. This is probably due to differences in sedimentary, environment and mineral compositions. The higher sediment velocity in the study area may also be attributed to the escape of gas from pore space which decreases void ratio.

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The Defect Characterization of Luminescence Thin Film by the Positron Annihilation Spectroscopy (양전자 소멸 측정을 이용한 발광 박막 구조 결함 특성)

  • Lee, Kwon Hee;Bae, Suk Hwan;Lee, Chong Yong
    • Journal of the Korean Vacuum Society
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    • v.22 no.5
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    • pp.250-256
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    • 2013
  • It is described that the proton beam induces micro-size defects and electronic deep levels in luminescence Thin Film. Coincidence Doppler Broadening Positron Annihilation Spectroscopy (CDBPAS) and Positron lifetime Spectroscopy were applied to study of characteristics of a poly crystal samples. In this investigation the numerical analysis of the Doppler spectra was employed to the determination of the shape parameter, S-parameter value. The samples were exposed by 3.0 MeV proton beams with the intensities ranging between 0 to ${\sim}10^{14}$ particles. The S-parameter values decreased as increased the proton beam, that indicates the protons trapped in vacancies. Lifetime ${\tau}_1$ shows that positrons are trapped in mono vacancies. Lifetime ${\tau}_2$ is not changed according to proton irradiation that indicate the cluster vacancies of the grain structure.