• 한국세라믹학회지
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• 제32권10호
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• pp.1123-1130
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• 1995

In the preparation of manganese zinc ferrite powders by alcoholic dehydration of citrate/formate solution. The effect of pH change on precipitation was investigated. The pH range for obtaining stable precipitates was studied. The glassy phase was obtained when the pH value of solution is higher than 5, and the formation mechanism of glassy phase was suggested. Below pH 5, the stable precipitates were formed, and the optimal pH was 2. Formation of glassy phase was accounted for the change of surface charge by pH change. The change of surface charge is caused by the interparticular agglomeration. The precipitate was redissolved into the water on the surface of precipitate itself and through the polymerization, it agglomerated. This mechanism is tought to be similar to that of viscous flow.

• 한국세라믹학회지
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• 제24권4호
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• pp.364-368
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• 1987

The Si5AION7 specimens containing 20% YAG composition have been sintered and then heat treated to induce the crystallization of the matrix glassy phase. Crystallization of YAG phase during the heat treatment was detected from the X-ray diffraction patterns and the consequent changes in room temperature toughness as well as in microstructures were investigated. Almost all the glassy boundary phase were found to crystallize even after 5 minutes of heat treatment and the KC at room temperature decreased accordingly. The results show that the matrix crystallization can be induced by slow cooling from the sintering temperature.

• 공업화학
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• 제9권4호
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• pp.475-480
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• 1998

본 연구에서는 고밀집 glassy carbon (GC) 섬유 다발체 전극 전해계를 사용하여 우라늄 (VI)를 함유한 유기상과 질산 수용상의 혼합상에서 전해 역추출시 우라늄 (VI) 환원 전해특성 연구가 수행되었고, 이에 관한 전해 역추출 모델을 제시하였다 우라늄 (VI) 전해환원 반응은 혼합상 내의 수용상에서 보다 혼합상 내의 유기상에서 빨리 일어났다. 유기상의 유속이 증가하는 경우 역추출 과정에서 유기상 내 우라늄 이온의 확산 저항 증가에 의해서 수용상으로의 역추출은 증가하다 일정하게 되었으며, 수용상 유속 변화는 총 우라늄 (VI) 환원전류에는 영향을 주지 않았다. 전해반응이 없는 경우보다 전해 반응이 동반되는 경우 우라늄 역추출이 보다 효과적으로 이루어 짐을 알 수 있었다.

• 산업기술연구
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• 제5권
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• pp.15-20
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• 1985

The microstructure of sintered body of two component(kaolin-pottery stone) system after firing was examined with scanning electron microscope. At first the pottery stone was melted into glassy phase and the kaoline was decomposed to mullite and silica at higher temperature. The interlocked mullite crystals and silica surrounded by glassy phase are belived to increase strength.

• 한국세라믹학회지
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• 제31권7호
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• pp.777-783
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• 1994

Oxidation behavior of hot-pressed silicon nitride ceramics with various sintering additives has been investigated. The weight gain of each specimens has shown in the range of 0.11 mg/$\textrm{cm}^2$ ~3.4 mg/$\textrm{cm}^2$ at 140$0^{\circ}C$ for 192 h and eleven compositions have shown good oxidation resistance with the weight gain below 0.5 mg/$\textrm{cm}^2$. The oxidation rate has been shown to obey the parabolic rate law and the oxidized surface has consisted of $\alpha$-cristobalite and M2Si2O7 or MSiO3 (M=rare earth or transition metals) phase. The oxidation rate of each specimens has related to the eutectic temperature between additive oxide and SiO2, and ionic radius of additive oxides, respectively. From the above results, it could be concluded that the oxidation behavior of hot pressed silicon nitride is dominated by the high temperature properties of grain boundary glassy phase and the high temperature properties of grain boundary glassy phase are affected by the ionic radius of additive oxides.

• 한국세라믹학회지
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• 제16권3호
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• pp.169-177
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• 1979

The effect of apparent porosity of the fired ceramics, metallizing temperature, and metallizing mixtures on the bond strength in metal-to-ceramic seals was investigated. Three different metallizing compounds were metallized on dense alumina bodies at 1300~$1500^{\circ}C$ in dry hydrogen atmosphere. Bond strength between metal and alumina body was measured by means of nstron test machine. The greater bond strength was observed as the apparent porosity and metallizing temperature was increased. This work indicated that the glassy phase in metallizing mixture, having had sufficient fluidity to migrate into the alumina body, reacted with alumina and thereby forming strong metal-ceramic interface bond. It also showed that the glassy phase having higher thermal expansion cofficient than molybdenum might contribute to the strong bond formation by providing compressive stress around the molybdenum particle.

• 한국세라믹학회지
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• 제28권10호
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• pp.785-792
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• 1991

An investigation of the crack propagation behavior of Al2O3-33Vol.% SiCw at 140$0^{\circ}C$ was conducted with various loading frequencies. Higher crack propagation was observed in lower frequency and higher load ratios. Interface sliding fracture due to glassy phase from the oxidation of SiCw and cavitation along grain boundary of diffusional creep appeared to be the main mechanism of fatigue fracture in slower crack propagation while interface sliding and whisker pull out aided by glassy phase formation played main role of fatigue fracture for higher crack growth condition. The frequency effect on deformation behavior was discussed with a Maxwell model.

• The Korean Journal of Ceramics
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• 제2권1호
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• pp.25-32
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• 1996

Solid electroyte nasion was synthesized by the optimized solid state reaction minimizing the volume fraction of secondary $ZrO_2$ and glassy phases. To compensate for the evaporation of Na and P during heat-treatment, excess Na and P were added to the starting composition $Na_{1+x} Zr_2 Si_x P_{d-x} O_{12}$ (x=2.1). Phases pure nasicon comparable in volume fraction to the one obtaied from sol-gel process were synthesized after the reaction at $1100~1150^{\circ}C$,$ P_{O2}>=0.1-0.15 $$ZrO_2$ increased with the heat-treatment time due to the decomposition of nasicon phase and that of glassy phase increased as partial oxygen pressure decreased. The synthesized nasion showed a good electrical conductivity of $-1{\times}10^{-2}({\omega}{\cdot}cm)^{-1}$ at $350^{\circ}C$.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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• pp.705-710
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• 2001

So for the quartz-glassy crucible wastes which was used for pulling up silicon-single-crystal ingot have simply reused for refractory raw-materials, or exhausted. This study is concerned on the advanced recycling-technology that is obtained by the proper micro-particle preparation process in order to fabricate fine amorphous silica filler for EMC (Epoxy Molding Compound). Therefore, this paper will deal with the physical, chemical and thermal pre-treatment process for efficient impurity removal and with the proper micro-particle process for producing the amorphous silicafiller. In view of the results, if the chemical, physical and thermal pre-treatment process for efficient elimination of impurity was passed, the purity of wasted fused glassy crucible is almost equal to the its of first anhydrous quartz glass. Thus, it was understood that this wasted fused glassy crucible was sufficient value of recycling, though it was damaged. When the ingot was fabricated, Phase transformation of crystallization by heat treatment (heat hysteresis phenomenon) was not changed. So, it was understood that as fused silica in the amorphous state, as It is, recycling possibility was very high

• 시멘트 심포지엄
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• 1호
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• pp.23-30
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• 1973

In this paper, the reaction of the formation of portland cement clinker is reviewed. 1. When the specimen is heat-treated, the glassy phase melt with increasing temperature, and the starting materials are dissolved into the melt. After the melt is saturat