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그래핀 옥사이드가 탄소나노튜브기반 바이오센서 전극의 포도당 산화효소 담지능및 민감도에 미치는 영향 (Effects of the Graphene Oxide on Glucose Oxidase Immobilization Capabilities and Sensitivities of Carbon Nanotube-based Glucose Biosensor Electrodes)

  • 박미선;김도영;정민정;이영석
    • 공업화학
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    • 제26권1호
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    • pp.47-52
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    • 2015
  • 본 연구에서는 다중벽탄소나노튜브(multi-walled carbon nanotube, MWCNTs) 기반 바이오센서 전극의 포도당 산화효소(glucose oxidase, GOD) 담지능을 높여 그 민감도를 개선하고자 그래핀 옥사이드(graphene oxide, GO)를 첨가하여 전극을 제조하였다. GO 첨가로 인하여 MWCNTs의 분산뿐만 아니라 전극의 친수성 및 표면에너지가 증가하였다. 또한, MWNCTs 0.05 g에 GO 0.05 g를 첨가하였을 때 $K_m$ (Michaelis-Menten constant)이 0.105로 가장 높은 값을 나타냈음에도 불구하고 GOD 담지능이 높아졌으며, 민감도가 $121{\mu}A\;mM^{-1}$까지 향상됨을 알 수 있었다. 이러한 실험 결과는 GO첨가에 의한 MWCNTs의 분산 안정성 향상, MWCNTs 전극 표면에서 친수성으로 개질 및 표면 자유에너지 증가가 GOD 담지능에 영향을 미친 것으로 사료된다.

Synthesis and Properties of Polyimide Composites Containing Graphene Oxide Via In-Situ Polymerization

  • Zhu, Jiadeng;Lee, Cheol-Ho;Joh, Han-Ik;Kim, Hwan Chul;Lee, Sungho
    • Carbon letters
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    • 제13권4호
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    • pp.230-235
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    • 2012
  • In this study, reduced graphene oxide/polyimide (r-GO/PI) composite films, which showed significant enhancement in their electrical conductivity, were successfully fabricated. GO was prepared from graphite using a modified Hummers method. The GO was used as a nanofiller material for the preparation of r-GO/PI composites by in-situ polymerization. An addition of 20 wt% of GO led to a significant decrease in the volume resistivity of composite films by less than nine orders of magnitude compared to that of pure PI films due to the electrical percolation networks of reduced GO created during imidization within the films. A tensile test indicated that the Young's modulus of the r-GO/PI composite film containing 20 wt% GO increased drastically from 2.3 GPa to 4.4 GPa, which was an improvement of approximately 84% compared to that of pure PI film. In addition, the corresponding tensile strength was found to have decreased only by 12%, from 113 MPa to 99 MPa.

An NLP-based Mixed-method Approach to Explore the Impact of Gratifications and Emotions on the Acceptance of Amazon Go

  • Arghya Ray;Subhadeep Jana;Nripendra P. Rana
    • Asia pacific journal of information systems
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    • 제33권3호
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    • pp.541-572
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    • 2023
  • Amazon Go is a cashierless convenience store concept, which is seen as a disruption in the grocery retail segment. Although Amazon Go has the ability to disrupt the retail segment, there are speculations on how Amazon Go will be perceived by users. Existing studies have not utilized user-generated content to understand the factors that affect customer behaviour in case of Amazon Go. Additionally, in case of phygital retail, studies have not attempted at understanding the effect of emotions and gratifications on user behaviour. To address the gap of exploring user perspectives based on their experience, we have examined the impact of gratifications and emotions on the acceptance of phygital retail using user-generated-content. A mixed-method approach has been utilized using only user-generated content. Utilizing topic-modelling based content analysis and emotion analysis on 30 articles related to Amazon Go, we found themes like, convenience, technology, experience, personalization, enjoyment and emotions like, bad, good, annoyance, success. In the empirical analysis, we have utilized 522 reviews about Amazon Go from the cognition and emotion theory stance, and found that hedonic gratifications have a positive impact on challenge emotions. We also found a significant impact of emotions on customer's favourite behaviour.

청공고(淸空膏)의 내피세포 의존성 혈관이완효과 (Endothelium Dependent Vasorelaxant Action of ChungGongGo Extract on Arterial Contraction in Rabbit)

  • 오철;김호현;고흥
    • 동의생리병리학회지
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    • 제22권3호
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    • pp.666-671
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    • 2008
  • This study was undertaken to define the effect of ChungGongGo extract on norepinephrine-induced arterial contraction in rabbit. In order to investigate the effect of ChungGongGo extract on rabbit's contracted vascular ring detached from common carotid artery, vascular ring with intact or damaged endothelium was used for the experiment using organ bath. To analyze the mechanism of ChungGongGo extract-induced relaxation, ChungGongGo extract was infused into contracted vascular ring which had been pretreated by $N{\omega}$-nitro-L-arginine(L-NNA), Methylene blue(MB), and $Ca^{2+}$ was infused into contracted vascular ring induced by NE or KCl after treatment of ChungGongGo in $Ca^{2+}$-free solution. The results were as follows: ChungGongGo extract had an effective relaxation to the contracted vascular ring by NE in 1.0mg/ml and 0mg/ml level. ChungGongGo extract had an effective relaxation to the intact endothelium vascular ring, but when endothelium was removed, vascular ring did not relax. ChungGongGo extract-induced relaxation was inhibited by the pretreatment of L-NNA and MB. Pretreatment of ChungGongGo extract inhibit the contraction by influx of extra-$Ca^{2+}$ in contracted vascular ring induced by NE in $Ca^{2+}$-free solution. As mentioned above, we suggest that ChungGongGo relaxes vascular ring through suppress influx of extra-cellular $Ca^{2+}$ by the action of nitric oxide from endothelium.

HUMAN-CENTERED DESIGN OF A STOP-AND-GO VEHICLE CRUISE CONTROL

  • Gu, J.S.;Yi, S.;Yi, K.
    • International Journal of Automotive Technology
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    • 제7권5호
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    • pp.619-624
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    • 2006
  • This paper presents design of a vehicle stop-and-go cruise control strategy based on analyzed results of the manual driving data. Human drivers driving characteristics have been investigated using vehicle driving data obtained from 100 participants on low speed urban traffic ways. The control algorithm has been designed to incorporate the driving characteristics of the human drivers and to achieve natural vehicle behavior of the controlled vehicle that would feel comfortable to the human driver under low speed stop-and-go driving conditions. Vehicle following characteristics of the cruise controlled vehicle have been investigated using a validated vehicle simulator and real driving radar sensor data.

Graphene Oxide 첨가에 따른 Sn-3.0Ag-0.5Cu 무연솔더 접합부의 Electromigration 특성 분석 (Effects of Graphene Oxide Addition on the Electromigration Characteristics of Sn-3.0Ag-0.5Cu Pb-free Solder Joints)

  • 손기락;김가희;고용호;박영배
    • 마이크로전자및패키징학회지
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    • 제26권3호
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    • pp.81-88
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    • 2019
  • 본 연구에서는 그래핀 산화(graphene oxide, GO) 분말 첨가가 ball grid array(BGA) 패키지와 printed circuit board(PCB)간 Sn-3.0Ag-0.5Cu(SAC305) 무연솔더 접합부의 electromigration(EM) 수명에 미치는 영향에 대하여 보고 하였다. 솔더 접합 직후, Ni/Au표면처리된 패키지 접합계면에서는 $(Cu,Ni)_6Sn_5$가 생성되었으며 organic solderability preservative(OSP) 표면처리 된 PCB 접합계면에서는 $Cu_6Sn_5$ 금속간화합물(intermetallic compound, IMC)이 생성되었다. $130^{\circ}C$, $1.0{\times}10^3A/cm^2$ 전류밀도 하에서 EM 수명평가 결과, GO를 첨가하지 않은 솔더 접합부의 평균 파괴 시간은 189.9 hrs으로 도출되었고, GO를 첨가한 솔더 접합부의 평균 파괴 시간은 367.1 hrs으로 도출되었다. EM에 의한 손상은 패키지 접합계면에 비하여 pad 직경이 작은 PCB 접합계면에서 전자 유입에 의한 Cu의 소모로 인하여 발생하였다. 한편, 첨가된 GO는 하부계면의 $Cu_6Sn_5$ IMC와 솔더 사이에 분포하는 것을 확인하였다. 따라서, SAC305 무연솔더에 첨가된 GO가 전류 집중 영역에서 Cu의 빠른 확산을 억제하여 우수한 EM 신뢰성을 갖는 것으로 생각된다.

확률적 평가에 기반한 컴퓨터 바둑의 후보 생성 시스템 (A Candidate Generation System based on Probabilistic Evaluation in Computer Go)

  • 김영상;유기영
    • 전자공학회논문지CI
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    • 제37권2호
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    • pp.21-30
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    • 2000
  • 바둑이 진행될 때마다 적절한 후보 자리를 계산하는 모델이 있다면, 사례를 이용하지 않고도 후보 생성알고리즘의 표준으로 정립될 수 있다. 본 논문에서는 바둑을 조합 게임론에 따라서 분석하고, 흑, 백간 영역의 차이를 반면의 형세로 나타내는 확률 행렬(PM)을 기반으로 임의의 국면에 대한 후보를 생성하는 후보 본 논문에서 설계된 CGS는 임의의 국면에 돌이 놓여지면 영향력, 안정도, 살아남을 확률 값(PV), 확률행렬(PM)을 계산하고, 현 국면에 대한 적당한 후보를 생성한다. CGS의 기본 전략은 현재의 반면에 대해서 다섯 개의 후보를 생성하고 그 중에서 PV가 높은 지점을 최종 후보로 선정한다. CGS는 공격보다 방어에 주력하였으며 정석 사례를 사용하는 NEMESIS에 비해서 사례를 전혀 구축하지 않은 CGS가 초반에 있어서 다소 우세함을 보여준다.

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고분자전해질 연료전지 분리판을 위한 Ni-P-rGO 무전해 복합도금층의 미세조직 분석 (Microstructure Analysis of Ni-P-rGO Electroless Composite Plating Layer for PEM Fuel Cell Separator)

  • Kim, Yeonjae;Kim, Jungsoo;Jang, Jaeho;Park, Won-Wook;Nam, Dae-Geun
    • 한국표면공학회지
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    • 제48권5호
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    • pp.199-204
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    • 2015
  • Recently, fuel cell is a good alternative for energy source. Separator is a important component for fuel cell. In this study, The surface of separator was modified for corrosion resistance and electric conductivity. Reduced graphene oxide (rGO) was made by Staudenmaier's method. Nickel, phosphorus and rGO were coated on 6061 aluminum alloy as a separator of proton exchange membrane fuel cell by composite electroless plating. Scanning electron microscope, energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy were used to examine the morphology of Ni-P-rGO. Surface images were shown that the rGO was dispersed on the surface of Ni-P electroless plating, and nickel was combined with the un-reduced oxygen functional group of rGO.

3GPP ARQ에서 재정렬 버퍼의 점유량 조절을 위한 부분 Go back N 방식 (Partial Go back N Scheme for Occupancy Control of Reordering Buffer in 3GPP ARQ)

  • 신우철;박진경;하준;최천원
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2003년도 통신소사이어티 추계학술대회논문집
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    • pp.302-305
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    • 2003
  • 3GPP RLC protocol specification adopted an error control scheme based on selective repeat ARQ. In the 3GPP ARQ, distinctive windows are provided at transmitting and receiving stations so that those stations are prohibited to send or receive data PDU's out of window. An increase in window size enhances delay performance. Such an increase, however, raises the occupancy at re-ordering buffer, which results in a long re-ordering time. Aiming at suppressing the occupancy at re-ordering buffer, we propose partial go back N scheme in this paper In the partial go back N scheme, the receiving station regards all data PDU's between the first (lowest sequence numbered) error-detected PDU and last (highest sequence numbered) error-detected PDU. By the employment of the partial go back N scheme, the occupancy at the re-ordering buffer is apparently reduced, while the delay and throughput performance may be degraded due to the remaining properties of go back N. We thus consider peak occupancy of re-ordering buffer, mean sojourn time at re-ordering buffer, mean delay time, and maximum throughput as measures to evaluate tile proposed scheme and investigate such performance by using a simulation method. From numerical examples, we observe a trade-off among performance measures and conclude that the partial go back N scheme is able to effectively reduce the occupancy of re-ordering buffer.

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