• 한국해양공학회지
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• 제14권3호
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• pp.90-99
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• 2000

This study has been investigated about the influence of moisture environment properties in the unidirectional and cross laminated carbon fiber/epoxy and glass fiber/epoxy composites. As a results, it was found that the weight gain of water increased with the immersion time and the mechanical properties were decreased with the weight gain of water. And it was also shown that the mechanical properties of carbon fiber/epoxy laminates were better than those of glass fiber/epoxy laminates. And a gap of the mechanical properties between the two kinds of laminates was increasing with the immersion time in distilled water of 80$^{\circ}C $. Mechanical properties which decreased by moisture absorption in the CF and GF reinforced laminates were recovered up to some extent by drying in oven at 80$^{\circ}C $ for 10 days.

• 한국전기전자재료학회논문지
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• 제26권2호
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• pp.126-133
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• 2013

This paper presents a study on the dispersion effect of the X-Ray diffraction, glass transition and DMA properties of organic modifier clay/epoxy nanocomposites produced in a homogenizer. Several experiments were conducted including different types of dispersion condition with varying processing conditions such as homogenizer rotor speed and applied time of homogenizer. The effects of these variables on the dispersion properties of nanocomposites were then studied. In order to fully understand the experimental results, a X-ray diffraction, DSC and DMA were used to investigate the effect of above mentioned variables on microstructure and intercalation/exfoliation of organic modifier clay/epoxy nanocomposites. The results from this work could be used to determine the best processing condition to obtain appropriate levels of d-spacing, glasss transition temperature and storage modulus in organic modifier clay/epoxy nanocomposites.

• Bulletin of the Korean Chemical Society
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• 제30권2호
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• pp.334-338
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• 2009

Trifunctional epoxy resin triglycidyl paraaminophenol (TGPAP)/$CaCO_3$ nanocomposites were prepared using the melt blending method. The effects of nano-$CaCO_3$ content on the thermal behaviors, such as cure behavior, glass transition temperature ($T_g$), thermal stability, and the coefficient of thermal extension (CTE), were investigated by several techniques. Differential scanning calorimetry (DSC) results indicated that the cure reaction of the TGPAP epoxy resin was accelerated with the addition of nano-$CaCO_3$. When the nano-$CaCO_3$ content was increased, the $T_g$ of the TGPAP/$CaCO_3$ nanocomposites did not obviously change, whereas the crosslinking density was linearly increased. The nanocomposites showed a higher thermal stability than that of the neat epoxy resin. This result could be attributed to the increased surface contact area between the nano-$CaCO_3$ particles and the epoxy matrix, as well as the high crosslinking density in the TGPAP/$CaCO_3$ nanocomposites. The CTE of the nanocomposites in the rubbery region was significantly decreased as the nano-$CaCO_3$ content was increased.

• E2M - 전기 전자와 첨단 소재
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• 제7권3호
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• pp.187-199
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• 1994

In order to find an effect of structural changes due to variation of addition ratio of anhydride hardener and postcuring herat-treatments upon electrical properties of epoxy composites, the dielectric properties over a frequency range from 30[Hz] to l[MHz] were investigated in the temperature range of 20-180[.deg. C]. From the dielectric properties, the a peaks related with glass-transition phenomena of epoxy network appeared near 130[.deg. C], the conduction loss in high temperature region above 150[.deg. C] due to thermal dissociation of hardener started off with the low frequency side and the .betha. peak concerned with contribution of movable unreacted terminal epoxy groups and curing agents in the glass states concurred with the high-frequency side below 20[.deg. C]. And an effect of an hydride hardener upon structural changes and of postcuring heat treatments upon structural stability in epoxy composites would be explained through the estimation of the distribution of relaxation times and the activation energy for a .alpha. peak according to the WLF equations.

• Composites Research
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• 제26권5호
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• pp.315-321
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• 2013

본 연구에서는 탄소재료의 우수한 열적 특성을 이용하여 에폭시 수지의 열전도도 특성을 향상시키기 위해 Pitch 탄화유리섬유를 제조하고 산처리 기능화 방법을 수행하여 형태학적, 기계적, 및 열전도 특성을 관찰하였다. 그 결과, 산처리 기능화된 Pitch 탄화유리섬유는 에폭시 수지 내에서 분산성 및 계면결합력이 향상됨에 따라 기계적 물성 및 열전도 특성이 증가함을 확인하였다. 특히, Pitch 탄화유리섬유 복합재료 내의 Pitch 탄화유리섬유의 함량이 증가함에 따라 기계적 물성 및 열전도 특성이 증가하여, 탄소섬유 복합재료보다 기계적 물성은 10%, 열전도 특성은 150% 향상됨을 확인하였다. 따라서, 본 연구에서 제조된 Pitch 탄화유리섬유의 우수한 구조배향성 및 계면결합력은 에폭시수지내의 분산성을 향상시키고 열전도성 경로를 형성하여 에폭시수지의 우수한 기계적 및 열전도 특성에 영향을 미치는 것으로 판단된다.

• Macromolecular Research
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• 제15권1호
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• pp.10-16
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• 2007

In this work, we prepared epoxy/BMI composites by using N,N'-bismaleimide-4,4'-diphenylmethane (BMI), epoxy resin (diglycidyl ether of bisphenol-A (DGEBA)), and 4,4'-diamino diphenyl methane (DDM). The thermal properties and water sorption behaviors of the epoxy and BMI composites were investigated. For the epoxy/BMI composites, the glass transition and decomposition temperatures both increased with increasing BMI addition, which indicates the effect of BMI addition on improved thermal stability. The water sorption behaviors were gravi-metrically measured as a function of humidity, temperature, and composition. The diffusion coefficient and water uptake decreased and the activation energy for water diffusion increased with increasing BMI content, indicating that the water sorption in epoxy resin, which causes reliability problems in electronic devices, can be diminished by BMI addition. The water sorption behaviors in the epoxy/BMI composites were interpreted in terms of their chemical and morphological structures.

• Korean Chemical Engineering Research
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• 제50권5호
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• pp.894-899
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• 2012

폐 전자제품의 양이 지속적으로 증가하므로 폐 인쇄회로기판(WPCBs: waste printed circuit boards)의 재활용에서 금속과 유리섬유 및 에폭시 수지를 분리하는 방법에 대한 연구가 필요하다. 본 연구에서는 WPCBs로부터 금속과 유리섬유 및 에폭시 수지를 분리하기위해 dimethylformamide 용매와 어트리션 밀 반응기를 사용하였다. WPCBs에서 유리섬유의 분리는 다양한 교반기를 이용하여 교반속도를 300~600 rpm에서 반응시간을 1~2 h에서 반응을 수행하였다. WPCBs에서 에폭시 수지의 분리도를 재생 유리섬유의 열 중량 분석을 통해 분석하였으며 기계화학적 방법인 어트리션밀 교반기에서 에폭시 수지의 분리도가 증가하였다. 재생 유리섬유를 보강재로 재활용하기 위하여 재생 유리섬유/불포화 폴리에스테르 수지 복합재료로 적용하였다.

• 박물관보존과학
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• 제15권
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• pp.26-37
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• 2014

국립중앙박물관 보존과학부에서는 국보 제193호 봉수형유리병의 구조적 안정성을 향상시키고 봉수형유리병 본연의 색과 투명도를 되살리기 위하여 재보존처리를 하기로 하였다. 재보존처리에 앞서 유리 재질 보존에 적합한 재료를 선정하기 위하여 에폭시 수지, 아크릴 수지, 광경화성 수지, 물유리에 대한 재료 실험을 하였다. 이 결과 접착제로는 시아노아크릴레이트 수지, 아크릴 수지, 광경화성 수지가, 복원 재료로는 아크릴 수지가 적합할 것으로 판정되었다. 단, 사용 방법에 있어 시아노아크릴레이트 수지는 단독 사용을 피하고 에폭시 수지는 착탈식으로 보존처리해야 한다.

• 한국안전학회지
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• 제21권3호
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• pp.73-80
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• 2006

Generally beam design depends on the yielding and maximum strength of each member varying with its section shape. Web plate of H-shape beam has not been substituted with glass plate, because it is known that its strength and heat properties are different and it is limited to substitute the existing steel web with glass element. Ceiling height of each room should be decreased with more than 60-80cm due to the beam. Differently from this condition, glass web beam has a good point to see through it and sunshine can be penetrate into the other size especially when it is installed as of outside wall. And also, it can be safer due to controlling room inside easier, if the strength is applicate. This study is to show some applicability after finding out the properties using the test. The test members with a size of $1,600{\times}200{\times}300{\times}9mm$ being SS41 rolled steel having THK 9mm flange while having 8,10mm and reinforced glass 12mm thickness is bonded with epoxy bond under the condition of temperature $28^{\circ}C$, humidity 50%, bonding power 24Mpa. It is show reinforced glass has 5 times of fracture stress more than the common glass but $50{\sim}150%$ difference between these 2 kinds of glass was shown. Reinforce glass did not support the original upper flange after fracture but the common glass did the upper flange after unloading. Generally reinforced glass is stronger than the common one but the common glass having a part of crack on it, compared with reinforced glass having the overall fracture could be more useful in case of needing ductility.

• 한국해양공학회지
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• 제12권3호통권29호
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• pp.31-41
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• 1998

Single fiber fragmentation technique was used to evaluate the change of interfacial properties by degradation of fiber tensile strength in the fiber reinforced composites. The influences of fiber tensile strength on the interfacial properties have been evaluated by the fragmentation specimens(weak fiber samples) of glass fiber/epoxy resin that was made using the pre-degraded glass fiber in distilled water at $80^{circ}C$ for specified periods. The effects of the immersion time on the interfacial properties in the distilled water at $80^{circ}C$ also have been evaluated by the fragmentation specimens(original fiber samples) of glass fiber/epoxy resin that was made using the received glass fiber. As the result, the tensile strength of glass fiber was decreased with the increasing of the treatment time in the distilled water at $80^{circ}C$ and the interfacial shear strength was independent of the change of the glass fiber strength in the single fiber fragmentation test. But in the durability test using the single fiber fragmentation specimen, interfacial shear strength decreased with the increasing of the immersion time in distilled water ar $80^{circ}C$. And it turned out that the evaluating of interfacial shear strength using original fiber tensile strength was valuable in the durability test for the water environment by the single fiber fragmentation technique.