• 대한화학회지
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• 제7권2호
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• pp.106-114
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• 1963

The products from polymer pyrolysis at $450^{\circ}$ are cooled with ice, then liquid and gaseous portions are analysed by gas chromatography. Di-2-ethyl hexyl sebacate column, silicone oil column, silica gel column and tetraethyleneglycol dimethylether column, which was most effective for the separation of hydrocarbon gases, are used. Identification of isomers could be secured more effectively by gas chromatography than mass spectrometry. Elucidation of the mechanism for thermal decomposition of polymers could be done through the identification of pyrolysis products. Although more extensive work is needed, some patterns of polymer pyrolysis are discussed.

• 대한화학회지
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• 제7권2호
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• pp.122-127
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• 1963

Pyrolysis fo polyethylene and polypropylene has been studied in order to clarify the mechanism of chain scission and effect of oxygen on degradation. Rate of weight decrease was measured under nitrogen and air atmosphere at constant temperature for the samples of high density polyethylene, low density polyethylene and isotactic polypropylene, and then gaseous hydrocarbons produced from pyrolysis were analysed by gas chromatography. Although there is little substantial difference between composition of hydrocarbon gases from pyrolysis of high density polyethylene and low density polyethylene except some difference in quantity of total gas produced, gas composition from polypropylene pyrolysis differs from that of polyethylene pyrolysis. Gases from pyrolysis under air contain much more unsaturated hydrocarbons than those from pyrolysis under inert gas.

• 대한화학회지
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• 제7권2호
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• pp.115-121
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• 1963

Aliphatic hydrocarbon gases from rubber pyrolysis have been identified by gas chromatography with tetraethyleneglycol dimethylether column. Rubbers used in this work are polyisoprene, SBR, NBR, polybutadiene, buthyl rubber, polychloroprene and polyurethane rubber. The chromatogram is characteristic for each polymer. Author proposes a method of identification of synthetic rubbers by gas chromatograph of pyrolyzed gas. Sample is pyrolyzed at $450^{\circ}C$ under nitrogen or more effectively helium and gaseous portion, which eliminated liquid condensate, is passed to the column. The appearance of exclusively large peak of isoprene, isobutylene and carbon dioxide shows the presence of polyisoprene, polyisobutylene and polyurethane, respectively. Large peak of butadiene will appear in case of polybutadiene, SBR and NBR, but SBR can be identified through the styrene peak in gas chromatogram of liquid pyrolyzate and NBR can be identified by the evolution of hydrogen cyanide during pyrolysis. Polychloroprene is identified by the evolution of hydrogen chloride. This method could be applied to the identification of copolymer or polymer blend.

• Nuclear Engineering and Technology
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• 제46권6호
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• pp.875-882
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• 2014

In terms of safety and the efficient management of spent fuel storage, detecting failed fuel is one of the most important tasks in a CANada Deuterium Uranium (CANDU) reactor operation. It has been successfully demonstrated that in a CANDU reactor, on-power failed fuel detection and location systems, along with alarm area gamma monitors, can detect and locate defective and suspect fuel bundles before discharging them from the reactor to the spent fuel storage bay. In the reception bay, however, only visual inspection has been used to identify suspect bundles. Gaseous fission product and delayed neutron monitoring systems cannot precisely distinguish failed fuel elements from each fuel bundle. This study reports the use of a sipping system in a CANDU reactor for the integrity assessment of spent fuel bundles. The integrity assessment of spent fuel bundles using this sipping system has shown promise as a nondestructive test for detecting a defective fuel bundle in a CANDU reactor.

• 상하수도학회지
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• 제24권5호
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• pp.561-572
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• 2010

The efficiency of biological hydrolysis at $80^{\circ}C$ on municipal solid waste mixed with anaerobic digestion sludge was investigated in 100L batch reactors. The hydrolysis effect was observed within a day, when the hydrolysis reactor used for a pre-treatment reactor for methanogenesis, and the effect was observed during two days, When the reactor used for post-treatment reactor. For both configurations, methane production rate decreased, when hydrolysis was carried out more than a day. Gaseous ammonia in the hydrolysis reactors was successtully removed by the ammonia stripping system. Microbial diversity analysis on the hydrolysis reactors indicated dependency of microbial diversity on the configuration of the hydrolysis reactors. Carbohydrate and lactate degrading microbes dominated in the hydrolysis reactor, when the hydrolysis reactor used for a pre-treatment reactor for methanogenesis, while protein degrading microbes dominated in the post-treatment reactor.

• 대한기계학회논문집
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• 제17권12호
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• pp.3187-3195
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• 1993

Combustion of liquid-fuelled combustion in a high-temperature vitiated-air stream was studied. The mathematical formulation comprise the application of Eulerian conservation equation to the gas phase and Lagrangian equation of droplet motion. The latter is coupled with a droplet-tracking technique (PSI-CELL Model) which regard the droplet phase as a source of mass, momentum, and energy to the gaseous phase. Reaction rate is determined by taking into account the Arrhenius reaction rate based on a single-step reaction mechanism. The calculated profiles show somewhat uncertainess at the upstream, but bases data for designing the combustor followed by 2-phase flow were obtained.

• 한국막학회:학술대회논문집
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• 한국막학회 1995년도 춘계 총회 및 학술발표회
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• pp.45-45
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• 1995

Filtration, one of the most important process in the various industrials, is defined as the separation of two or more compounds from a fluid by passing the mixture refers to the separation of solid, immisible particles from liquid or gaseous mixture. Membrane filtration which is a type of filtration extends it's application further to include the separation, concentration, and filtration. The main objective of this investigation is the preparation of organic solvents-resistant polyimide membranes by using phase inversion technique and their application as a UF membrane. Specially, the dope solution was prepared from the newly developed method. The newly developed method is that the dope solution was directly prepared from the polyimide solution which was prepared by the modified one-step polymerization. The effects of the parameters for membrane preparation such as the casting solution composition and the casting conditions were investigated and the performance and chemical stabfiity of membrane are going to be tested.

• 한국표면공학회지
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• 제29권1호
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• pp.45-59
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• 1996

Ultrafine powders(UFPs) of aluminum nitride(AlN) have been synthesized by chemical reactions in the nitrogen atmosphere and the gaseous aluminum evaporated from Al powders in thermal plasmas produced by a DC plasma torch. A synthesis system consisting of a plasma torch, a finely-controllable powder feeder, a reaction chamber, and a quenching-collection chamber have been designed and manufactured, and a filter for gathering AlN UFPs produced by the quenching process subsequent to the synthesis is set up. The synthesis process is interpreted by numerical analyses of the plasma-particle interaction and the chemical equilibrium state, respectively, and a fully-saturated fractional factorial test is used to find the optimum process conditions. The degrees and ultrafineness of synthesis are evaluated by means of SEM, TEM, XRD, and ESCA analyses. AlN UFPs synthesized in the optimum process conditions have polygonal shapes of the size of 5-100 nm, and their purities differ depending on collecting positions and filter types, and the maximum purity obtained is 72 wt% at the filter.

• Journal of Korean Society for Atmospheric Environment
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• 제17권E3호
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• pp.117-124
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• 2001

The present paper examined the kinetics of photocatalytic degradation of volatile organic compounds (VOCs) including gaseous trichloroethylene (TCE) and acetone. In this study, we examined the effects of the initial concentration of VOCs and the light intensity of ultra-violet (UV). A batch photo-reactor was specifically designed for this work. The photocatalytic degradation rate increased with the initial concentration of VOCs but remained almost constant beyond a certain concentration. It matched well with the Langmuir-Hinshelwood (L-H) kinetic model. When the effect of light intensity was concerned, it was found that photocatalytic degradation occurs in two regimes with respect to light intensity.

• 한국대기환경학회지
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• 제19권3호
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• pp.325-331
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• 2003

A biofilter study was conducted by changing inlet concentration and residence time for the removal of gaseous benzene and ethylene. In addition, carbon dioxide produced from the biofilters was investigated. Over 96% of benzene was removed at the residence times of 2 and 4.3 min, and inlet benzene concentrations of 220∼300 ppm. The ethylene biofilter was capable of achieving ethylene removal efficiency as much as 100％ at a residence time of 14 min, and inlet concentrations of 99∼290 ppm. At a steady state, the carbon dioxide of 409∼611 ppm was produced with an ethylene inlet concentration of 290 ppm. Most of benzene and ethylene were degraded at lower part of the biofilters where more microbial activity occurred.