• Title/Summary/Keyword: Glass recycling

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The Characteristics of P.H.C Pile using Admixture by Waste TFT-LCD Glass Powder (폐 TFT-LCD 유리분말을 혼입한 고강도 콘크리트 파일의 특성)

  • Jeon, Seong-Hwan;Min, Kyung-San;Soh, Yang-Seob
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.419-425
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    • 2010
  • In order to examine the P.H.C pile raw material using glass forming ceramic. The used materials is ordinary portland cement, waste TFT-LCD glass powder and reactive agent(Ca$(OH)_2$). The first experiment is characteristics analysis of the waste TFT-LCD glass powder, For the second experiment is mortar and concrete compressive strength for using of the concrete file raw material for waste TFT-LCD glass powder. The results of experiment showed that the substitution ratio of 10% waste TFT-LCD glass powder and 1% reactive agent(Ca$(OH)_2$) was excellent at a point of view for the physical characteristic. The study's most important finding is that the recycling of waste TFT-LCD glass powder.

Immobilized ${\beta}-Cyclodextrin$ as a Simple and Recyclable Method for Cholesterol Removal in Milk

  • Kwak, H.-S.;Kim, S.-H.;Kim, J.-H.;Choi, H.-J.;Kang, J.
    • Archives of Pharmacal Research
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    • v.27 no.8
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    • pp.873-877
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    • 2004
  • This study was designed to determine the optimum conditions of three different factors (mixing time, mixing temperature, and tube size) in reduction of cholesterol in milk using immobilized $\beta$-CD beads. Immobilized $\beta$-CD glass beads were prepared at different conditions of silaniza-tion and $\beta$-CD immobilization reactions. In result, the glass beads (diameter 1 mm) at 20 mM 3-isocyanatopropyltriethoxysilane and 30 mM $\beta$-CD without base showed the highest choles-terol removal rate as 41%. Using above immobilized $\beta$-CD glass beads, the cholesterol removal rate was 40.2% with 6 h of mixing time in 7 mm diameter tube at $10^{\circ}C$. After choles-terol removal from milk, the glass beads were washed for cholesterol dissociation and reused. In recycling study, the cholesterol removal rate was 41%, which was mostly same as that using new glass beads. These results indicated that cholesterol removal rate was about 40% with $\beta$-CD immobilized glass beads, however, the recycling efficiency was almost 100%.

Properties of Wollastonite-Reinforced Glass-Ceramics Made from Waste Automobile Glass and Waste Shell

  • Yun, Yeon-Hum;Yoon, Chung-Han;Kim, Chi-Kyun;Hwang, Kyu-Seog
    • Resources Recycling
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    • v.13 no.1
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    • pp.54-58
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    • 2004
  • Wollastonite-type glass ceramics were prepared by milling and firing at various temperatures using an automobile waste glass and waste shell as starting materials. Powder mixture ground by disk-type ball mill for 3 hours was pressed into a disk. The pressed specimen was fired at $850^{\circ}C$,$950^{\circ}C$ and $1050^{\circ}C$ for 1 hour in air. From FE-SEM observation, with an increase of the firing temperature from $850^{\circ}C$ to $1050^{\circ}C$, whisker-type phase was grown to about 10 $\mu\textrm{m}$ in length. Specimen fired at $1050^{\circ}C$ showed the formation of well-crystallized whisker-type wollastonite grains and the highest compressive strength.

Physical Characteristics of Cement Mortar Prepared Using Waste Glass and Graphene Oxide (폐유리와 산화 그래핀을 사용한 시멘트 모르타르의 물성 연구)

  • Kim, Kyoungseok;Chu, Yongsik
    • Resources Recycling
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    • v.28 no.6
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    • pp.54-63
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    • 2019
  • This study investigated on the compressive strength and the length change test with using the waste glass and graphene oxide for recycling the waste glass as the aggregate. Curing on 3-day and 7-day, the compressive strength was enhanced as the usage of waste glass was increased. Especially, the huge difference in the compressive strength was observed when the amount of substituting on the waste glass was used on 10~50%. With 50% of waste glass condition, the compressive strength was portionally enhanced as the usage of graphene oxide was increased and its value was 42.6 N/㎟ with 0.2% of graphene oxide. In terms of the length change test, the use of high content of waste glass led length change value to increase, but it was dropped down as the portion of waste glass was above 50%. Furthermore, in the case of using 50% of waste glass, the use of high amount of graphene oxide tended to decrease the length change value. That is, graphene oxide may contribute on boosting the cement hydration reaction and blocking the ion's movement.

A Study on the Thermal Properties of Glass for Effective Salvage Process of Flat Cathode-ray Tube (평면 음극선관의 재생률 향상을 위한 유리재료의 열적 특성에 관한 연구)

  • Park, Sang-Hu;Lee, Bu-Yun;Kim, Won-Jin;Heo, Bo-Seok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.12
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    • pp.1988-1994
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    • 2001
  • The CRT(Cathode-ray Tube) of salvage is a process of separating the panel and funnel to recycle a cathode-ray tube. In this paper, the thermal properties of glass for CRT were studied to improve its recycling ratio. In the salvage process, several patterns of breakage, as called 'comer pull', were easily generated on the sealing surface of panel or funnel glass due to the residual tensile stress, which had correlations with some parameters of the manufacturing process of CRT and the initial material properties of glass. Finite element analyses and experimental approaches on the flit sealing process were carried out to obtain the major characteristic of glass related to the residual stress. From this study, it was identified that the thermal expansion coefficient of glass had much influence on the residual stress of panel glass after frit sealing process. Therefore, the optimal conditions of thermal properties for CRT glass were proposed to achieve an effective salvage process. By using these optimal conditions, the size of comer pull on the panel and funnel glass was reduced to 10% level compared with the original size, and the recycling ratio of CRT was increased in the salvage process.

Environmental Impact Assessment of Beverage Containers (음료 포장용기의 환경성 평가)

  • Seo, Yong-Chil;Chung, Jae-Chun;Shim, Sang-Guel;Kwon, Dong-Myung
    • Clean Technology
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    • v.3 no.1
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    • pp.88-95
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    • 1997
  • Energy required, air emission, and solid waste generation are calculated with available foreign data ad domestic status using Life Cycle Analysis in order to compare the environmental impact of beverage containers such as PET bottle, aluminum can, glass bottle, and paper pack. Glass bottles are found to be the worst acceptability when considering only recycling rate of glass cullet, however it becomme the best when the refill(reuse) rate of glass bottles is accounted into. To assess tile current and future environmental impact of beverage containers, energy required, air emission, solid waste generation of current data and recycling goals are compared. As a result of the study, recycling of each containers and the reuse of glass bottles must be increased by governmental enforcement to reduce the environmental impacts by beverage containers. Further study on this subject using detailed LCA(life cycle assessment) data should be implemented for the exact environmental and economic assessment.

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Recycling of Separate Glass Fiber from Waste Printed Circuit Boards Using Attrition Mill and DMF (어트리션 밀과 DMF 용매를 이용한 폐 인쇄회로기판에서 분리된 재생 유리섬유의 재활용)

  • Kim, Jong-Seok;Lee, Jae-Cheon;Jeong, Jin-Ki
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.894-899
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    • 2012
  • In recent years, recycling process has come to be necessary for separating metals, glass fibers and polymer from WPCBs (waste printed circuit boards) due to an increasing amount of electronic device waste. In this study, dimethylformamide (DMF) and attrition mill reactor were used to separate the component such as metals, glass fiber and epoxy resin from WPCBs. Separation of glass fiber from WPCBs was carried out under stirring rates 300~600 revolution per minute (rpm) for 1~2 h as the various agitator. The recycled glass fibers (RGF) were analyzed by thermogravimetric analyzer (TGA) for degree of separation of epoxy resin in the WPCBs. The degree of separation of epoxy resin of WPCBs increased in attrition mill agitator as a mechanochemical process for recycling WPCBs. The RGF separated in the WPCBs was applied as a reinforcement in the RGF/unsaturated polyester composites to reuse as a reinforcement.

The Effect of Remelting Cycles and Its Carbon Content on the Glass Forming Ability and Mechanical Properties of the Zr-based Amorphous Alloy Return Scrap (Zr 기지 비정질 합금 스크랩의 비정질 형성능 및 기계적 성질에 미치는 재용해 횟수와 탄소 함량의 영향)

  • Lee, Byung-Chul;Kim, Sung-Gyoo;Park, Bong-Gyu;Park, Heung-Il;Park, Hwa-Soon
    • Journal of Korea Foundry Society
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    • v.34 no.3
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    • pp.94-99
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    • 2014
  • A commercially used Zr-based amorphous alloy was recycled and the effects of introducing carbon during recycling on the glass forming ability and mechanical properties of the alloy were investigated. The initial carbon content used in this study was 229ppm. The carbon content was gradually increased as the number of recycling iterations was increased and after the $4^{th}$ recycling it rapidly increased. As return scrap was recycled, polygonal particles precipitated, and they were identified as ZrC. The amount of the precipitates also increased with recycling. Tg, Tx and ${\Delta}T$ of the base alloy were 615 K, 696 K and 81 Kr respectively and they changed to 634 K, 706 K and 72 K after the $10^{th}$ recycling. The decrease of the ${\Delta}T$ value indicates deterioration of the glass forming ability. Hardness was not changed during three iterations of recycling but after the $4^{th}$ recycling it significantly increased. This is ascribed to an increase of amount of the hard particles, namely ZrC.

Preparation of Glass-Ceramic by Recycling of Various Slags and Its Properties (다종슬래그를 재활용한 Glass-Ceramic의 제조 및 물성)

  • Lee, Duk-Hee;Shin, Dongyoon;Yoon, Mijung;Park, Hyun Seo;Yoon, Jin-Ho
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.266-270
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    • 2016
  • Glass-ceramics were developed many years ago and have been applied in many fields such as electronics, chemistry, optics, etc. Much is already known about glass-ceramic technology, but many challenges in glass-ceramic research are still unresolved. Recently, large amounts of slag have steadily increased in the steel industry as by-products. To promote recycling of industrial waste, including steel industry slags, many studies have been performed on the fabrication of basalt-based high-strength glass-ceramics. In this study, we have fabricated such ceramics using various slags to replace high performance cast-basalt, which is currently imported. Glass-ceramic material was prepared in similar chemical compositions with commercial cast-basalt through a pyro process using slags and power plant by-product (Fe-Ni slag, converter slag, dephosphorization slag, Fly ash). The properties of the glass-ceramic material were characterized using DTA, XRD, and FE-SEM; measurements of compressive strength, Vicker's hardness, and abrasion were carefully performed. It is found that the prepared glass-ceramic material showed better performance than that of commercial cast-basalt.

Acid Resistance of Unsaturated Polyester Mortar Using Crushed Wate Glass (폐유리를 골재로 사용한 불포화폴리에스테르 모르타르의 내산성에 관한 연구)

  • 한창호;최길섭;김완기;조영국;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.04a
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    • pp.339-342
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    • 2000
  • Recently, the importance of the conutermeasures for waste materials has pointed out. Waste glass is also one to waste materials used for the recycling in construction sites. The crushed waste glass has been used to make a glass polymer composite that can be applied for sewer, storm drain pipe and interlocking block, etc. In this study, the crushed waste glass is explored with the possibility of recycling it, as a substitute for fine aggregates. The prepose of this investigation is to improve the strengths and acid resistance of the UP mortars using crushed waste glass. The UP mortars are prepare with blast furnace slag fly ash filler. the UP-fine aggregate ratios the crushed waste glass replacements for fine aggregate are tested strengths before and after immersion(H (아래첨자2)SO(아래첨자4) 10%), weight change and acid resistance are also tested. From the test results, the relative strength or UP mortars using fly ash as filler are found to be somewhat superior to that of the UP mortars using blast furnace as filler, And a UP mortar with fly ash as a filler, a UP-fine aggregate ratio of 15% and a waste glass replacement if 50% for fine aggregate is recommended as optimal mix proportion of UP mortar using crushed waste glass. Accordingly, it is enough to assure the use of the crushed waare glass as an aggregate for the production of UP mortar.

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