• Title/Summary/Keyword: Glass composition

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Analysis of the relationship between composition and viscosity of soda-lime glass bottles (소다석회유리병의 조성과 점도의 상관관계 분석)

  • Seung Min Kang;Chang-Sam Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.1
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    • pp.7-14
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    • 2023
  • Forty Viscosity data of glass bottles fabricated in a glass bottle manufacturing plant for 4 years were calculated using Lakatos model. The relationship between the glass bottle compositions and viscosities at log η of 3, 6.6, 10 and 12.3 Pa·s was analyzed. MgO that was a component of the glass bottle showed the maximum coefficient of variation of 0.89, but it gave a very small change in the viscosity. CaO that was another component of the glass bottle lowered the isokom temperature because it tended to reduce the number of non-bridging oxygen at temperature below a softening point.

Preparation of bioactive materials by crystallization sintering (결정화 소결에 의한 생체활성재료의 제조)

  • 명중재;이안배;정용선;신건철;김호건
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.169-178
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    • 1998
  • The crystal phases precipitated in various compositions glass of CaO-$SiO_2-P_2O_5$ system, were identified by XRD. E composition (CaO 49.4, $SiO_2\;36.8,\;P_2O_5$ 8.8 wt%) glass in which both apatite(($Ca_{10}(PO_4)_6O$ and $\beta$-wollastonite($CaSiO_3$) crystals would precipitate by heating, was selected as an experimental composition to prepare the glass ceramics with high bending strength and good bioactivity to the living bone. Glass powders of E composition were unidirectionally crystallized at $1050^{\circ}$C in the temperature-gadient furnace and the resultant glass ceramics were characterized. Bending strength of the glass ceramics was also measured. To investigate the bond forming ability between the glass ceramics and living bone tissue, soaking test of glass ceramics in simulated body fluid was carried out. Densed glass ceramics composed of apatite and $\beta$-wollastonite crystal were prepared by unidirectional crystallization under the optimum conditions. (2 0 2) plane of $\beta$-wollastonite crystals tended to grow perpendicularly to the crystallization direction. Average bending strength of this glass ceramics was 186.9 MPa, higher than that of the glass ceramics prepared by isothermal (not directional) crystallization In soaking test, a thin layer of apatite crystallite was formed on surface of the glass ceramics in 3 days. Apatite crystals formed on the glass ceramics could be act a role to make the chemical bond between the glass ceramics and living bone tissue.

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Experimental investigating the properties of fiber reinforced concrete by combining different fibers

  • Ghamari, Ali;Kurdi, Javad;Shemirani, Alireza Bagher;Haeri, Hadi
    • Computers and Concrete
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    • v.25 no.6
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    • pp.509-516
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    • 2020
  • Adding fibers improves concrete performance in respect of strength and plasticity. There are numerous fibers for use in concrete that have different mechanical properties, and their combination in concrete changes its behavior. So, to investigate the behavior of the fiber reinforced concrete, an in vitro study was conducted on concrete with different fiber compositions including different ratios of steel, polypropylene and glass fibers with the volume of 1%. Two forms of fibers including single-stranded and aggregated fibers have been used for testing, and the specimens were tested for compressive strength and dividable tensile strength (splitting tensile) to determine the optimal ratio of the composition of fibers in the concrete reinforced by hybrid fibers. The results show that the concrete with a composition of steel fibers has a better performance than other compounds. In addition, by adding glass and propylene fibers to the composition of steel fibers, the strength of the samples is reduced. Also, if using the combination of fibers is required, the use of a combination of glass fibers with steel fibers will provide a better compressive strength and tensile strength than the combination of steel fibers with propylene.

Approach to Compositional Effect on Properties of Aspherical Optical Glass for GMP Process with Design of Experiments (실험계획법에 의한 GMP용 비구면 광학유리의 성질에 미치는 조성의 효과 연구)

  • Maeng, Jee-Hun;Kim, Hyeong-Jun;Jung, Ah-Reum;Kim, Jong-Cheol;Choi, Sung-Churl
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.40-45
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    • 2011
  • In this study, the composition of optical glass for GMP(glass molding process) was designed with 'Design of Experiments' method. All the composition batch was performed by 'Create Factorial Design' method. Particularly, $SiO_2$, BaO and $Al_2O_3$ were chosen major parameters for investigating the effects of components on optical and thermal properties. BaO and $Al_2O_3$ strongly influenced on optical and thermal properties, respectively. Finally, the approximate values of desired optical and thermal values were obtained by microtuning of compositions. At the composition of $BaO:Al_2O_3:SiO_2$=10:4:48 (molar ratio), refractive index($n_d$) was 1.5833, coefficient of thermal expansion(CTE) was $104{\times}10^{-7}/^{\circ}C$.

Effect of Additive Composition on Flexural Strength of Cullet-Loess Tile Bodies (첨가제의 조성이 폐유리-점토 타일의 곡강도에 미치는 영향)

  • Lee, Young-Il;Eom, Jung-Hye;Kim, Young-Wook;Song, In-Hyuck
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.416-422
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    • 2013
  • Cullet-loess tile bodies are successfully fabricated using cullet, loess, hollow microspheres, and sintering additives (borosilicate glass frit, boric acid, or fumed silica) as starting materials. The effects of the additive composition and sintering temperature on the sintered density and flexural strength of the cullet-loess tile bodies are investigated. The sintered density of the cullet-loess tile bodies increases with an increase in the sintering temperature as a result of the enhanced densification of pore walls through the viscous flow of a liquid phase formed from the glass frit and sintering additives. The flexural strength of the cullet-loess tile bodies increases with increases in the sintering temperature and the cullet content in the starting composition. A maximal flexural strength of 40 MPa is obtained in cullet-loess tile bodies sintered with glass frit at $800^{\circ}C$ in air.

Investigation on Lead-Borosilicate Glass Based Dielectrics for LTCC (Lead-Borosilicate Glass계 LTCC용 유전체에 대한 고찰)

  • Yoon, Sang-Ok;Oh, Chang-Yong;Kim, Kwan-Soo;Jo, Tae-Hyun;Shim, Sang-Heung;Park, Jong-Guk
    • Journal of the Korean Ceramic Society
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    • v.43 no.6 s.289
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    • pp.338-343
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    • 2006
  • The effects of lead-borosilicate glass frits on the sintering behavior and microwave dielectric properties of ceramic-glass composites were investigated as functions of glass composition of glass addition ($10{\sim}50vol%$), softening point (Ts) of the glass, and sintering temperature of the composites ($500{\sim}900^{\circ}C$ for 2 h). The addition of 50 vol% glass ensured successful sintering below $900^{\circ}C$. Sintering characteristics of the composites were well described in terms of Ts. PbO addition in to the glass enhanced the reaction with $Al_{2}O_3$ to form liquid phase and $PbAl_{2}Si_{2}O_8$, which was responsible to lower Ts. Dielectric constant(${\epsilon}_r$), $Q{\times}f_0$ and temperature coefficient of resonant frequency (${\tau}_f$) of the composite with 50 vol% glass contents ($B_{2}O_{3}:PbO:SiO_{2}:CaO:Al_{2}O_3$ = 5:40:45:5:5) demonstrated 8.5, 6,000 GHz, $-70\;ppm/^{\circ}C$, respectively, which is applicable to substrate requiring a low dielectric constant. When the same glass composition was applied sinter $MgTiO_3\;and\;TiO_2,\;at\;900^{\circ}C$ (50 vol% glass in total), the properties were 23.8, 4,000 GHz, $-65ppm/^{\circ}C$ and 31.1, 2,500 GHz, $+80ppm/^{\circ}C$ respectively, which is applicable to filter requiring an intermidiate dielectric constant.

Mechanical Properties of Alumina-Glass Dental Composites Prepared from Aqueous-Based Tape Casting (수계공정에 의한 알루미나 테이프로 제조한 세라믹 인공치관용 알루미나 유리 복합체의 기계적 물성)

  • 이명현;김대준;이득용;이정훈;김창은
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1123-1131
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    • 1999
  • Alumina-glass composites which are considered as the material of the choice for all dental crown was prepared by aqeous-based tape casting and sintering for 2h at 1120$^{\circ}C$ followed by glass infiltration for 2h at 1100$^{\circ}C$ Biaxial strength and fracture toughness of the composites were evaluated to determine the optimum composition of the tape as a function of the amount of constituent such as alumina binder and plasticizer. The strength and the fracture toughness of the alumina tape increased with increasing the contents of alumina and binder. These observations are consistent with in fluence of the constituents on mean alumuna particle distance in tapes suggesting that high strength of the glass infiltrated alumina composites is related to toughening by crack bowing. The biaxial strength and the fracture toughness of the composite containing the optimum constituent composition were 523 MPa and 3.3 MPa$.$1/2 respectively.

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The characteristics of alumina cement utilized for binder of glass insulators in braket (브래킷 유리애자의 접합재로 이용되는 알루미나 시멘트의 특성)

  • Shong, Kil-Mok;Jung, Jin-Soo;Han, Woon-Ki;Kim, Young-Seok;Ryu, Young-Tae;Jun, Yong-Joo
    • Proceedings of the KIEE Conference
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    • 2008.09a
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    • pp.261-262
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    • 2008
  • Damaged glass insulator that is utilized the high-speed railroad in domestic try to find the cause. This paper is investigated on the characteristics of alumina cement as the binder of class insulator. The components of glass insulator ore stub(tin), rod(tin), shed(tempered glass), and alumina cement. If composition of alumina cement is not unified, crack of alumina cement generated. As these results, cracked marks of cement is appeared and composition of alumina cement is not unified. Therefore, it is estimated that main element of long-term degradation is a alumina cement.

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Sintering and Microstructure of Alumina/Mica and Spinel/Mica Composites

  • Suzuki, Sofia-Saori;Taruta, Seiichi;Takusagawa, Nobuo
    • The Korean Journal of Ceramics
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    • v.4 no.4
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    • pp.363-367
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    • 1998
  • Alumina/mica and spinel/mica composites were fabricated by sintering of compacts containing 20 mass% fluoromica ($KMg_3AlSi_3O-{10}F_2$) glass and alumina or spinel. In both composites, mica precipitated as plate-like crystals at temperatures lower than $1300^{\circ}C$ and melted at $1300^{\circ}C$ to $1400^{\circ}C$. In alumina/mica composites, alumina and glass reacted to produce spinel, and the densification progressed by the solution-precipitation of alumina. Consequently, the glass composition changed and the mica did not precipitate at temperatures higher than $1400^{\circ}C$. However, mica precipitated after a reheating process. In spinel/mica composites, the glass composition did not change. After the mica phase melted, it recrystallized during slow cooling. The relative density reached the maximum at $1500^{\circ}C$ for alumina/mica and at $1300^{\circ}C$ spinel/mica composites, and decreased at further high temperatures.

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Archaeological Chemistry of Classes Excavated at Songdong-ri tombs, Sangju, Korea (경상북도 상주 성동리고분 출토 유리구슬의 고고화학적 연구)

  • KIM, Gyu-Ho
    • Journal of Conservation Science
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    • v.16 s.16
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    • pp.104-109
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    • 2004
  • The characteristics and composition of the ancient glasses excavated at Songdong-ri, Sangju, Kyongsangbuk-do were analyzed using Scanning Electron Microscope attached with Energy Dispersive Spectrometer. As the results, the glass beads of Songdong-ri showed that there were changed the composition, the color and types according to the periods. There were appeared potash and soda glass group at A.D.4 century and potash and mixed alkali glass group at A.D. 17 century. The potash glasses of A.D. 4c. were colored blue and contained low $Al_2O_3$ and CaO composition as below $5\%$. The soda glasses of This period were colored blue and red, and contained $Al_2O_3$ composition as upper $5\%$. But the potash glasses of A.D.17c. showed the transparent yellow color and considerably higher CaO, $11.7\%$. 'Coil glasses' typed unique were colored yellow-brown, Cu-blue and colorless, were classified the mixed alkali glass as upper $5\%\;of\;Na_2O\;and\;K_2O$. The composition of coil glasses were presented first at this study.

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