• 폴리머
• /
• 제39권2호
• /
• pp.247-255
• /
• 2015

Poly(1,2-propylene glycol adipate) (PPA) was used as an environmentally friendly plasticizer in flexible poly(vinyl chloride) (PVC). Thermal, mechanical, and rheological properties of the PVC/PPA blends were characterized by differential scanning calorimetry, dynamic mechanical analysis, tensile test, scanning electron microscopy and small amplitude oscillatory shear rheometry. The results showed that PPA lowered the glass transition temperature of PVC. The introduction of PPA could decrease tensile strength and Young's modulus of the PVC/PPA blends; however, elongation-at-break was dramatically increased due to the plastic deformation. The plasticization effect of PPA was also manifested by the decrease of dynamic storage modulus and viscosity in the melt state of the blends. The results indicated that PPA had a good plasticizing effect on PVC.

• 한국재료학회지
• /
• 제24권1호
• /
• pp.60-65
• /
• 2014

Fe-based amorphous coatings were fabricated on a soda-lime glass substrate by the vacuum kinetic spray method. The effect of the gas flow rate, which determines particle velocity, on the deposition behavior of the particle and microstructure of the resultant films was investigated. The as-fabricated microstructure of the film was studied by field emission scanning electron microscopy (FE-SEM) and high resolution transmission electron microscopy (HR-TEM). Although the activation energy for transformation from the amorphous phase to crystalline phase was lowered by severe plastic deformation and particle fracturing under a high strain rate, the crystalline phases could not be found in the coating layer. Incompletely fractured and small fragments 100~300 nm in size, which are smaller than initial feedstock material, were found on the coating surface and inside of the coating. Also, some pores and voids occurred between particle-particle interfaces. In the case of brittle Fe-based amorphous alloy, particles fail in fragmentation fracture mode through initiation and propagation of the numerous small cracks rather than shear fracture mode under compressive stress. It could be deduced that amorphous alloy underwent particle fracturing in a vacuum kinetic spray process. Also, it is considered that surface energy caused by the formation of new surfaces and friction energy contributed to the bonding of fragments.

• Composites Research
• /
• 제32권5호
• /
• pp.279-283
• /
• 2019

구체 비행 시뮬레이터는 6자유도 운동과 무제한 회전 운동을 정밀하고 신속하게 제어하는 비행 훈련용 시뮬레이터이다. 이러한 시뮬레이터를 제작하기 위해서는 고강도 경량화 설계 및 검증이 필요하다. 본 연구에서는 유리섬유강화플라스틱과 폼코어로 구성된 샌드위치 복합재를 이용하여 높은 비강도와 비강성을 확보하고, 내부에 T형 스테인리스 스틸 프레임을 삽입하여 하중에 의한 구체 곡률 변형이 최소화되도록 시뮬레이터를 설계하였다. 그 결과 구체가 접촉하는 각 영역에 균일한 토크 전달이 가능해지고 제어 정확도를 높일 수 있다. 시뮬레이터의 구조 안정성 평가를 위해 유한요소해석을 수행하였으며 재료에 대한 기계적 물성은 ASTM 규격에 따라 측정되었다. 하중 조건은 중력가속도를 고려하고 실제 탑재될 장비와 사용자의 무게를 200 kg으로 가정하였다. 두 가지 상황을 모사하여 하중과 자중에 의해 시뮬레이터에 작용하는 응력과 변위를 해석하고 안전성을 검증하였다.

• Advances in concrete construction
• /
• 제7권3호
• /
• pp.151-166
• /
• 2019

This paper introduces a new efficient analytical method, based on shear deformations obtained with 2D elasticity theory approach, to perform an explicit closed-form solution for calculation the interfacial shear and normal stresses in plated RC beam. The materials of plate, necessary for the reinforcement of the beam, are in general made with fiber reinforced polymers (Carbon or Glass) or steel. The experimental tests showed that at the ends of the plate, high shear and normal stresses are developed, consequently a debonding phenomenon at this position produce a sudden failure of the soffit plate. The interfacial stresses play a significant role in understanding this premature debonding failure of such repaired structures. In order to efficiently model the calculation of the interfacial stresses we have integrated the effect of shear deformations using the equilibrium equations of the elasticity. The approach of this method includes stress-strain and strain-displacement relationships for the adhesive and adherends. The use of the stresses continuity conditions at interfaces between the adhesive and adherents, results pair of second-order and fourth-order coupled ordinary differential equations. The analytical solution for this coupled differential equations give new explicit closed-form solution including shear deformations effects. This new solution is indented for applications of all plated beam. Finally, numerical results obtained with this method are in agreement of the existing solutions and the experimental results.

• 대한건축학회논문집:구조계
• /
• 제35권12호
• /
• pp.149-156
• /
• 2019

Recently, skyscraper building and apartment fires, which were rapidly spread out from a low floor to a rooftop, have become a frequent occurrence in mass media. This fire problems have a fatal disadvantage that the exterior wall finish of the building emits toxic gas in case of fire by using dry bit method or organic insulating material. Therefore, in order to remedy these problems, many exterior wall finishing construction methods have been proposed, but the current trend is to use existing construction methods due to problems such as economy, weight, and durability. On the other hand, in countries such as Germany and Japan, ceramic sidings are used as exterior finishing material for buildings, which is environmentally friendly, excellent natural beauty, long life, easy maintenance and high-quality exterior materials. However, those ceramic sidings have still the problems such as manufacturing cost and weight problem because of boosting the sintering temperature up to 1,350℃ or more. Also, conventional CRC, MgO, FRP sidings which are composed of pulp, glass fiber and organic materials, have been reports of deformation due to ultraviolet rays, discoloration, corrosion and scattering, surface rupture, lifting and peeling. Therefore, in this study as an alternative to solve this problem, halosite nano kaolin produced in Sancheong in Korea and frit flux were used to satisfy the required properties as ceramic siding using low temperature sintering (below 1,000℃) and lightweight materials such as pearlite. This study aims to design the optimal formulation and process of materials and to study the characteristics of nano-coated ceramic siding material development and to present relevant basic data. The findings show that ceramic siding for nanocoated building materials is excellent as a natural ceramic siding building material. The fire resistance of natural minerals and nano particle refining technology satisfy the bending strength of 80kgf / cm2, the volume ratio of 2.0 and the absorption rate of less than 10.0%.

• 대한금속재료학회지
• /
• 제48권3호
• /
• pp.203-209
• /
• 2010

An application of the instrumented indentation technique has been expanded from the measurements of hardness and elastic modulus to the analysis of residual stress. A slope of the indentation loading curve increases (or decreases) according to compressive (or tensile) residual stress. A theoretical equation has been established for quantifying residual stress from the slope change. However, a precise observation of the remnant indents is indispensible because the theoretical approach needs actual contact information. In addition, the conventional hardness test is still used for predicting the residual stress distribution of welded joints. Thus, we observed the three-dimensional morphologies of the remnant indents formed on artificial stress states and analyzed stress effects on morphological recovery of the indents. First, a depth recovery ratio, which has been regarded as a sensitive stress indicator, did not show a clear dependency with the residual stress. Thus an analysis on volumetric recovery was tried in this study and yielded a inverse proportional behavior with the residual stress. In addition, an elastic to plastic volume recovery ratio showed more significant correlation with the residual stress.

• Structural Engineering and Mechanics
• /
• 제87권6호
• /
• pp.529-540
• /
• 2023

A novel laminated-hybrid-composite-beam (LHCB) of glass-epoxy infused with flyash and graphene is constructed for this study. The conventional mixture-rule and constitutive-relationship are modified to incorporate filler and lamina orientation. Eringen's non-local-theory is used to include the filler effect. Hamilton's principle based on fifth-order-layer-wise-shear-deformation-theory is applied to formulate the equation of motion. The analogous shear-spring-models for LHCB with multiple-cracks are employed in finite-element-analysis (FEA). Modal-experimentations are conducted (B&K-analyser) and the findings are compared with theoretical and FEA results. In terms of dimensionless relative-natural-frequencies (RNF), the dynamic-response in cantilevered support is investigated for various relative-crack-severities (RCSs) and relative-crack-positions (RCPs). The increase of RCS increases local-flexibility in LHCB thus reductions in RNFs are observed. RCP is found to play an important role, cracks present near the end-support cause an abrupt drop in RNFs. Further, multiple cracks are observed to enhance the nonlinearity of LHCB strength. Introduction of the first to third crack in an intact LHCB results drop of RNFs by 8%, 10%, and 11.5% correspondingly. Also, it is demonstrated that the RNF varies because of the lamina-orientation, and filler addition. For 0° lamina-orientation the RNF is maximum. Similarly, it is studied that the addition of graphene reduces weight and increases the stiffness of LHCB in contrast to the addition of flyash. Additionally, the response of LHCB to moving mass is accessed by appropriately modifying the numerical programs, and it is noted that the successive introduction of the first to ninth crack results in an approximately 40% to 120% increase in the dynamic-amplitude-ratio.

• 청정기술
• /
• 제16권4호
• /
• pp.245-253
• /
• 2010

대구경 강관 표면 보호를 위해 사용되는 필라멘트 와인딩 공정에 불포화 폴리에스터 (unsaturated polyester: UP)를 이용한 자외선 (ultraviolet) 경화 방법을 적용하고자, UP를 이용한 최적의 UV 경화 조건을 찾아보았다. 기존의 유기계 과산화물을 개시제로 사용한 열경화 방법에서는 개시제의 불안정성, 휘발성 유기물 발생, 열에 약한 대상물질의 변형 등 문제점이 발생하므로 이에 대한 개선책으로 UV 경화방법을 시도하였다. UV 경화에 사용되는 다양한 개시제 중에서 비교적 침투력이 높아서 두꺼운 고분자 층 형성이 가능한 개시제 2 종(Irgacure 819 및 Darocure 1173)을 선정하여 이들의 조합비율에 따라 경화된 UP 고분자에 대한 열역학적, 기계적 물성을 비교 분석하여 우수한 경화조건 (개시제 함량 1.5 phr, 혼합 비율 1:1.2, UV 램프로는 갈륨램프)을 찾아내었다. 또한 UP 광경화수지의 경도, 충격강도, 굴곡강도 향상을 위해 유리섬유를 수지 내에 적층하여 복합재료를 제조하고 이들의 특성을 비교한 결과 충격강도가 매우 향상되었다.

• 한국지반공학회논문집
• /
• 제25권8호
• /
• pp.47-55
• /
• 2009

본 연구는 해양부산물로 발생되는 고막껍질을 재활용하기 위하여 매립이나 성토재료로 활용되고 있는 황토에 혼합 적용함으로써 친환경적인 건설재료의 대체재료로 활용성을 연구하는데 그 목적이 있다. 이를 위해 황토를 조립재료인 고막껍질과 혼합하여 반복삼축시험을 통하여 역학적인 특성을 알아보았다. 고막껍질-황토 혼합토의 혼합비율은 중량비를 이용하였으며 황토에 고막껍질을 일정한 함유율로 혼합한 고막껍질의 혼합비율은 5종류로 하고 각각의 혼합토에 대해 반복삼축시험을 실시하였다. 반복삼축시험 결과 고막껍질 치환 함유율이 20.0% 이상인 혼합토에서 액상화저항성에 한계가 있는 것으로 나타났다. 따라서 본 연구에서는 고막껍질-황토 혼합토의 액상화 저항성을 증대시키고자 약간의 유리섬유를 첨가 하여 입증하였다.

• Composites Research
• /
• 제22권6호
• /
• pp.23-31
• /
• 2009

압축하중 및 굽힘하중을 받는 유리섬유플라스틱(GFRP) 표피/ 알루미늄 하니컴 코어(GF-AH) 하이브리드 복합재료의 음향방출(AE) 특성을 다양한 파괴과정과 연결시켜 연구하였다. 표피층 파괴, 표피/코어간의 계면박리, 하니컴 알루미늄 벽의 국부적인 소성항복 좌굴 및 셀벽간의 접착수지 박리와 같은 다양한 파괴모드가 하니컴 코어/GFRP표피 복합재를 이용한 AE주파수 분포 해석과 진폭분포 해석결과를 통해 분류되었다. 높은 진폭을 가진 AE 사상율의 분포는 셀벽 접착수지의 파괴, 표피층과 심층 사이의 박리및 미세파괴, 섬유파단에 대응하였으며 다른 피크 주파수의 분포는 알루미늄 셀벽의 소성변형, 셀벽간의 마찰로부터 발생한 것이다. 결론적으로 GF-AH 하이브리드 복합재료의 파괴거동 특성은 AE기법을 활용한 비파괴 평가를 통해 분석 가능하였다.