• Title/Summary/Keyword: Gaseous

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Properties of CdS Thin Films Prepared by CMD Method (CMD 방법으로 제조한 CdS 박막의 특성)

  • 정길룡;임호빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1992.05a
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    • pp.46-49
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    • 1992
  • Cadmium sulfide thin films were deposited on glass substrate by Chemical Mist Deposition from solutions containing equimolar (0.1M) cadmium chloride and thiourea [(NH$_2$)$_2$CS] at a mist velocity of 1.6m/sec. Substrate temperatures were ranged between 200$^{\circ}C$ and 400$^{\circ}C$. The microstructure and semiconducting property of the films were investigated using SEM, X-ray diffraction, UV transmittance measurement and four point probe method. All the films have hexagonal structure and diffraction patterns indicate that the intensity of (112) and (101) reflections increase with increasing substrate temperature, whereas (002) reflection substrate temperature, whereas(002) reflection decrease for substrate temperatures between 250$^{\circ}C$ and 350$^{\circ}C$. The films prepared at lower temperature have a significant number of pinholes due probably to entrapped gaseous reaction. Optical transmittance of the films deposited at 350$^{\circ}C$ was about 75%. Optical bandgap of the films were 2.43eV regardless of substrate temperature. The dark resistivity of the films decreased with increasing substrate temperature up to 300$^{\circ}C$ and increased with further increasing substrate temperature. The films were photosensitive and had dark-to-light resistivity ratios of about 10 at room temperature for a white-light photoexcitation intensity of 50mw/$\textrm{cm}^2$.

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Effect of Adding Al-Ca Fluoride on Sintering Behavior of Aluminum-Bronze Powder

  • Masuoka, Sachiko;Arami, Yoshiro;Nagai, Shozo
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.276-277
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    • 2006
  • In order to accelerate the sintering of Al-Bronze powder covered with passive oxide film, we focused on the way to add Al-Ca fluoride consisting of $AlF_3$ and $CaF_2$, examined the effect of the $CaF_2$ mixing rate in Al-Ca fluoride, the amount of the added Al-Ca fluoride and the sintering temperature on sintering properties of Al-Bronze powder and considered the mechanism of the sintering acceleration. Al-Bronze powder was sintered most effectively by adding Al-Ca fluoride with the $CaF_2$ mixing rate of 20mass%. If the amount of added fluoride was over 0.05mass% and the sintering temperature was over 1123K, the sintering acceleration of the Al-Bronze powder appears. Regarding the mechanism of the sintering acceleration, it was presumed that $Al_2O_3$ film on the surface of the Al-Bronze particles was removed in the process of the formation of gaseous AlOF by the reaction with $AlF_3$, and the reaction was accelerated further by the presence of the liquid phase which is formed in Al-Ca fluoride.

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An Experimental Assessment of Combustion Stability of Coaxial Swirl Injectors and an Impinging Injector through Simulating Combustion Test (상압기상연소시험을 통한 동축형 스월 분사기와 충돌형 분사기의 연소 안정성 평가)

  • Park, Junhyeong;Kim, Hongjip
    • Journal of the Korean Society of Combustion
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    • v.22 no.1
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    • pp.46-52
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    • 2017
  • High-frequency combustion instabilities may occur during the development of feasible engine combustors. These instabilities can result in irreparable damages to the wall of combustors or the degradation of engine performance. So, it is essential to identify injectors that have high stability characteristics during the early stages of development. The objective of present study was to assess the stability of coaxial injectors and an impinging injector with different recess lengths in order to develop stable injectors optimally. Stability margin was evaluated based on the distance from operating condition to the unstable regions. A simulating combustion test method was used to analyze the stability of injectors. A small-scale combustion chamber was designed to simulate the first tangential acoustic mode of the actual combustor. Gaseous oxygen and a mixture of methane and propane were used as simulant propellants to satisfy their flow similarity to the actual propellants of a combustor in a liquid rocket combustor. The results indicated that injectors having small recess lengths showed relatively large combustion stability margins. For the injectors of large recess lengths, instability regions with large and super-large amplitude oscillations were observed. Thus, injector with shorter recess lengths had a higher stability than that of longer one due to the different mixing processes.

Effect of AC electric fields on Free Jet Flow in a Laminar (층류 자유제트유동에 인가된 교류전기장의 영향)

  • Kim, Gyeong Taek;Lee, Won June;Cha, Min Suk;Park, Jeong;Chung, Suk Ho;Kwon, Oh Boong;Kim, Min Kuk;Lee, Sang Min;Yun, Jin Han;Keel, Sang In
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.79-81
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    • 2015
  • The experimental study on gasesous laminar free-jet flow was investigated by applying high voltage alternating current (AC) to the nozzle. The jet flows were affedcted significatly by AC electric fields particularly at high voltages for applied frequencies less than 80 Hz, while those were not responded to further increased frequencies. Under certain AC conditions of applied voltgae and frequency, the laminar gaseous fuel stem was broken down at an axial distance and subsequently separtaed into some parts. The velocity fields in jet flows interactiong with applied electric fields were compared with those without having electric field. Interaction of applying electric fields with laminar free jet flow was discussed in detail, and the possible mechanism was also explained.

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Photocatalytic Degradation of Gaseous Formaldehyde and Benzene using TiO2 Particulate Films Prepared by the Flame Aerosol Reactor

  • Chang, Hyuksang;Seo, Moonhyeok
    • Environmental Engineering Research
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    • v.19 no.3
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    • pp.215-221
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    • 2014
  • Nano-sized $TiO_2$ particles were produced by a premixed flame aerosol reactor, and they were immobilized on a mesh-type substrate in form of particulate film. The reactor made it possible maintaining the original particulate characteristics determined in the flame synthetic process. The particulate morphology and crystalline phase were not changed until the particulate were finally coated on the substrate, which resulted in the better performance of the photocatalytic conversion of the volatile organic compounds (VOCs) in the ultraviolet $(UV)-TiO_2$ system. In the flame aerosol reactor, the various specific surface areas and the anatase weight fractions of the synthesized particles were obtained by manipulating the parameters in the combustion process. The performance of the $TiO_2$ particulate films was evaluated for the destruction of the VOCs under the various UV irradiation conditions. The decomposition rates of benzene and formaldehyde under the irradiation of UV-C of 254 nm in wavelength were evaluated to check the performance of $TiO_2$ film layer to be applied in air quality control system.

A Pesticide Residue Risk Assessment from Agricultural Land Using GIS

  • Lee, Ju-Young;Krishina, Ganeshy;Han, Moo-Young;Yang, Jung-Seok;Choi, Jae-Young
    • Environmental Engineering Research
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    • v.13 no.3
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    • pp.107-111
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    • 2008
  • Water quality contamination issues are of critical concern to human health, whilst pesticide release generated from irrigated land should be considered for protecting natural habitats and human health. This paper suggests new method for evaluation and analysis using the GIS technique based on integrated spatial modeling framework. The pesticide use on irrigated land is a subset of the larger spectrum of industrial chemicals used in modern society. The behavior of a pesticide is affected by the natural affinity of the chemical for one of four environmental compartments; solid matter, liquid, gaseous form, and biota. However, the major movements are a physical transport over the ground surface by rainfall-runoff and irrigation-runoff. The irrigated water carries out with the transporting sediments and makes contaminated water by pesticide. This paper focuses on risk impact identification and assessment using GIS technique. Also, generated data on pesticide residues on farmland and surface water through GIS simulation will be reflected to environmental research programs. Finally, this study indicates that GIS application is a beneficial tool for spatial pesticide impact analysis as well as environmental risk assessment.

Acetone PLIF for Fuel Distribution Measurements in Liquid Phase LPG Injection Engine (LPG 액상분사 엔진에서 아세톤 PLIF를 이용한 연료분포 측정기법 연구)

  • 오승묵;박승재;허환일;강건용;배충식
    • Transactions of the Korean Society of Automotive Engineers
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    • v.12 no.1
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    • pp.74-82
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    • 2004
  • Planar laser-induced fluorescence(PLIF) has been widely used to obtain two dimensional fuel distribution. Acetone PLIF is chosen because fluorescence signal from acetone as a fluorescent tracer is less sensitive to oxygen quenching than other dopants. Acetone PLIF is applied to measure quantitative air excess ratio distribution in an engine fueled with LPG. Acetone is excited by KrF excimer laser (248nm) and its fluorescence image is acquired by ICCD camera with a cut-off filter to suppress Mie scattering from the laser light. For the purpose of quantifying PLIF signal, an image processing method including the correction of laser sheet beam profile is suggested. Raw images are divided by each intensity of laser energy and profile of laser sheet beam. Inhomogeneous fluorescence images scaled with the reference data, which is taken by a calibration process, are converted to air excess ratio distribution. This investigation shows instantaneous quantitative measurement of planar air excess ratio distribution for gaseous fuel.

Theoretical and Experimental Considerations of Thermal Humidity Characteristics

  • Choi, Seok-Weon;Cho, Ju-Hyeong;Seo, Hee-Jun;Lee, Sang-Seol
    • International Journal of Aeronautical and Space Sciences
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    • v.3 no.1
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    • pp.9-18
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    • 2002
  • Thermal humidity characteristics were considered theoretically and experimentally. A Simply well-fitted correlation of a saturated vapor pressure-temperature curve of water was introduced based on Antoine equation to make theoretical prediction of relative humidity according to temperature variation. Characteristics of dew point were also examined theoretically and its relation with temperature and humidity was evaluated. The exact mass of water vapor in a specified humidity and temperature condition was estimated to provide useful insight into the idea about how much amount of water corresponds to a specified humidity and temperature condition in a confined system. A simple but well-fitting model of dehumidification process was introduced to anticipate the trend of relative humidity level during GN2(gaseous nitrogen) purge process in a humidity chamber. Well-suitedness of this model was also verified by comparison with experimental data. The overall appearance and specification of two thermal humidity chambers were introduced which were used to perform various thermal humidity tests in order to yield useful data necessary to support validity of theoretical models.

Shock compression of condensed matter using multi-material Reactive Ghost Fluid method : development and application (충격파와 연소 현상 하에서의 다중 물질 해석을 위한 Reactive Ghost Fluid 기법 개발 및 응용)

  • Kim, Ki-Hong;Yoh, Jai-Ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.37 no.6
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    • pp.571-579
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    • 2009
  • For the flow analysis of reactive compressible media involving energetic materials and metallic confinements, a Hydro-SCCM (Shock Compression of Condensed Matter) tool is developed for handling multi-physics shock analysis of energetics and inerts. The highly energetic flows give rise to the strong non-linear shock waves and the high strain rate deformation of compressible boundaries at high pressure and temperature. For handling the large gradients associated with these complex flows in the condensed phase as well as in the reactive gaseous phase, a new Eulerian multi-fluid method is formulated. Mathematical formulation of explosive dynamics involving condensed matter is explained with an emphasis on validating and application of hydro-SCCM to a series of problems of high speed multimaterial dynamics in nature.

A Study on Clean Agent Fire Extinguishing Ability Using Nitrogen and Novec Mixtures Gas (질소와 노벡 혼합가스를 이용한 청정소화약제의 소화성능에 관한 연구)

  • Lim, Woo-Sub;Jung, Jong-Jin;Nam, Dong-gun;SaKong, Seong-Ho;Kim, Jong-Won;Choi, Kenu-Joo
    • Journal of the Korean Society of Safety
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    • v.23 no.6
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    • pp.76-83
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    • 2008
  • In the course of increasing in human and material damage caused by fire, it is an important research field to develop clean extinguishing agent which does no harm to global environment as well as has a good extinguishing efficiency. This research is a basic step to develop a new clean extinguishing agent. In order to get a satisfactory result, we tested fire extinguishing ability using nitrogen and Novec mixtures gas which are inert gas and new clean extinguishing agent. We used Cup Burner Test made by international standard ISO-14520 regulations of gaseous extinguishing agent ability test, and the fuels used in the test are n-heptane, methanol, ethanol, iso-propanol and 1-butanol. The experimental results of flame extinguishing concentration are n-heptane 6.54%, methanol 8.47%, ethanol 6.98%, isopropanol 6.10% and butanol 6.54% by pure Novec agent. So the finding is that a new clean agent, Novec has an efficient extinguishing ability in a state of gas. Also, in a test as to mixtures gas of nitrogen and Novec, it has a good result for minimum oxygen concentration is under 16%.