• Title/Summary/Keyword: Geopolymer Concrete

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Anti-Corrosion Property of Geopolymer Evaluated by an Impressed Current Cathodic Protection Method, Exposed to Marine Environment (염해환경에서 외부전원법에 의한 지오폴리머 시험체 보강철근의 방식특성 평가)

  • Lee, Hae-Seung;Cho, Ggu-Hwan;Park, Dong-Cheon
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.5
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    • pp.397-405
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    • 2014
  • There are many literatures reporting that the service life of re-bars in concrete structures is reduced in the oceanic environment due to chloride attack. To solve this problem, this study used geo-polymer as a mix material for concrete to increase its resistance to salt damage, and the external voltage method, one of the electric methods, is was applied to evaluate the likelihood of re-bars in the oceanic structure being exposed to the extreme salt environment. The items evaluated include the natural potential of re-bars and the corrosion rate. The results of the tests showed that in all of the salt environmental conditions (submerged zone, tidal zone, and crack), the tested materials were remarkably effective compared with ordinary concrete. The corrosion protective property was found not only in the evaluation of the natural potential but also in the evaluation of the corrosion rate, suggesting that the external voltage method can be used stably for geo-polymer RC structures in an extreme salt environment.

Efficient repair of damaged FRP-reinforced geopolymeric columns using carbon fiber reinforced polymers

  • Mohamed Hechmi El Ouni;Ali Raza;Khawar Ali
    • Structural Engineering and Mechanics
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    • v.87 no.6
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    • pp.585-599
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    • 2023
  • Geopolymer concrete (GC) can be competently utilized as a practical replacement for cement to prevent a high carbon footprint and to give a direction toward sustainable concrete construction. Moreover, previous studies mostly focused on the axial response of glass fiber reinforced polymer (glass-FRP) concrete compressive elements without determining the effectiveness of repairing them after their partial damage. The goal of this study is to assess the structural effectiveness of partially damaged GC columns that have been restored using carbon fiber reinforced polymer (carbon-FRP). Bars made of glass-FRP and helix made of glass-FRP are used to reinforce these columns. For comparative study, six of the twelve circular specimens-each measuring 300 mm×1200 mm-are reinforced with steel bars, while the other four are axially strengthened using glass-FRP bars (referred to as GSG columns). The broken columns are repaired and strengthened using carbon-FRP sheets after the specimens have been subjected to concentric and eccentric compression until a 30% loss in axial strength is attained in the post-peak phase. The study investigates the effects of various variables on important response metrics like axial strength, axial deflection, load-deflection response, stiffness index, strength index, ductility index, and damage response. These variables include concentric and eccentric compression, helix pitch, steel bars, carbon-FRP wrapping, and glass-FRP bars. Both before and after the quick repair process, these metrics are evaluated. The results of the investigation show that the axial strengths of the reconstructed SSG and GSG columns are, respectively, 15.3% and 20.9% higher than those of their original counterparts. In addition, compared to their SSG counterparts, the repaired GSG samples exhibit an improvement in average ductility indices of 2.92% and a drop in average stiffness indices of 3.2%.

Flexural behavior of reinforced concrete beams strengthened with a hybrid inorganic matrix - steel fiber retrofit system

  • Papakonstantinou, Christos G.;Katakalos, Konstantinos
    • Structural Engineering and Mechanics
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    • v.31 no.5
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    • pp.567-585
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    • 2009
  • The aim of this study was to investigate the flexural behavior of reinforced concrete beams strengthened with a novel strengthening system. Concrete beams were strengthened with a hybrid retrofit system consisting of high strength steel cords impregnated in an inorganic fireproof matrix (Geopolymer). The strengthened reinforced concrete beams along with non-strengthened control beams were tested monotonically under four point bending loading conditions. Moreover, an analytical model is introduced, that can be used to analyze the flexural performance of the strengthened beams. The experimental results indicate that the failure of the strengthened beams was based on the yielding of the reinforcement in the tension face of the beams, followed by a local slippage of the steel cords. The flexural stiffness of the strengthened beams was significantly improved compared to the stiffness of the non-strengthened beams. In conclusion, the strengthening system can provide an effective alternative to commercially available systems.

Synchrotron X-ray diffraction study on alkali-activated slag cement and fly ash-based geopolymers (플라이 애시 지오폴리머와 활성 슬래그 시멘트 생성물의 방사광 X선 회절 실험 연구)

  • Oh, Jae-Eun;Jun, Ssang-Sun;Choi, Se-Jin;Paulo, J.M-Monteiro
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.319-320
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    • 2009
  • The alkali activation products of slag, fly ash C and fly ash F were investigated using compressive strength test and synchrotron x-ray diffraction. We propose that the predominantly amorphous geopolymer formed under ambient conditions is a disordered form of one of the ABC-6 group of zeolites, which includes poly-types such as hydroxycancrinite, hydroxysodalite, chabazite, levyne or fransinite.

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Development of Geopolymer Mortar Based on Fly Ash (플라이애시 기반 지오폴리머 모르타르 개발)

  • Koh, Kyung-Taek;Ryu, Gum-Sung;Lee, Jang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.119-126
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    • 2012
  • Portland cement production-1.5billion tonnes yearly worldwide-contributes substantially to global atmospheric pollution(7% of total of $CO_2$ emissions). Attempts to increase the utilization of fly ash, by-products from thermal power plant to partially replace the cement in concrete are gathering momentum. But most of fly ash is currently dumped in landfills, thus creating a threat to the environment. Many researches on alkali-activated concrete that does not need the presence of cement as a binder have been carried out recently. Instead, the sources of material such as fly ash, that are rich in Silicon(Si) and Aluminium(Al), are activated by alkaline liquids to produce the binder. Hence concrete with no cement is effect reduction of $CO_2$ gas. In this study, we investigated the influence of the compressive strength of mortar on alkaline activator and curing condition in oder to develop cementless fly ash based alkali-activated concrete. In view of the results, we found out that it was possible for us to make alkali-activated mortar with 70MPa at the age of 28days by using alkaline activator manufactured as 1:1 the mass ratio of 9M NaOH and sodium silicate and applying the atmospheric curing after high temperature at $60^{\circ}C$ for 48hours.

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The Compressive Strength Development of Briquette Ash by Alkali Activated Reaction (알칼리 활성반응에 의한 Briquette ash의 강도 발현 특성)

  • Seo, Myeong-Deok;Lee, Su-Jeong;Park, Hyun-Hye;Kim, Yun-Jong;Lee, Su-Ok;Kim, Taik-Nam;Cho, Sung-Baek
    • Korean Journal of Materials Research
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    • v.18 no.9
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    • pp.463-469
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    • 2008
  • Non-sintering cement was manufactured with briquette ash. Alkali activator for compression bodies used a NaOH solution. In order to apply alkali-activated briquette ash and the non-sintering cement to concrete, several experimental studies were performed. It was necessary to study the binder obtained by means of a substitute for the cement. This study concentrated on strength development according to the concentration of NaOH solution, the curing temperature, and the curing time. The highest compressive strength of compression bodies appeared as $353kgf/cm^2$ cured at $80^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is needed to get a higher strength body. Also, geopolymerization was examined by SEM and XRD analysis after the curing of compression bodies. According to SEM and XRD, the main reaction product in the alkali activated briquette ash is aluminosilicate crystal.

Hybrid fuzzy model to predict strength and optimum compositions of natural Alumina-Silica-based geopolymers

  • Nadiri, Ata Allah;Asadi, Somayeh;Babaizadeh, Hamed;Naderi, Keivan
    • Computers and Concrete
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    • v.21 no.1
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    • pp.103-110
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    • 2018
  • This study introduces the supervised committee fuzzy model as a hybrid fuzzy model to predict compressive strength (CS) of geopolymers prepared from alumina-silica products. For this purpose, more than 50 experimental data that evaluated the effect of $Al_2O_3/SiO_2$, $Na_2O/Al_2O_3$, $Na_2O/H_2O$ and Na/[Na+K] on (CS) of geopolymers were collected from the literature. Then, three different Fuzzy Logic (FL) models (Sugeno fuzzy logic (SFL), Mamdani fuzzy logic (MFL), and Larsen fuzzy logic (LFL)) were adopted to overcome the inherent uncertainty of geochemical parameters and to predict CS. After validating the model, it was found that the SFL model is superior to MFL and LFL models, but each of the FL models has advantages to predict CS. Therefore, to achieve the optimal performance, the supervised committee fuzzy logic (SCFL) model was developed as a hybrid method to combine the benefits of individual FL models. The SCFL employs an artificial neural network (ANN) model to re-predict the CS of three FL model predictions. The results also show significant fitting improvement in comparison with individual FL models.

A new geopolymeric grout blended completely weathered granite with blast-furnace slag

  • Zhang, Jian;Li, Shucai;Li, Zhaofeng;Li, Hengtian;Du, Junqi;Gao, Yifan;Liu, Chao;Qi, Yanhai;Wang, Wenlong
    • Advances in concrete construction
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    • v.9 no.6
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    • pp.537-545
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    • 2020
  • In order to reduce the usage of cement slurry in grouting engineering and consume the tunnel excavation waste soil, a new geopolymeric grouting material (GGM) was prepared by combine completely weathered granite (CWG) and blast-furnace slag (BFS), which can be applied to in-situ grouting treatment of completely weathered granite strata. The results showed CWG could participate in the geopolymerization process, and GGM slurry has the characteristics of short setting time, high flowability, low viscosity, high stone rate and high mechanical strength, and a design method of grouting pressure based on viscosity evolution was proposed. By adjusted the content of completely weathered granite and alkali activator concentration, the setting time of GGM were ranged from 5 to 30 minutes, the flowability was more than 23.5 cm, the stone rate was higher than 90%, the compressive strength of 28 days were 7.8-16.9 MPa, the porosity were below 30%. This provides a novel grouting treatment and utilizing excavated soil of tunnels in the similar strata.

Analysis of Mechanical Properties and Micro structure of Fly Ash Based Alkali-activated Mortar (플라이애쉬 기반(基盤) 알칼리 활성(活性) 모르타르의 역학적(力學的) 특성(特性) 및 미세구조(微細構造) 분석(分析))

  • Ryu, Gum-Sung;Koh, Kyung-Taek;Chung, Young-Soo
    • Resources Recycling
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    • v.21 no.3
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    • pp.28-38
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    • 2012
  • The purpose of this paper is to develop the alkali-activated concrete which uses 100% fly ash as a binder without any cement. The compressive strength of the mortar was examined depending on the chemical change in alkali-activator through SEM and SEM/EDS observations and the XRD analysis. It was found from the test that the higher molar concentration induced the greater effect on the initial strength, and that $Si^{4+}$ and $Al^{3+}$ were eluted relative to the compressive strength of mortar. In addition, it was confirmed that Al and Si were determined to be most influential ingredients on the microstructural development of the mortar, and that the different ingredient of the activator was almost no change in solidity from the XRD analysis.

Valorization of bottom ash with geopolymer synthesis: Optimization of pastes and mortar

  • Froener, Muriel S.;Longhi, Marlon A.;de Souza, Fabiana;Rodriguez, Erich D.;Kirchheim, Ana Paula
    • Advances in concrete construction
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    • v.14 no.1
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    • pp.1-13
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    • 2022
  • Due to the physical-chemical characteristics of some bottom ash (BA), there are technical, economic and environmental limitations to find a destination that will add value to it. In Brazil, this residue is eventually used for filling coal extraction pits or remains in sedimentation ponds, creating a susceptible panorama to environmental issues. The geopolymers binders are one of the alternatives to the proper use high amounts of these materials. In this work, geopolymeric binder pastes were produced with BA mixed to activators with different alkali contents (expressed as %Na2O), as well as the incorporation of soluble silicates (Ms content). The production of binary geopolymeric pastes based on the use of two industrial wastes: fluid catalytic cracking (FCC) and aluminum anodizing sludge (AAS), was also assessed. The content in mass of BA/FCC and BA/AAS ranged from 100/0, 90/10; 80/20 and 70/30. Systems with soluble silicates as activator in a molar ratio SiO2/Na2O of 1.0 (Ms = 1.0) and Na2O content of 15%, showed the best results of mechanical strength (42 MPa at day 28th). The improvement is up to 5X when compared to NaOH based systems. For systems with partial replacement of BA of 10% of AAS and 20% of FCC (80/20), the presence of soluble silicates was also effective to increase compressive strength.