• Title/Summary/Keyword: Glass content

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Feasibility on Fillers for Bismate Glass System Used for Etching Process in Barrier-Ribs

  • Sung, Woo-Kyung;Jeon, Jae-Sam;Chong, Eu-Gene;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.938-941
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    • 2006
  • It is suggested that the bismate glass system is one of alternatives to the lead glass for barrier-ribs in PDP. Moreover it is necessary to investigate the resultant change in properties with addition of ceramic fillers. Glass frit was selected to be a $Bi_2O_3-ZnO-B_2O_3-Al_2O_3$ and two fillers, ZnO and $Al_2O_3$ were added into a glass matrix with the different content. We investigated thermal, chemical properties of bismate glass system with two different fillers. We confirmed that addition of fillers effects properties of composites such as the thermal expansion coefficient, etching mechanism.

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Effect of Al2O3 on Crystallization Behavior and Microstructure of Na2O-CaO-P2O5-SiO2 Glass-ceramic System

  • Mirhadi, Bahman;Mehdikhani, Behzad
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.146-150
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    • 2012
  • The effects of $Al_2O_3$ on the crystallization behavior of glass compositions in the $Na_2O$-CaO-$SiO_2$ system were investigated by differential thermal analysis (DTA), X-ray diffraction (XRD), and scanning electron microscopy (SEM). The effect of $Al_2O_3$ content on the mechanical properties, density, phase formation, and microstructures of $Na_2O$-CaO-$P_2O_5$-$SiO_2$ glass ceramics were studied. The thermal parameters of each glass were studied by DTA. The density of the glass ceramic samples was measured by Archimedes' method. It was found that the glass-ceramic containing 2.0 molar percent $Al_2O_3$ had desirable sintering behavior and reached an acceptable density. Phase investigation and micro-structural analysis were performed by XRD and SEM, respectively.

An Experimental Study on the Properties of Mortar with Powdered Waste Glasses (폐유리 미분말을 혼입한 모르타르의 특성에 관한 실험적 연구)

  • Kim, Ho-Soo;Baek, Chul-Woo;Park, Cho-Bum;Jeun, Jun-Young;Ryu, Deuk-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.805-808
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    • 2006
  • At the present time, as part of the movement of natural resource conservation, there have been doing many recycling research works for wasted concrete, etc. In this study, we carried out an experiment for using crushed waste glass as a binder. It dealt with comparative analysis of the engineering properties of mortar containing crushed waste glass through a physical experiment. The experimental variables are the crushed waste glass powder substitution ratio(C-type : $0{\sim}25%$, B-type : $0{\sim}50%$, F-type : $0{\sim}100%$). According to this study, As the substitute of waste glass powder increases, air content and unit weight, the compressive strength decreases exactly proportion to the substitute ratio of waste glass powder. if, when waste glass is substituted as the binder, it is necessary to use an admixture.

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Adsorption of Nicotinic Acid on the Porous Powders (니코틴 산의 다공성 분체 흡착)

  • Shin, Sang-Chul;Cho, Cheong-Weon
    • Journal of Pharmaceutical Investigation
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    • v.27 no.1
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    • pp.39-49
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    • 1997
  • Nicotinic acid was mixed with glass powders such as controlled pore glass (CPG), glyceryl controlled pore glass (GPG) and glass beads (GB) at room temperature. The physicochemical properties of nicotinic acid in the various mixtures were examined by differential thermal analysis, X-ray diffraction study. Infrared spectroscopy and BET gas adsorption measurements. The peak area at the melting point from the various mixtures of nicotinic acid and CPG was increased with an increase of nicotinic acid concentration while the broad peak area was remained unchanged in the DTA curve. As shown in the powder X-ray diffraction patterns, the crystalline peaks of nicotinic acid disappeared in mixture with CPG, suggesting the interaction of nicotinic acid and porous powders. It was found that the larger the content of CPG, the higher the ratio of an amorphous state to a crystalline state. BET isotherm showed that as the amount of nicotinic acid was increased, the specific surface area was reduced proportionally to nicotinic acid content of up to 40% and remained constant thereafter. Sublimation of nicotinic acid from the mixture of nicotinic acid and CPG was examined. A large quantity of nicotinic acid was retained in the mixture when stored on various temperatures in vacuo for 10 hours. The nicotinic acid mixtures with CPG or GPG showed a high dissolution rates of nicotinic acid in aqueous solution, especially in the initial dissolution stage. CPG is expected to be a good pharmaceutical excipient to reduce the crystallinity of drugs and to prevent sublimation of drugs.

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Hydrophobic Properties of PTFE Film Deposited on Glass Surface Etched by Ar-plasma (아르곤 플라즈마를 이용하여 유리기판에 증착된 PTFE 박막의 초친수 특성 연구)

  • Rhee, Byung Roh;Bae, Kang;Kim, Hwa-Min
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.8
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    • pp.516-521
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    • 2014
  • An excellent hydrophobic surface has a high contact angle over 147 degree and the contact angle hysteresis below $5^0$ was produced by using roughness combined with hydrophobic PTFE coatings, which were also confirmed to exhibit an extreme adhesion to glass substrate. To form the rough surface, the glass was etched by Ar-plasma. A very thin PTFE film was coated on the plasma etched glass surface. Roughness factors before or after PTFE coating on the plasma etched glass surface, based on Wensel's model were calculated, which agrees well with the dependence of the contact angle on the roughness factor is predicted by Wensel's model. The PTFE films deposited on glass by using a conventional rf-magnetron sputtering. The glass substrates were etched Ar-plasma prior to the deposition of PTFE. Their hydrophobicities are investigated for application as a anti-fouling coating layer on the screen of displays. It is found that the hydrophobicity of PTFE films mainly depends on the sputtering conditions, such as rf-power, Ar gas content introduced during deposition. These conditions are closely related to the deposition rate or thickness of PTFE film. Thus, it is also found that the deposition rate or the film thickness affects sensitively the geometrical morphology formed on surface of the rf-sputtered PTFE films. In particular, 1,950-nm-thick PTFE films deposited for 30 minute by rf-power 50 watt under Ar gas content of 20 sccm shows a very excellent optical transmittance and a good anti-fouling property and a good durability.

Study on Thermal Properties and Plasma Resistance of MgO-Al2O3-SiO2 Glass (MgO-Al2O3-SiO2계 유리의 열물성과 내플라즈마성 연구)

  • Yoon, Ji Sob;Choi, Jae Ho;Jung, YoonSung;Min, Kyung Won;Im, Won Bin;Kim, Hyeong-Jun
    • Journal of the Semiconductor & Display Technology
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    • v.20 no.2
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    • pp.61-66
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    • 2021
  • In this study, we studied the alternative of plasma resistant ceramic parts that constitute plasma chambers in the semiconductor dry etching process. MgO-Al2O3-SiO2(MAS) glass was made of 13 types of glass using the Design Of Experiments(DOE) and the effect on thermal properties such as glass transition temperature and crystallization temperature depending on the content of each composition and etching resistance to CF4/O2/Ar plasma gas. MAS glass showed excellent plasma resistance and surface roughness up to 20 times higher than quartz glass. As the content of Al2O3 and MgO increases, the plasma resistance is improved, and it has been confirmed that it has an inverse relationship with SiO2.

Determination of X-ray and gamma-ray shielding capabilities of recycled glass derived from deteriorated silica gel

  • P. Sopapan;O. Jaiboon;R. Laopaiboon;C. Yenchai;C. Sriwunkum;S. Issarapanacheewin;T. Akharawutchayanon;K. Yubonmhat
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3441-3449
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    • 2023
  • We determined the radiation shielding properties for 10CaO-xPbO-(90-x) deteriorated silica gel (DSG) glass system (x = 20, 25, 30, 35, 40, and 45 mol.%). The mass attenuation coefficient (MAC) has been estimated at photon energies of 74.23, 97.12, 122, 662, 1173, and 1332 keV using a narrow beam X-ray attenuation and transmission experiment, the XCOM program, and a PHITS simulation. The obtained MAC values were applied to estimate the half value layer (HVL), mean free path (MFP), effective atomic number, and effective electron density. Results show that the MAC value of the studied glasses ranges between 0.0549 and 1.4415 cm2/g, increases with the amount of PbO, and decreases with increasing photon energy. The HVL and MFP values decrease with increasing PbO content and increase with increasing photon energy. The recycled glass, with the addition of PbO content (20-45 mol.%), exhibited excellent radiation shielding capabilities compared to standard barite and ferrite concretes and some glass systems. Moreover, the experimental radiation shielding parameters agree with the XCOM and PHITS values. This study suggests that this new waste-recycled glass is an effective and cost-saving candidate for X-ray and gamma-ray shielding applications.

Effect of MgO-CaO-Al2O3-SiO2 Glass Additive Content on Properties of Aluminum Nitride Ceramics (MgO-CaO-Al2O3-SiO2 glass 첨가제 함량이 AlN의 물성에 미치는 영향)

  • Kim, Kyung Min;Baik, Su-Hyun;Ryu, Sung-Soo
    • Journal of Powder Materials
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    • v.25 no.6
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    • pp.494-500
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    • 2018
  • In this study, the effect of the content of $MgO-CaO-Al_2O_3-SiO_2$ (MCAS) glass additives on the properties of AlN ceramics is investigated. Dilatometric analysis and isothermal sintering for AlN compacts with MCAS contents varying between 5 and 20 wt% are carried out at temperatures ranging up to $1600^{\circ}C$. The results showed that the shrinkage of the AlN specimens increases with increasing MCAS content, and that full densification can be obtained irrespective of the MCAS content. Moreover, properties of the AlN-MCAS specimens such as microhardness, thermal conductivity, dielectric constant, and dielectric loss are analyzed. Microhardness and thermal conductivity decrease with increasing MCAS content. An acceptable candidate for AlN application is obtained: an AlN-MCAS composite with a thermal conductivity over $70W/m{\cdot}K$ and a dielectric loss tangent (tan ${\delta}$) below $0.6{\times}10^{-3}$, with up to 10 wt% MCAS content.

Comparative Study of Mechanical and VOC Properties According to Manufacturing Conditions of Glass Fiber/Bamboo Fiber/PP Composites (유리섬유/대나무섬유/PP 복합재의 제조 조건에 따른 기계적 및 VOC 특성 비교 연구)

  • Lee, Su-kyoung;Park, Tae-sung;An, Seung-kook
    • Textile Coloration and Finishing
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    • v.33 no.3
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    • pp.153-160
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    • 2021
  • In this study, composite materials were prepared by varying the content of glass fiber and bamboo fiber in PP/glass fiber/bamboo fiber. Experiments were conducted to confirm the mechanical properties(tensile, impact and burst strength) and volatile organic compound content of the bamboo fiber composite prepared under these conditions. An improvement in the main properties was observed at a fiber content of 30wt%. When the fiber fraction was increased above 30wt%, the mechanical properties tended to decrease due to the agglomeration of fibers at higher load fractions. In addition, the content of volatile organic compounds increased as the content of bamboo fibers increased, which is thought to be due to the volatile organic compounds generated during the manufacturing process of the composite material being present in the composite material without escaping from the pores of the bamboo fibers and volatilizing at a certain temperature. As a result of confirming the physical properties of the composite, it is considered that the optimal mixing condition is 30wt% of bamboo fiber for the composite produced by varying the amount of bamboo fiber composite. In the future, it is thought that follow-up experiments to confirm and improve the pre-treatment conditions for reducing the content of volatile organic compounds in the manufactured composite material are possible.