• Title/Summary/Keyword: Gaseous Phase

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Development of an Apparatus for the Determination of In Vitro Metabolic Rate Constants of Volatile Organic Chemicals (휘발성 유기용매의 In vitro 대사속도 측정 장치의 개발)

  • Hwang, In-Young;Lee, Yoon
    • Environmental Analysis Health and Toxicology
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    • v.12 no.3_4
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    • pp.43-54
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    • 1997
  • Species, doses and routes extrapolation can be sucessfully carried out by using a physiologically-based pharmacokinetic (PBPK) approach. And PBPK approach to assess risk of hazardous chemicals is reasonable whatever the exposure scenarios are happened. Both partitioning coefficients of chemical between tissue and blood and enzymatic metabolic rate constants are key parameters to build up the PBPK model. In this study, we tried to estimate in vitro metabolic rate constants using a special apparatus instead to measure the in vivo constants which are used to PBPK simulation since the in vitro tests are less expensive and more convenient than in vivo tests. For the purpose, we designed and tested the new system to measure continuously the headspace concentration of VOC. The newly designed system is composed with a diffusion chamber which generates gaseous substrate, a reaction vessel with a recirculating pump to establish a closed system, an autbmatic sampler from a gas phase, a gas chromatography to analyze the headspace. In addition, a cold water condenser is attached between the reaction vessel and pump to reduce the content of gaseous moisture which interferes with chemical analysis. To validate the newly developed methodology, in vitro metabolic rate constants of trichloroethylene (TCE) as a prototype VOC were estimated by simulating observed results with an ACSL program. The simulated results are consistent to those estimated by the other research groups. This finding suggests that our newly designed closed system may be a useful apparatus to estimate in vitro metabolic rate constants for VOC.

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Distinction between HAPS and LEO Satellite Communications under Dust and Sand Storms Levels and other Attenuations

  • Harb, Kamal
    • International Journal of Computer Science & Network Security
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    • v.22 no.3
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    • pp.382-388
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    • 2022
  • Satellite communication for high altitude platform stations (HAPS) and low earth orbit (LEO) systems suffer from dust and sand (DU&SA) storms in the desert regions such as Saudi Arabia. These attenuations have a distorting effect on signal fidelity at high frequency of operations. This results signal to noise ratio (SNR) to dramatically decreasing and leads to wireless transmission error. The main focus in this paper is to propose common relations between HAPS and LEO for the atmospheric impairments affecting the satellite communication networks operating above Ku-band crossing the propagation path. A double phase three dimensional relationship for HAPS and LEO systems is then presented. The comparison model present the analysis of atmospheric attenuation with specific focus on sand and dust based on particular size, visibility, adding gaseous effects for different frequency, and propagation angle to provide system operations with a predicted vision of satellite parameters' values. Skillful decision and control system (SD&CS) is proposed to control applied parameters that lead to improve satellite network performance and to get the ultimate receiving wireless signal under bad weather condition.

Reduction of a Numerical Grid Dependency in High-pressure Diesel Injection Simulation Using the Lagrangian-Eulerian CFD Method (Lagrangian-Eulerian 기법을 이용한 고압 디젤 분무 시뮬레이션의 수치해석격자 의존성 저감에 관한 연구)

  • Kim, Sa-Yop;Oh, Yun-Jung;Park, Sung-Wook;Lee, Chang-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.1
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    • pp.39-45
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    • 2012
  • In the standard CFD code, Lagrangian-Eulerian method is very popular to simulate the liquid spray penetrating into gaseous phase. Though this method can give a simple solution and low computational cost, it have been reported that the Lagrangian spray models have numerical grid dependency, resulting in serious numerical errors. Many researches have shown the grid dependency arise from two sources. The first is due to unaccurate prediction of the droplet-gas relative velocity, and the second is that the probability of binary droplet collision is dependent on the grid resolution. In order to solve the grid dependency problem, the improved spray models are implemented in the KIVA-3V code in this study. For reducing the errors in predicting the relative velocity, the momentum gain from the gaseous phase to liquid particles were resolved according to the gas-jet theory. In addition, the advanced algorithm of the droplet collision modeling which surmounts the grid dependency problem was applied. Then, in order to validate the improved spray model, the computation is compared to the experimental results. By simultaneously regarding the momentum coupling and the droplet collision modeling, successful reduction of the numerical grid dependency could be accomplished in the simulation of the high-pressure injection diesel spray.

Source Identification of Gaseous Mercury Measured in New York State Using Hybrid Receptor Modeling (수용원 모델을 사용한 대기 중 수은 오염원의 위치 추정에 대한 연구)

  • Han Young-Ji
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.2
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    • pp.179-189
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    • 2006
  • Ambient gas phase mercury concentrations including elemental mercury ($Hg^0$) were measured at the Potsdam, Stockton, and Sterling sites in NY from 2000 to 2003. Also, concentrations of ambient reactive gaseous mercury (RGM; $Hg^{2+}$) were measured at the Potsdam site during one year. The contribution of RGM($4.2{\pm}6.4pg/m^3$) was about $0.2{\sim}3%$ of the total gas phase mercury concentration measured (TGM: $1.84{\pm}1.24,\;1.83{\pm}0.32,\;3.02{\pm}2.14ng/m^3$ in Potsdam. Stockton, and Sterling, respectively) at the receptor sites. Potential Source Contribution Function (PSCF), a hybrid receptor modeling incorporating backward trajectories was performed to identify source areas of TGM. Using PSCF, southern New York, North Carolina, and eastern Massachusetts were identified as important source areas in the United States, while the copper smelters and waste incinerators located in eastern Quebec and Ontario were determined to be significant sources in Canada. The Atlantic Ocean was suggested to be a possible mercury source. PSCF incorporating back-dispersion and deposition was applied for RGM , as well as PSCF based on 2-days back-trajectories. Two different approaches yielded considerably different results, primarily due to the consideration of dispersion rather than deposition. Using back-trajectory based PSCF, eastern Ohio, southern New York, and southern Pennsylvania where large coal -fired power plants area located were identified as the large sources in US. Metallurgical industry located in eastern Quebec was resolved as well. From the result of back-dispersion and deposition based PSCF, Pennsylvania, mining facilities around Lake Superior, Toronto, Boston, MA, Quebec, and coal power plants in NY were identified to be the significant source areas for Potsdam site.

Numerical Study on Pulverized Coal Combustion Applying Two-Phase WSGGM (이상 회체가스 가중합산모델을 적용한 미분탄 연소의 수치적 연구)

  • Yu, Myoung-Jong;Kang, Shin-Jae;Baek, Seung-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.10
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    • pp.1368-1379
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    • 2000
  • A numerical study on swirling pulverized coal combustion in an axisymmetric enclosure is carried out by applying the 2-phase weighted sum of gray gases model (WSGGM) approach with the discrete ordinate method (DOM) to model the radiative heat transfer equation. In the radiative transfer equation, the same polynomial equation and coefficients for weighting factors as those for gas are adopted for the coal/char particles as a function of partial pressure and particle temperature. The Eulerian balance equations for mass, momentum, energy, and species mass fractions are adopted with the standard and RNG k-${\varepsilon}$ turbulence model, whereas the Lagrangian approach is used for the particulate phase. The eddy-dissipation model is employed for the reaction rate for gaseous mixture, and the single-step and two-step first-order reaction model for the devolatilization process for coal. Special attention is given to establish the thermal boundary conditions on radiative transfer equation By comparing the numerical results with experimental ones, the radiation model used here is confirmed and found to provide an alternative for simulating the radiative transfer.

Combustion Modeling of a Solid Fuel Bed with Consideration of the Multiple Solid Phases (다중 고체상을 고려한 고체 연료층 연소 모델링)

  • Yang, Won;Ryu, Chang-Kook;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.119-127
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    • 2003
  • In this study we propose an unsteady I-dimensional model of bed combustion with multiple solid phases, which confers a phase on each solid material. This model can be applied to a variety of bed combustion cases of various configurations and ignition methods. It contains fuel combustion, gaseous reaction, heat transfers between each phase, and geometric changes of the solid particles. An iron ore sintering pot is selected for verifying the model validity and simulation results are compared with the limited experimental data set of various coke contents and air supply rates. They predict the experimental results well and show applicabilities to the various system of the fuel bed with various solid materials.

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Methodology for Describing Different Phase States of Molecular Nitrogen

  • Cho, Haeng Muk;Kudryavtsev, I.N.;Kramskoy, A.V.
    • Journal of Energy Engineering
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    • v.23 no.4
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    • pp.215-222
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    • 2014
  • A theory-based methodology for describing the thermodynamic properties of molecular nitrogen is presented. The results obtained indicate a successful application of a fully consistent statistical method for the description of a molecular system in different phase states. The method employs a density of states equation for solid nitrogen and a perturbation potential for gaseous and liquid nitrogen. The main characteristics of the calculation method include the need for a minimal number of initial data and the absence of fitting parameters. The adequacy of the physical model that is the basis for the method allows a description of existing experimental data and the peculiarities of the thermodynamic properties.

SPECTRAL BEHAVIORS OF Hβ LINE OF CH CYGNI IN A QUIESCENT PHASE

  • YOO KYE HWA;KIM KANG MIN;LEE BYUNG CHUL;YOON TAE SEOG;LEE JUNG AE
    • Publications of The Korean Astronomical Society
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    • v.19 no.1
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    • pp.21-25
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    • 2004
  • We analyzed the high resolution H,6 line spectra of CH Cygni obtained at the Bohyunsan Astronomical Observatory (BOAO) on April 2004. The temporal changes in the $H\beta$ line profiles are reported. We obtained the equivalent widths of the Gaussian components. Using this we estimated the length of the gaseous nebula which emits the $H\beta$ line and the mass loss rate from the star.

Different chemical and dynamical environments in two massive star forming regions, G19.61-0.23 and G75.78+0.34

  • Baek, Giseon;Lee, Jeong-eun;Cho, Se-Hyung;Yun, Youngjoo
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.1
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    • pp.55.4-56
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    • 2017
  • Complex organic molecules (COMs) are commonly detected in star forming regions and considered important species since they are seeds of prebiotic molecules. Although COMs form in ice mantles on dust grains, they are preferentially detected in the gas phase. The origin of the gaseous COMs highly depends on the circumstance of each star forming region. Therefore, the distribution of COMs emission reflects the physical and chemical conditions of the region. We present the newly detected COMs, especially methanol emission lines toward two massive star forming regions, G19.61-0.23 and G75.78+0.34 in the Atacama Large Millimeter/submillimeter Array Band 3 observations during the Cycle 2 phase. Multiple transitions of methanol are detected in both regions but show different emission morphology. The origin of the desorption (e.g. shocks or high energy photons) is discussed.

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Modeling of Coke Combustion and Heat Transfer in an Iron Ore Sintering Bed with Considerations of Multiple Solid Phases (다중 고체상을 고려한 소결기의 코크스 연소-열전달 모델링)

  • Yang, Won;Ryu, Chang-Kook;Choi, Sang-Min
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.79-84
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    • 2003
  • In this study we propose an unsteady I-dimensional model of an iron ore sintering bed with multiple solid phases, which confers a phase on each solid material. This model contains coke combustion, limestone decomposition, gaseous reaction, heat transfers between each phase, and geometric changes of the solid particles. Simulation results are compared with the limited experimental data set of various coke contents and air supply rates. Effect of the coke diameter is also evaluated. They predict the experimental results well and show applicabilities to the various system of the fuel bed with various solid materials.

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