• Title/Summary/Keyword: Glass recycling

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Performance Evaluation of Admixture for Durability Improvement of Shielding Materials Used Waste Glass as Fine Aggregate (폐유리를 잔골재로 사용한 차폐채움재의 내구성 개선을 위한 혼화재료의 성능평가)

  • Hwang, Byoung-Il;Kim, Hyo-Jung;Song, Yong-Soon;Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.2
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    • pp.20-27
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    • 2019
  • Compared to the development and manufacturing technology of electronic goods, the development of waste glass recycling technology is relatively insufficient, leading to the acceleration of waste of resources and environmental pollution. Although waste glass recycling technology is being actively developed overseas, waste glass recycling technology is insufficient in Korea, leading to the illegal dumping or burial of waste glass. Waste glass has been confirmed to have pozzolan reaction potential when having hydration reaction with cement. Waste glass is also reported to be effective in reducing bleeding and inhibiting the development of hydration heat by improving the physical properties of concrete and the rheology properties of fresh concrete. Therefore, this paper analyzed the strength characteristics and the effect of alkalic-silica reaction on the expansion of shielding concrete that used waste glass as fine aggregate. Where, suitable admixture materials were used as a measure to suppress the expansion.

Physical and Chemical Properties of Waste LCD Glass as Raw Materials for the Production of Foamglass (발포유리 제조원료로서 폐 LCD유리의 물리화학적 특성)

  • Lee, Chul-Tae;Lee, Jinsoo;Jang, Moonho;Lee, Sunyoung
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.266-272
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    • 2009
  • Physical and chemical properties of waste LCD glass were investigated to test the feasibility of feed materials for the production of foamed glass. For this study, chemical analysis, thermal analysis, rheological consideration with the viscosity change under high temperature and thermal expansion coefficient were carried out and the trial production of foamed glass as; in spherical and block type also attempted. All results showed waste LCD glass would be a good feed material for the production of foamed glass and foaming technology of LCD glass would be an effective recycling alternative.

Developing An Extracting Method of Laminated Glass-Fiber for Waste FRP Boats Regenerating (폐FRP 선박의 재자원화를 위한 유리면포 추출장치 개발)

  • Yoon, Koo-Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.1
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    • pp.50-54
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    • 2008
  • There are several basic classes of recycling methods for FRP boats. The main one is 'Mechanical recycling' which involves shredding and grinding of the scrap FRP in a new product. That is one of the simpler and more technically proven methods. It recently has been reported that FRP can be recycled by separating into layers instead of crushing into powder. Many researchers should be more interested in these mechanical recycling for the eligibility. Nevertheless, because resins is very useful renewable energy, most of waste FRP regenerating methods depend on incineration (reclamation) or thermal recycling (pyrolysis). FRP is made up of laminated glass- fiber (roving cloth layer) which is also very unlikely to break into each layer. If there is an extracting method which is efficient and environment friendly removing glass fiber from waste FRP, it should also solve the another urgent problem. Laminated glass-fiber which is very limited renewable, is a serious barrier to wast FRP boat regenerating. This study is to propose a new extracting method which is efficient and environment friendly waste FRP regenerating system. And it should be applied to renewable energy applications with the waste resins of FRP. Also recycling glass fiber obtained by the separation of the roving layer from waste FRP will be consider to be useful for concrete products or structures.

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A Study on Improvement of Recycling Process of Waste Fluorescent Lamps (폐형광등 재활용 공정의 개선 연구)

  • Lee, Gee Hun;Lee, Dong Hoon;Song, Young Jun;Kim, Chang Kwon
    • Resources Recycling
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    • v.29 no.3
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    • pp.61-74
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    • 2020
  • This study was conducted to improve the recycling process of waste fluorescent lamp, and investigate the possibility of using the waste fluorescent lamp glass as a raw material for glass beads, the leaching method of rare earth from the waste phosphor powder, and the possibility of solvent extraction of rare earth from the rare earth leaching solution. The waste phosphor contained 28.9% yttrium oxide, 3.46% cerium oxide, 1.95% europium oxide, 1.76% terbium oxide, and 1.43% lanthanum oxide. As a result of the trial production of glass beads using waste fluorescent lamp glass, it was judged that the production yield and quality were excellent, so that waste fluorescent lamp glass could be used as a raw material for glass beads. The soda roasted waste phosphor was leached in water and thereby the aqueous solution was blown with CO2 to drop the pH to about 7, Then, Al, Si and residual N2CO3 were dissolved, and NaAlCO3(OH)2 and SiO2 were precipitated in the aqueous solution. In the solvent extraction of cyanex272-hydrochloric acid, cyanex272-sulfuric acid, D2EHPA-hydrochloric acid, D2EHPA-sulfuric acid, Ionquest290-hydrochloric acid, Ionquest290-sulfuric acid, p507-hydrochloric acid using xylene as a diluent, the extraction yield of Y, Eu, Ce, La, and Tb are close to 100%. However, in this conditions, the difference in extraction yield for each element, that is, selectivity is 16% or less.

Material Flow Analysis and Impact of Greenhouse Gas Reduction by Glass Bottle Recycling (유리병 물질흐름 분석과 재활용에 따른 온실가스 감축 영향 분석)

  • SukWon Jung;Yong-Chul Jang
    • Journal of Environmental Impact Assessment
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    • v.33 no.5
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    • pp.204-213
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    • 2024
  • Greenhouse gas (GHG) emissions are a major cause of global warming and climate change, and are currently emerging as serious environmental problems worldwide. Among them, glass bottles do not decompose naturally, and a lot of resources and energy are input into the production and processing processes, so recycling of glass bottles is important in terms of resource conservation, minimizing environmental pollution, and reducing GHG. Therefore, this study created a material flow diagram of glass bottles using related statistical data such as domestic glass bottle production and processing volume. In addition, the US EPA WARM model, Germany Prognos calculation method, and Denmark Christensen's calculation method were used to estimate the greenhouse gas reduction amount of glass bottles. As a result of the study, out of about 490,000 tons of waste glass bottles discharged as municipal waste, about 300,000 tons (61.2%) were recycled, and the rest were incinerated (22.1%) and landfilled (17.3%). As of 2022, it is estimated that approximately 73,399 tons CO2eq/yr will be reduced when applying the US EPA WARM model, approximately 52,847 tons CO2eq/yr when applying the Prgonos calculation method, and approximately 135,201 tons CO2eq/yr when applying the Christensen's calculation method. Further research is warranted that the methodology and GHG saving emission factors by reflecting glass recycling conditions and processes in Korea should be developed to reduce uncertainty of the results.

An experimental study on the durability of steel fiber reinforced concrete containing waste glass (폐유리를 활용한 강섬유보강 콘크리트의 내구성에 관한 실험적 연구)

  • 정명일;조광연;이봉춘;김경훈;박승범
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.841-846
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    • 2002
  • As growing of industrialization and increasing of population. the quantities of waste are rapidly growing in the earth. It cause some problems such as the waste of natural resources and environmental pollution. In this context, recycling waste glass as a material of concrete has a great advantage environmentally and economically. On that score, other contries have start recycling waste glass widely and accoumulatig the technology of manufacturing equipment and construction. However, few studies have been done in this country. Therefore, this study was conducted freeze-thaw resistance test and neutralization reaction test to analyze the durability properties of steel fiber reinforced concrete containing waste glass as fine aggregate and containing industrial by-products(Fly ash).

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Developing a Study on the Extracting Method of Laminated Glass Fiber from FRP Boats (폐FRP 선박으로부터 섬유보강재 추출공정 개선 연구)

  • Yoon, Koo-Young
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.1
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    • pp.23-28
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    • 2009
  • There is several ways of recycling methods for waste FRP boats. The main one is mechanical recycling that is one of the simple and technically proven methods. It recently has been reported that FRP can be recycled by separating into laminated glass fiber layers instead of crushing into powder. Even though the mechanical recycling is a good way for the eligibility of laminated glass fiber reinforced material, the system should have another option which can collect resin of FRP. Because the resin is still very useful renewable energy source, that cannot be discarded, But FRP is made up of laminated glass fiber(roving cloth layer) which is fire retardant substances and very hard to break into each layer. Due to the high cost of fossil energy the waste plastics should be regenerated to the source of renewable energy. Laminated glass fiber which is recyclable in a very limited way, is currently a serious barrier to waste FRP boat regenerating. This study is to propose a new extracting method which is efficient and environment friendly FRP waste regenerating system. The recycled glass fiber which is obtained by the separation of the roving layer from FRP waste has been found to be useful for concrete(FRC) products or concrete(FRC) structures as fiber reinforced material. And it can be successively applied to renewable energy applications using the waste resins of FRP residue without laminated glass fiber.

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A Study on the Recovery of Lithium from Secondary Resources of Ceramic Glass Containing Li-Al-Si by Ca-based Salt Roasting and Water Leaching Process (Li-Al-Si 함유 유리세라믹 순환자원으로부터 Ca계열 염배소법 및 이에 따른 수침출 공정에 의한 리튬의 회수 연구)

  • Sung-Ho Joo;Dong Ju Shin;Dongseok Lee;Shun Myung Shin
    • Resources Recycling
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    • v.32 no.1
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    • pp.42-49
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    • 2023
  • The glass ceramic secondary resource containing Li-Al-Si is used in inductor, fireproof glass, and transparent cookware and accounts for 14% of the total consumption of Li, which is the second most widely used after Li-ion batteries. Therefore, new Li resources should be explored when the demand for Li is exploding, and extensive research on Li recovery is needed. Herein, we recovered Li from fireproof Li-Al-Si glass ceramic, which is a new secondary resource containing Li. The fireproof glass among all Li-Al-Si glass ceramics was used as raw material that contained 1.5% Li, 9.4% Al, and 28.9% Si. The process for recovering Li from the fireproof glass was divided into two parts: (1) calcium salt roasting and (2) water leaching. In calcium salt roasting, a sample of fireproof glass was crushed and ground below 325 mesh. The leaching efficiency was compared based on the presence or absence of heat treatment of the fireproof glass. Moreover, the leaching rates based on the input ratios of calcium salt, Li-Al-Si glass, and ceramics and the leaching process based on calcium salt roasting temperatures were compared. In water leaching, the leaching and recovery rates of Li based on different temperatures, times, solid-liquid ratios, and number of continuous leaching stages were compared. The results revealed that fireproof glass ceramics containing Li-Al-Si should be heat treated to change phase to beta-type spodumene. CaCO3 salt should be added at a ratio of 6:1 with glass ceramics containing Li-Al-Si, and then leached 4 times or more to achieve a recovery efficiency of Li over 98% from a solution containing 200 mg/L of Li.

A Basic Study for Manufacturing High Refractive Beads from the Waste Fluorescent Glass (폐형광등 유리를 활용한 고굴절 글래스비드의 제조 연구)

  • Lee, Gee Hun;Lee, Dong Hoon;Song, Young Jun;Kim, Chang Kwon
    • Resources Recycling
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    • v.29 no.3
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    • pp.51-60
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    • 2020
  • This study was carried out to get the optimum conditions for manufacturing high refractive glass beads from waste fluorescent lamp glass. Chemical composition, X-ray diffraction pattern, particle size distribution, refractive index of glass beads, and the effect of air mixing ratio and ejection rate were investigated. The obtained results are as follows. The X-ray diffraction pattern and chemical composition of glass beads made of waste fluorescent glass are similar to common glass except ReO2 0.0108 wt%, BaO 0.071 wt%, NiO 0.0039 wt% and CaO 7.8 wt% but 11.7 wt% of common glass. The glass beads made of waste fluorescent lamp glass have the narrower particle size distribution of and the higher refractive index than the glass beads made of common glass. The optimal conditions of kiln operation for manufacturing glass beads from waste fluorescent lamp glass are 20 m/sec of ejection rate, 1.7 of air mixing ratio, and 940℃ of temperature.