• Journal of the Korean Ceramic Society
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• v.39 no.6
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• pp.558-565
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• 2002

Coal fly ash, produced from a power plant in Korea was used for the production of glass-ceramics and the physical properties of glass-ceramics were evaluated. CaO and TiO$_2$ were added into the fly ash during the melting process to reduce the viscosity of molten glass and to induce internal crystallization of glass, respectively. Glass-ceramic was produced through a single stage heat treatment (at 950∼1050$\^{C}$ for 37∼240 min) after preparing glass (iota fly ash powder. As a result, a new tiny rod type crystals (a=7.4480, b=10.7381, c=4.3940 A, $\alpha$=94.9, $\beta$=98.6, γ=108.5°) was found in the glass-ceramics, which showed attractive mechanical properties, high hardness (7.1∼7.6 GPa) and wear resistance (by erosion test). Thus a glass-ceramic produced from thermal power plant fly ash and cell as a source for CaO exhibits a suitable treatment for the recycling and exploitation of waste materials and would be acceptable for a new application far building materials.

• Journal of the Korean Ceramic Society
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• v.22 no.2
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• pp.3-10
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• 1985

In the study the characteristics change of crystallized $Li_2O$.$Al_2O_3$.$SiO_2$ glass-ceramics when varying RO ratio and increasing Al2O3 were investigated to produce a glass-ceramics with high mechanical strength and low thermal expansion. Parent glass was obtained by melting at 1,350~1,40$0^{\circ}C$ for 3 hours and annealing at 45$0^{\circ}C$ and the various physical characteristics were measured. Results were as follows; 1. When ZnO was replaced by MgO thermal expansion coefficient was lowered when increasing ZnO content. 2. Major crystal phase was $\beta$-spodumene the crystal growth mophology was the three dimensional sphere and the activation energy for crystallization was 54.6 Kcal/mol. 3. Parent glass heat-treated at 95$0^{\circ}C$ for 10 hours had ; a) thermal expansion coeff. of $23.2{\times}10^{-7}$/$^{\circ}C$ b)whiteness of 76 c) microhardness of 1,089kg/$mm^2$

• Transactions of the Korean Society of Mechanical Engineers A
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• v.33 no.11
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• pp.1274-1278
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• 2009

Fracture characteristics for plate and dome shapes of glass filled ceramics using shock tube were carried out. Glass filled ceramics have been considered as a promising candidate material for the dome port cover of air breathing engine. This part of the air breathing engine has an important role as separated membrane between combustion and external air, and needs the frangible characteristics that the particles of fractured glass filled ceramics should not affect the internal components of combustion. The objectives of this study are to evaluate the fracture pressures for various thicknesses and diameters of shock impact area. Also fracture phenomena of separated membrane using a shock tube compare with analytical method. The experimental apparatus consists of a driver, a driven section and a dump tank. The used material is glass filled ceramic made from Corning company. Specimens have the thickness of 3, 4.5 and 6mm. It is expected that the results obtained from this study can be used in the basic data for the dome port cover design of an air breathing engine.

• Journal of the Korean Ceramic Society
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• v.43 no.5 s.288
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• pp.277-283
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• 2006

A porous material with a surface layer was fabricated from glass abrasive sludge and expanding agents. The glass abrasive sludges were mixed with expanding agents and compacted into precursors. These precursors were sintered in the range of $700-900^{\circ}C$ for 20 min. The sintered porous materials had a surface layer with smaller pores and inner parts with larger pores. The surface layer and closed pores controlled water absorption. As the expanding agent fraction and the sintering temperature increased, the porosity and pore size increased. The porous materials with $Fe_2O_3$ and graphite as the expanding agents had a low absorption ratio of about 3% or lower while the porous material with $CaCO_3$ as the expanding agent had a higher absorption ratio and more open pores.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.523-527
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• 2000

Vanadate glasses in the Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ system containing 10mo1% glass former, P$_2$O$_{5}$ were prepared by melting the batch in pt. crucib1e followed by quenching on the copper plate. We found that Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics obtained from nucleation of glass showed significantly higher capacity and longer cycle life than conventionally made crystalline LiCoO$_2$, LiNiO$_2$and LiV$_3$O$_{8}$. In the present paper, We describe electro-chemical properties during crystallization process and find the best crystallization condition of Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ g1ass as cathod material. Li$_2$O-P$_2$O$_{5}$-V$_2$O$_{5}$ glass-ceramics shows superior rechargeable capacity of 220 mAh/g in the cycling between 2.0 and 3.9V.etween 2.0 and 3.9V.

• Journal of the Microelectronics and Packaging Society
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• v.9 no.2
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• pp.19-25
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• 2002

Glass composed of $Li_2$O.MgO. $MgF_2$.$SiO_2$.$B_2O_3$ for the fabrication of green sheet was prepared by melting process, and glass ceramics was prepared by the process of nucleation and grystal growth for the glass of $Li_2$O.MgO. $MgF_2$.$SiO_2$.$B_2O_3$ system with Lithium fluorhectorite and Lithium boron fluorphlogopite crystal phase. Powderization of the glass ceramics was carried out by water swelling. The average particle size at this point was 2.574 $\mu\textrm{m}$. Slurry was prepared for green sheet using high viscous sol fabricated by water swelling, which shows cleavage phenomenon in prepared glass ceramics. The optimum ratio of powder to water for the tape casting was 18:100, and its viscosity was 11,000~14,000 cps.

• Journal of the Korean Ceramic Society
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• v.50 no.1
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• pp.70-74
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• 2013

Dependence of microwave dielectric properties on the crystallization behaviors of $CaMgSi_2O_6$ (diopside) glass-ceramics was investigated with different heat treatment methods (one and/or two-step). The crystallization behaviors of the specimens, crystallite size and degree of crystallization, were evaluated by differential thermal analysis (DTA), scanning electron microscope (SEM) and X-ray diffraction (XRD) analysis by combined Rietveld and reference intensity ratio (RIR) methods. With an increase in heattreatment temperature, the dielectric constant (K) and the quality factor (Qf) increased due to the increase of the crystallite size and degree of crystallization. The specimens heat-treated by the two-step method had a higher degree of crystallization than the specimens heat-treated by the one-step method, which induced improvement in the quality factor (Qf) of the specimens.

• Environmental Analysis Health and Toxicology
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• v.7 no.3_4
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• pp.81-84
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• 1992

Physical compositions of solid waste in Wonju, shopping area were investigated with combustibles 78.13% (papers 35.89%, foods 14.41% etc.) incombustibles 21.87% (glass and ceramics 11.02%, metals 6.0% etc.) in 1991, solid waste in apartment area were investigated with combustibles 84.27% (foods 34.29%, papers 22.58% etc.), incombustibles 15.73% (glass and ceramics 8.77%, metals 4.85% etc.) and residence area were characterised with combustibles 70.37% (foods 33.55% , papers 10.53% etc.) and incombustibles 29.63% (ash of briquet 17.29%, glass and ceramics 7.49% etc.). Water qualities of a leachate from municipal landfill of Wonju city were analysed pH 8.0~8.4, total suspended solid 102~140 mg/1, CN￣ 0.003~ 0.008 mg/1, NO$_2$-N 0.108~0.294 mg/1 and phenols 0.46~1.12 mg/1. Volume of the leachate for 20% methemoglobin formation were 0.2~0.4 mg/ml in Octever, 0.3~0.4 ml/ml in December sampling, 0.2~0.3 ml/ml in St.1 and 0.4 ml/ml in St.3.

• Journal of the Korean Ceramic Society
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• v.31 no.12
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• pp.1552-1560
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• 1994

Glasses in K2O-Na2O-MgO-Al2O3-SiO2-F system were crystallized to prepare machinable glass-ceramics. The optimum nucleating and crystal growing temperatures were approximately $700^{\circ}C$ and 1060~112$0^{\circ}C$, respectively for the samples investigated. Crystalline phases of sellaite, norbergite, and fluorphlogopite appeared progressively as heat-treatment temperature was increased. Surface roughness of the crystallized specimens after the machining was similar to that of metal aluminum (2.18 ${\mu}{\textrm}{m}$). Thermal expansion coefficient, Vickers hardness and dielectric constants of the fluorphlogopite glass-ceramics prepared were 7.37~10.21 ($\times$10-6/$^{\circ}C$), 302~456kgf/$\textrm{mm}^2$ and 5.97~16 respectively.

• Proceedings of the International Microelectronics And Packaging Society Conference
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• 1999.11a
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• pp.111-115
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• 1999

The $Li_2O-MgO-MgF_2-SiO_2$glasses with addition of $B_2O_3$ were investigated in order to make glass-ceramics for low temperature firing substrate. Glasses were made by melting at $1450^{\circ}C$ in the electronic furnace and crystallized at $750^{\circ}C$. After the crystallization, crystal phases and microstructure were observed. The crystal phases were polycrystalline of lithium boron fluorphlogopite and lithium fluorhectorite. The crystal shape was changed to grande type from needle type with the increase in $B_2O_3$ contents. Average particle size of the glass-ceramics aftar water swelling was $3.77{\mu}{\textrm}{m}$. The optimum sintering temperature and sintering shrinkage of the substrate were $900^{\circ}C$ and 13.4vol%, respectively.