• Title/Summary/Keyword: Glass composition

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Preparation of Porous Ceramics Sound Absorbent Material Using Sewage Sludge Slag (하수슬러지 슬래그를 이용한 다공성 세라믹스 흡음재료 제조)

  • 신대용;한상목
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.273-278
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    • 2003
  • The effects of content and particle size of sewage sludge slag on the sound absorption was investigated and the physical$.$mechanical properties of porous ceramics for sound absorbent material was studied. The physical$.$mechanical properties of specimens have depended on sintering temperature and slag content without particle size effect of slag. As water glass content increase and particle size of slag decrease at the same slag content, physical$.$mechanical properties of them have been improved. The bulk density and compressive strength of specimens with the batch composition of 77∼89 wt% of slag content and particles with 1∼3 mm, and sintered at 1,050$^{\circ}C$ for 2 h were 1.48∼1.71 and 86∼163 kgf/$\textrm{cm}^2$, respectively. The specimens with 1∼3 mm and <1 mm of particles size showed good sound absorption property at low frequency and high frequency region. With increasing thickness of specimens, sound absorption properties at low frequency region were increased.

Compressive Strength of Geopolymers while Varying the Raw Materials (무기질 원료에 따른 지오폴리머의 압축강도 특성)

  • Joo, Gi-Tae;Lee, Tae-Kun;Park, Mihye;Hwang, Yeon
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.575-580
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    • 2012
  • Geopolymers were synthesized using raw materials produced from two different areas: one was from Indonesia and the other was from Habcheon, Korea. The constituting phases of the Indonesian raw material were quartz and kaolinite, while those of the Habcheon sample were quartz, halloysite and albite. They were both calcined at $750^{\circ}C$ for 6 hours, and solution of NaOH and water glass was added to activate the geopolymeric reaction. The compressive strength of geopolymer synthesized from the Indonesian raw material showed a low value of $151\;kgf/cm^2$ after curing for 28 days. However, it could be greatly increased by adding blast furnace slag powders of $1188\;kgf/cm^2$ and $1969\;kgf/cm^2$ at 20 wt% and 40 wt% additions, respectively. The compressive strength of the geopolymer synthesized from the Habcheon raw material was high, at $557\;kgf/cm^2$, after 28 days, and the very high early-stage (3 days) strength of $556\;kgf/cm^2$ for this sample was remarkable. Commercially available Habcheon metastate raw material, of which composition showed low CaO and $Na_2O$ contents compared to the calcined Habcheon raw material, was also examined. It was found that the compressive strength of the commercial metastate type was nearly identical to that of the calcined Habcheon raw material except for the relatively low value at an early curing stage and at a high curing temperature of $60^{\circ}C$.

Enhancements in Performance and Manufacturing Efficiencies of GFRP Rebar (GFRP 보강근의 성능 및 제작 효율화 방안)

  • You, Young Jun;Kim, Jang Ho;Park, Young Hwan;Park, Ji Sun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.1
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    • pp.110-119
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    • 2012
  • Fiber reinforced polymer (FRP) reinforcing rebar with non-corrosive property is suggested as an alternative replacement to steel reinforcing rebar due to its enhanced durability and non-corrosive characteristics. Currently, a limited number of glass fiber reinforced polymer rebar (GFRP) are sold commercially due to their high cost, relatively low performances, and brittle failure characteristics. Therefore, the performance enhancements and cost reduction of GFRP rebar are needed to increase its applications in construction fields. The intent of this study is to develop high performance GFRP rebar by improving its tensile and shear properties. Also, in order to reduce manufacturing costs, factors such as material composition and manufacturing process were evaluated to improve manufacturing efficiency. Finally a GFRP rebar with enhanced material properties and less expensive than the GFRP rebar currently sold in the market was manufactured and evaluated for its application possibility in construction fields.

Heat treatment effects on the electrical properties of $In_2O_3$-ZnO films prepared by rf-magnetron sputtering method (마그네트론 스퍼터링 방법으로 제작된 $In_2O_3$-ZnO 박막의 전기적 특성에 대한 열처리 효과)

  • Kim, Hwa-Min;Kim, Jong-Jae
    • Journal of the Korean Vacuum Society
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    • v.14 no.4
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    • pp.238-244
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    • 2005
  • IZO thin films are prepared on a corning 7059 glass substrate in a mixed gases of Ar +$O_2$ by rf-magnetron sputtering, using a powder target with a composition ratio of $In_{2}O_{3}$ : ZnO=90 : 10 $wt.\%$. Their electrical sheet resistance are strongly dependent on the oxygen concentration introduced during the deposition, a minimum resistivity of $3.7\times10^{-4}\Omega\cdot$ cm and an average transmittance over $85\%$ in the visible range are obtained in a film deposited in pure Ar gas which is close to near the stoichiometry. During the heat treatment from room temperature up tp $600^{\circ}C$ in various environments, the electrical resistance changes are explained by cyrstallizations or oxidizations of In metal and InO contained in the IZO film. The electrical properties due to oxygen adsorption and phase transitions occurring at temperatures over $40000^{\circ}C$ during heat treatment in air are also investigated.

Comparison assessment of semi-transparent solar cell for BIPV windows (반투과형 태양전지를 이용한 창호형 BIPV 건물의 환경성능 분석)

  • Chung, Min Hee
    • Land and Housing Review
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    • v.11 no.1
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    • pp.87-94
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    • 2020
  • To implement the planning of zero-energy buildings, their energy performance must be improved, and renewable energy applications must also be included. To accelerate the use of renewable energies in such buildings, BIPVs should be actively used in windows and on roofs. Window-type BIPVs are being developed in various forms depending on the size, composition, area ratio of the window, specification of glass, and so on. To analyze the applicability of various solar cells as window-type BIPVs, in this study, we evaluated their applicability, at the current development level, by analyzing the indoor illuminance, heat gain and heat loss; the cooling, heating, and lighting energy levels; and the generation performance of the various solar cells. To enhance the future applicability of window type BIPV, we analyze the overall energy performance of the building, according to changes in visible light transmittance and generation efficiency. The main research results are as follows. The area ratios above the standard illuminance, based on the window type and according to the VLT, were in order of low-e glazing, a-Si window, DSSC window, and c-Si window. The heat gain of the semi-transparent solar cell winodw was remarkably low. The energy consumption of buildings was highest in the order of c-Si window, DSSC window, a-Si window, and clear low-e window. However, in the case of including the power generation performance of the solar cell, the energy consumption was found to be high in order of DSSC window, c-Si window, a-Si window, and clear low-e window. In the future, if a window-type BIPV is developed, we believe that improvement in power generation performance and improvement in visible light transmittance will be needed.

Concentration Characteristics of Indoor and Outdoor Airborne Total Fiber Particles and Identification of Asbestos in Gyeongnam Provinces (경남지역의 실내외 공기 중 총섬유 입자의 농도특성 및 석면 입자의 확인)

  • Park, Hee-Eun;Park, Jeong-Ho;Kim, Hyoung-Kab
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.22 no.2
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    • pp.119-127
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    • 2012
  • Objectives: The aim of this study is to identify concentration characteristics of indoor and outdoor airborne total fiber particles and asbestos in Gyeongnam Provinces. Methods: This study investigated concentration characteristics of indoor fiber particles from 748 schools and 38 public facilities as well as outdoor particles from 11 sites through PCM (phase contrast microscope). SEM/EDX (scanning electron microscope/energy dispersive using X-ray analysis) was used to obtain physicochemical information of asbestos fiber particles. The study identified asbestos rate in the 15 samples from indoor and outdoor airborne total fiber particles. Results: 1. The average indoor airborne concentrations of total fiber particles were $0.0011{\pm}0007$ f/cc in schools and $0.0015{\pm}0007$ f/cc in public facilities by PCM. Over 90% of the fiber particles were identified as single fibers. 2. The average outdoor airborne concentrations of total fiber particles were $0.0007{\pm}0002$ f/cc, and they were lower than those of indoor airborne concentrations. 3. The results showed that the form of asbestiform was diverse as skein of thread like form and long needle, which was relatively narrower than that of glass fiber and rock wool. 4. The results of SEM/EDX analysis of 15 areas where total fiber particle was relatively high showed that the form was rather similar to that of asbestos, but chemical composition was proven to be non-asbestos. Conclusions: The concentration of indoor and outdoor airborne total fiber particles of Gyeongnam Provinces satisfied the IAQ (Indoor air quality) level of 0.01 f/cc and asbestos was not found in most of the samples by SEM/EDX.

Comparison of Dustiness of Eleven Nanomaterials using Voltex Shaker Method (볼텍스쉐이커를 이용한 11개 나노물질의 분진날림 비교)

  • Lee, Naroo;Park, Jinwoo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.3
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    • pp.273-282
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    • 2018
  • Objectives: Dustiness of nanomaterials is considered as exposure index of essential material. Research on dustiness of nanomaterial is needed to control exposure in workplaces. Method: Dustiness measurement using vortex shaker were installed in the laboratory. Nanomaterials, 1 g, was put in the glass test tube and shaked using vortex shaker. Aerosol dispersed was measured using scanning mobility particle sizer(SMPS) and optical particle counter(OPC). Mass concentration using PVC filter and cassette was measured and TEM grid sampling was conducted. Total particle concentration and size distribution were calculated. Image and chemical composition of particles in the air were observed using transmission electron microscopy and energy dispersive X-ray spectrometer. Eleven different test nanomaterials were used in the study. Results: Rank of mass concentration and particle number concentration were coincided in most cases. Rank of nanomateirals with low concentration were not coincided. Two types of fumed silica had the highest mass concentration and particle number concentration. Indium tin oxide, a mixture of indium oxide and tin oxide, had high mass concentration and particle number concentration. Indium oxide had very low mass concentration and particle number concentration. Agglomeration of nanoparticles in the air were observed in TEM analysis and size distribution. In this study, mass concentration and particle number concentration were coincided and two index can be used together. The range of dustiness in particle number concentration were too wide to measure in one method. Conclusion: Particle number concentration ranged from low concentration to high concentration depend on type of nanomaterial, and varied by preparation and amount of nanomaterial used. Further study is needed to measure dustiness of all nanomaterial as one reference method.

Effect of Annealing Process Pressure Over Atmospheric Pressure on Cu2ZnSn(S,Se)4 Thin Film Growth (대기압 이상의 열처리 공정압력이 Cu2ZnSn(S,Se)4(CZTSSe) 박막 성장에 미치는 영향)

  • Lee, Byeong Hoon;Yoo, Hyesun;Jang, Jun Sung;Lee, InJae;Kim, Jihun;Jo, Eunae;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.29 no.9
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    • pp.553-558
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    • 2019
  • $Cu_2ZnSn(S,Se)_4(CZTSSe)$ thin film solar cells areone of the most promising candidates for photovoltaic devices due to their earth-abundant composition, high absorption coefficient and appropriate band gap. The sputtering process is the main challenge to achieving high efficiency of CZTSSe solar cells for industrialization. In this study, we fabricated CZTSSe absorbers on Mo coated soda lime glass using different pressures during the annealing process. As an environmental strategy, the annealing process is performed with S and Se powder, without any toxic $H_2Se$ and/or $H_2S$ gases. Because CZTSSe thin films have a very narrow stable phase region, it is important to control the condition of the annealing process to achieve high efficiency of the solar cell. To identify the effect of process pressure during the sulfo-selenization, we experiment with varying initial pressure from 600 Torr to 800 Torr. We fabricate a CZTSSe thin film solar cell with 8.24 % efficiency, with 435 mV for open circuit voltage($V_{OC}$) and $36.98mA/cm^2$ for short circuit current density($J_{SC}$), under a highest process pressure of 800 Torr.

A Molecular Dynamics Simulation Study on the Thermoelastic Properties of Poly-lactic Acid Stereocomplex Nanocomposites (분자동역학 전산모사를 이용한 폴리유산 스테레오 콤플렉스 나노복합재의 가수분해에 따른 열탄성 물성 예측 연구)

  • Ki, Yelim;Lee, Man Young;Yang, Seunghwa
    • Composites Research
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    • v.31 no.6
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    • pp.371-378
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    • 2018
  • In this study, the thermoelastic properties of poly lactic acid (PLA) based nanocomposites are predicted by molecular dynamics (MD) simulation and a micromechanics model. The stereocomplex mixed with L-lactic acid (PLLA) and D-lactic acid (PDLA) is modeled as matrix phase and a single walled carbon nanotube is embedded as reinforcement. The glass transition temperature, elastic moduli and thermal expansion coefficients of pure matrix and nanocomposites unit cells are predicted though ensemble simulations according to the hydrolysis. In micromechanics model, the double inclusion (D-I) model with a perfect interface condition is adopted to predict the properties of nanocomposites at the same composition. It is found that the stereocomplex nanocomposites show prominent improvement in thermal stability and interfacial adsorption regardless of the hydrolysis. Moreover, it is confirmed from the comparison of MD simulation results with those from the D-I model that the interface between CNT and the stereocomplex matrix is slightly weak in nature.

Analysis of Jacket Shapes by Designers in the 2000s (2000년대 디자이너별 재킷 형태분석)

  • Park, MiKyeong;Song, Jung-A
    • Fashion & Textile Research Journal
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    • v.24 no.2
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    • pp.249-259
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    • 2022
  • To analyze recent changes in designer-specific garment composition, detail, and design elements of jackets, we classified jackets from the Paris Haute Couture Collection from 2000 S/S to 2019 F/W according to their designers and examined their characteristics. Our analysis of the jackets by Armani, Chanel, Dior, Jean-Paul Gaultier, and Valentino shows that the hour-glass silhouette was most common in Armani, Chanel, Dior, Jean-Paul Gaultier and Valentino jackets; Chanel used more straight silhouettes compared to other designers. Most jackets, regardless of the designer, had midlength waist-to-bottom, tight sleeves fitted to the body, natural shoulder shape, and solid color. Moreover, woven fabric was the most common material. Jackets with no collar were the most common for Armani, tailored collars for Dior and Jean-Paul Gaultier, and standing collars for Chanel and Valentino. For the closure method, Armani used hook-and-eye, Chanel, Jean-Paul Gaultier, Valentino used button closures, and Dior used snap closures the most. New design attempts by designers are bringing details and design elements together. In an era characterized by an abundance of designs and frequent replacement of each brand's creative designers, it is important to create and maintain a brand's unique design identity and philosophy that can meet consumers' elevated standards, which tend to be biased towards new and stimulating designs due to the development of the IT industry.