• 제목/요약/키워드: Glass formulation

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Binary Metal Oxide ($IrO_2-RuO_2$) pH Sensor Prepared by Sol-gel Method (Sol-gel 법을 이용한 이성분 금속산화물 ($IrO_2-RuO_2$) pH 센서)

  • Lee, Jeong-Ran;Oh, Se-Lim;Han, Won-Sik;Hong, Tae-Kee
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.2
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    • pp.190-196
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    • 2014
  • The sol-gel method was used to prepare binary metal oxide ($IrO_2-RuO_2$) pH sensor. The electrodes that mole percent compositions (mol%) of $IrO_2$ and RuO2 were 70:30 and 30:70 were selected. The characterizations of Nernstian response over pH range, response rate, interference on alkaline metals and reproducibility were investigated. Also the electroanalytical properties of these electrodes were evaluated in comparison with a commercial glass pH electrode. The composition of $IrO_2:RuO_2$ 70:30 mol% was chosen as better electrode formulation. The electrode was not susceptible to the action of interfering ions such as $Li^+$, $Na^+$ and $K^+$.

Dynamic prediction fatigue life of composite wind turbine blade

  • Lecheb, Samir;Nour, Abdelkader;Chellil, Ahmed;Mechakra, Hamza;Ghanem, Hicham;Kebir, Hocine
    • Steel and Composite Structures
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    • v.18 no.3
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    • pp.673-691
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    • 2015
  • In this paper we are particularly focusing on the dynamic crack fatigue life of a 25 m length wind turbine blade. The blade consists of composite materiel (glass/epoxy). This work consisted initially to make a theoretical study, the turbine blade is modeled as a Timoshenko rotating beam and the analytical formulation is obtained. After applying boundary condition and loads, we have studied the stress, strain and displacement in order to determine the critical zone, also show the six first modes shapes to the wind turbine blade. Secondly was addressed to study the crack initiation in critical zone which based to finite element to give the results, then follow the evolution of the displacement, strain, stress and first six naturals frequencies a function as crack growth. In the experimental part the laminate plate specimen with two layers is tested under cyclic load in fully reversible tensile at ratio test (R = 0), the fast fracture occur phenomenon and the fatigue life are presented, the fatigue testing exerted in INSTRON 8801 machine. Finally which allows the knowledge their effect on the fatigue life, this residual change of dynamic behavior parameters can be used to predicted a crack size and diagnostic of blade.

Modelling of the interfacial damping due to nanotube agglomerations in nanocomposites

  • Jarali, Chetan S.;Madhusudan, M.;Vidyashankar, S.;Lu, Y. Charles
    • Smart Structures and Systems
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    • v.19 no.1
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    • pp.57-66
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    • 2017
  • Nanocomposites reinforced with carbon nanotube fibers exhibit greater stiffness, strength and damping properties in comparison to conventional composites reinforced with carbon/glass fibers. Consequently, most of the nanocomposite research is focused in understanding the dynamic characteristics, which are highly useful in applications such as vibration control and energy harvesting. It has been observed that those nanocomposites show better stiffness when the geometry of nanotubes is straight as compared to curvilinear although nanotube agglomeration may exist. In this work the damping behavior of the nanocomposite is characterized in terms of loss factor under the presence of nanotube agglomerations. A micro stick-slip damping model is used to compute the damping properties of the nanocomposites with multiwall carbon nanotubes. The present formulation considers the slippage between the interface of the matrix and the nanotubes as well as the slippage between the interlayers in the nanotubes. The nanotube agglomerations model is also presented. Results are computed based on the loss factor expressed in terms of strain amplitude and nanotube agglomerations. The results show that although-among the various factors such as the material properties (moduli of nanotubes and polymer matrix) and the geometric properties (number of nanotubes, volume fraction of nanotubes, and critical interfacial shear stresses), the agglomeration of nanotubes significantly influences the damping properties of the nanocomposites. Therefore the full potential of nanocomposites to be used for damping applications needs to be analyzed under the influence of nanotube agglomerations.

Hard Coatings on Polycarbonate Plate by Sol-Gel Reaction of (3-glycidoxypropyl)trimethoxysilane (폴리카보네이트 판 위에 (3-glycidoxypropyl)trimethoxysilane의 졸-겔 반응을 이용한 하드 코팅)

  • Kim, Ju Youn;Shin, Young Jae;Shin, Youn Rok;Ji, Young Jon;Yoon, Yeo Seong;Shin, Jae Sup
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.170-176
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    • 2006
  • The hard coatings on the polycarbonate plate were performed with the object of substitution the glass in the car to the polycarbonate plate. In this research, (3-glycidoxypropyl)trimethoxysilane (GPTMS), (3-aminopropyl)triethoxysilane (APS), and diethylenetriamine (DETA) were used to prepare the coatings by a sol-gel process. The optimum conditions and formulation to achiere the excellent physical properties of the coating were determined. In the case of using GPTMS and DETA, the smooth coating which had the 2 H class in pencil hardness was formed. In the case of using GPTMS and APS, the coating which had the 2 H class in pencil hardness was also formed. And the coatings with GPTMS and DETA showed an excellent abrasion resistant.

Evaluation of Engineering Properties of Retaining Wall Material Using Fiber Reinforcement (섬유보강재를 이용한 흙막이 벽체 재료의 공학적 특성평가)

  • Lee, Jong-Ho;Lee, Kang-Il;Yu, Nam-Jae;Kim, Yong-Seong
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.4
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    • pp.243-252
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    • 2019
  • Recently, as the utilization of underground space increases, the demand for underground excavation increases. In this study, the concrete mixture with a new material was used to develop and evaluate the stability of the CS-H wall that can greatly minimize the problems of existing wall and minimize the impact of ground depression and surrounding ground that may occur in the future for excavation of over 30 m deep in urban areas. The fiber reinforcement formulation of steel fibers, synthetic fibers, and glass fibers, along with fine aggregate parts of PS-ball and ferronickel, were mixed. The Mixture ratios were determined by conducting slump test compresive strength test, modulus of elastic test, flexural strength test, splitting tensile strength test and conductivity test. As a result of the test, the steel fiber mixture showed very good results compared to other reference values in all items, and it is considered to be the most suitable for the CS-H wall to be developed.

Improving printability by designing a multi-layered coating structure (I) - The effect of binder properties in the pre-coating layer on the characteristics of the top-coating layer - (다층도공층의 설계에 의한 인쇄적성 개선 (제1보) - 프리코팅층의 바인더 물성이 탑코팅층의 특성에 미치는 영향 -)

  • Kim, Sun-Kyung;Won, Jong Myoung;Lee, Yong-Kyu
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.48 no.1
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    • pp.27-33
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    • 2016
  • This study was carried out in order to investigate the effect of binder properties in pre-coating layer on the characteristics of top-coating layer and print mottle of coated paper. Four different latices were used as a binder in pre-coating layer, and coating color prepared with a same formulation was applied for top-coating. The properties and print mottle of coated paper were evaluated. It was found that glass transition temperature (Tg) was the important factor to control the properties of pre- and top-coating layer. PPS roughness of coated paper was decreased and paper gloss was increased with applying binder which has lower Tg. Properties of top-coating layer were affected by the binder used in pre-coating layer. Print mottle of coated paper was improved with using binder which has lower Tg in pre-coating layer. These results indicate that final printability and properties of top-coating layer can be improved with using suitable binder in pre-coating layer.

Hard Coatings on Polycarbonate Plate by Sol-Gel Reactions of Silicates and Melamine Derivative (폴리카보네이트 판 위에 Silicates와 Melamine 유도체의 졸-겔 반응을 이용한 하드 코팅)

  • Kim, Se-Ra;Kang, Min-Kyung;Shin, Young-Jae;Oh, Mee-Hye;Yoon, Yeo-Seong;Shin, Jae-Sup
    • Polymer(Korea)
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    • v.31 no.6
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    • pp.485-490
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    • 2007
  • Hard coating was made on a polycarbonate plate using a sol-gel process with a melamine derivative and silicates, and examined as potential substitutes for automobile glass. Methylated poly(melamine-co-formaldehyde), tetraethoxysilane, and phenyltriethoxysilane were used to form a coating solution. The coatings on the polycarbonate plate were deposited using a sol-gel process. Poly(methyl methacrylate) was coated on the surface of polycarbonate in order to improve adhesion property. The optimum conditions and formulation to obtain excellent physical properties of the coating were determined. Adding the melamine derivative to the coating solution, the pencil hardness of the coating was improved. The hardness of a 3H class pencil, excellent abrasion resistance, and surface uniformity were found in the coated polycarbonate surface.

Hard Coatings on Polycarbonate Plate by Sol-Gel Process (폴리카보네이트 판 위에 졸-겔 과정을 이용한 하드 코팅)

  • Ji, Young Jon;Kim, Hae Young;Yoon, Yeo Seong;Lee, Seung Woo;Shin, Jae Sup
    • Journal of Adhesion and Interface
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    • v.6 no.3
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    • pp.10-18
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    • 2005
  • The hard coatings on the polycarbonate plate were performed with the object of substitution the glass in the car to the polycarbonate plate. In this research, tetraethyl orthosilicate (TEOS), methyltriethoxysilane (MTES) were used to prepare the coatings by sol-gel process. The optimum conditions and formulation to get the excellent physical properties were determined. The pretreatment condition of polycarbonate plate, the mole ratio of TEOS and MTES, selection of the solvent, the aging time, the amount of acid catalyst, and the number of folds of coating were characterized. Pretreatment with poly(methyl methacrylate) was very effective to increase the adhesion strength. The smooth coating which got the 2 H class in pencil hardness was formed in this research by sol-gel process.

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Align-free Micro-optic Mach-Zehnder Interferometric Filter (정렬에 무관한 마이크로옵틱 마하젠더 간섭계형 필터)

  • Lee, Jong-Hoon;Kim, Hyun-Deok;Song, Jae-Won
    • Korean Journal of Optics and Photonics
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    • v.17 no.3
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    • pp.285-289
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    • 2006
  • A novel alignment-free micro-optic MZI filter has been demonstrated. The filter is composed of two fiber-pigtailed collimators and a beam-splittingplate with a periodically etched stripe pattern. We fabricated the plate through a standard lithographic formulation process by using a pyrex substrate glass with SU-8 resist coating on its one of the surfaces. The maximum insertion loss of the implemented filter was less than 2 dB over 1000 nm to 1600 nm and the extinction ratio was larger than 33 dB. The measured PDL within the 3-dB pass band of the filter was less than 0.15dB and the maximum extinction ratio variation was less than 2 dB even when the worst alignment error occured.

Determination of major and minor elements in low and medium level radioactive wastes using closed-vessel microwave acid digestion (밀폐형 극초단파 산분해법을 이용한 중${\cdot}$저준위 방사성폐기물의 성분 원소 분석)

  • Lee Jeong-Jin;Pyo Hyung-Yeal;Jeon Jong-Seon;Lee Chang-Heon;Jee Kwang-Yong;Ji Pyung-Kook
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.4
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    • pp.231-238
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    • 2004
  • The conditions are obtained for the decomposition of solid radioactive wastes, including ion exchange resin, zeolite, charcoal, and sludge from nuclear power plant. In the process of decomposing the radioactive wastes was used the microwave acid digestion method with mixed acid. The solution after acid digestion by the following method was colorless and transparent. Each solution was analyzed with ICP-AES and AAS and the recovery yield for 5 different elements added into the simulated radioactive wastes were over $94{\%}$. The elemental analysis of destructive low and medium level radioactive wastes by the proposed microwave acid digestion conditions concerning the chemical characteristics of each radioactive waste are expected to be useful basic data for development of optimal glass formulation.

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