• Title/Summary/Keyword: Gaseous

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$CO_2$ removal system by dry sorbent for passenger train (건식 흡착제를 이용한 차량용 이산화탄소 저감장치 개발)

  • Cho, Yong-Dae;Lee, Ju-Yeol;Park, Duck-Shin
    • Proceedings of the KSR Conference
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    • 2008.06a
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    • pp.1735-1739
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    • 2008
  • Malfunction or inappropriate management of ventilation system in public transportation may cause unpleasant atmosphere or health problems to the old or feeble passengers. In this work, gaseous carbon dioxide removal system is developed and tested under the various serviced passenger cabins. Finally an optimum operating conditions for the $CO_2$ removal system will presented.

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Does the Gaseous Aniline Cation Isomerize to Methylpyridine Cations Before Dissociation?

  • Choe, Joong Chul
    • Bulletin of the Korean Chemical Society
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    • v.34 no.11
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    • pp.3249-3252
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    • 2013
  • We have explored the potential energy surface for the isomerization of the aniline (AN) radical cation to the 2-, 3-, and 4-methylpyridine (picoline, MP) radical cations using G3 model calculations. The isomerization may occur through the 1H-azepine (7-aza-cycloheptatriene) radical cation. A quantitative kinetic analysis has been performed using the Rice-Ramsperger-Kassel-Marcus theory, based on the potential energy surface. The result shows that isomerization between $AN^{+\bullet}$ and each $MP^{+\bullet}$ hardly occurs before their dissociations.

Design and Combustion Tests of 1[N] Micro-Thruster with $H_2/O_2$ Propellants

  • Fujii, Masaya;Seki, Lssei;Yuasa, Saburo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.628-633
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    • 2004
  • 초소형위성은 개발기간의 단축에 따른 발사 비용의 저감과 업무와 기능의 분산화에 따른 발사 실패의 리스크 저감 등 여러 장점이 있기 때문에 그 필요성이 높아지고 있다.(중략)

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A method for properties evaluation of activated charcoal sorbents in iodine capture under dynamic conditions

  • Magomedbekov, Eldar P.;Obruchikov, Alexander V.
    • Nuclear Engineering and Technology
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    • v.51 no.2
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    • pp.641-645
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    • 2019
  • Experimental equipment for studying the sorption properties of iodine sorbents using radioactive methyliodide has been developed. The sorption capacity index ${\alpha}$ is proposed as a criterion parameter for assessing the quality of impregnated activated charcoals. It was found that this parameter does not depend on the dynamic conditions during the sorbent test. It was shown that values of the sorption capacity index allow to recommend iodine sorbents for industrial gas cleaning processes.

A Study on the Decomposition Characteristics of PVC and PS Mixtures with ZnO in Air Atmosphere (공기분위기에서 ZnO를 첨가한 PVC와 PS 혼합물의 분해특성에 관한 연구)

  • Oh, Sea Cheon;Jung, Myung Uk;Jun, Hyun-Chul;Kim, Hee Taik;Lee, Hae Pyeong
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.229-234
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    • 2006
  • The effect of ZnO in the decomposition of poly(vinyl chloride) (PVC) and polystyrene (PS) mixtures in air atmosphere has been studied by thermogravimetry (TG) and gas chromatograph-mass spectrometry (GC-MS) under various mixing ratios and reaction temperatures. From this work, it can be seen that the yields of a liquid product were increased with the increase of PS in mixtures, whereas those of gaseous products were decreased. And the yields of a gaseous product and HCl were decreased with the increase of ZnO in mixtures. It was also found that HCl was rarely produced at ZnO/Mixture = 0.5 by the effect of ZnO in dehydrochlorination of PVC.

Air Cleaning Unit using Combination of $TiO_2$ Photocatalyst and Pulsed Discharge Plasma (산화티타늄 광촉매와 펄스 방전 플라즈마 조합에 의한 공기정화장치)

  • Hong, Yeong-Gi;Sin, Su-Yeon;Gang, Jeong-Hun;Lee, Seong-Hwa;Jo, Jeong-Su;Park, Jeong-Hu
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.10
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    • pp.710-715
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    • 1999
  • The purpose of this work is to develop a high-efficiency air cleaning system for air pollutants such as particulate and gaseous state in indoor environments. In order to enhance a removal efficiency of gaseous state pollutants, we suggested that pulsed discharge plasma be combined with $TiO_2$ photocatalyst (photocatalytic plasma air cleaning unit). We investigated experimentally the basic characteristics of photocatalytic plasma air cleaning unit and measured air pollutants removal efficiency. The wavelength of light radiated from pulsed discharge plasma under the atmospheric condition was 310~380nm. Its energy is enough to excite the $TiO_2$ photocatalyst and it makes a photochemical reaction in the surface of $TiO_2$ photocatalyst. The removal quantity of trimethylamine$((CH_3)_3N)\; was\; 130mg/m^34 which is twice quantity of pulsed discharge plasma without $TiO_2$ phtocatalyst unit. From the result of gas analysis using FT-IR, nitric oxide was not detected and trimethylamine was decomposed to $H_2O\; and \;CO_2$. And trimethylamine removal efficiency was 95%. These experimental results indicate that photocatalytic plasma air cleaning unit is a potential method in removing the pollutants.

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Study on the Regional Deposition of Smoke Particles in Human Respiratory Tract under the Variation of Fire and Breathing Conditions (화재 및 호흡조건 변화에 따른 연기입자의 인체 호흡기 내 영역별 침착량 분석)

  • Goo, Jaehark
    • Fire Science and Engineering
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    • v.33 no.6
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    • pp.95-104
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    • 2019
  • Smoke generated in a fire consists of gaseous substances and particulate matter, such as unburned carbon that adsorbed the gases. Human injury caused by inhalation of gaseous substances present in smoke is mostly short-term, whereas damage caused by inhalation of particulate matter is relatively a long-term phenomenon depending on the state of the gas-phase adsorption. The amount and location of the deposited smoke particles are important factors in estimating the damage caused to humans, which are affected by the breathing conditions as well as particle conditions, such as the size and concentration affected by the combustion conditions. In this study, in order to understand the characteristics of the deposition of smoke particles in the respiratory tract related to the study of human smoke inhalation injury, the number and mass concentration of smoke particles deposited in different areas of the respiratory tract for different fuel types, combustion conditions and breathing conditions were calculated. In addition, the amount of mass deposition of smoke in the respiratory tract for a certain period of inhalation was compared with the atmospheric standard of fine dust.

Measurement of Dry deposition at Seoul, Chunchon and Anmyon-do by Using Filter pack Method (필터팩을 이용한 서울과 춘천, 안면도의 건성 강하량 측정)

  • Kim, Man-Goo;Kang, Mi-Hee;Hong, Young-Min;Park, Ki-Jun;Lee, Bo-Kyung;Lee, Dong-Soo;Kim, San
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.1
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    • pp.19-29
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    • 2001
  • Atmospheric concentrations of acidic pollutant were measured by the 4 stage filter pak method at Chunchon and by the 3 stage filter pack method at Seoul and Anmyon-do from January to December 1998. The sample was collected for 24 hours on every Wednesday. Concentrations of particulate matters were highest at Anmyon-do. The particulate concentration was much higher during the warm season than other seasons. While the particulate concentration was higher during the warm season, the concentration of gaseous matter was higher in winter. Dry deposition flux was calculated by using reported deposition velocities and concentration of pollutants measured in this study. The dry deposition velocities used in this study for SO$_2$, SO$_{4}^{2}$, HNO$_3$,NO$_{3}^{-}$ and NH$_3$ were 0.29, 0.15, 2.08( 2.13 only for Anmyon-do), 0.20 and 1.00cm/sec, respectively. At Chunchon, annual sulfur flux originated from dry deposition was 384 kg/$textrm{km}^2$, and the flux from wet deposition was 782kg/$textrm{km}^2$. Dry deposition of sulfur was 33% of total sulfur deposition. The annual nitrogen flux originated from dry deposition was 1,892kg/$textrm{km}^2$. And the flux from wet deposition was 1,066kg/$textrm{km}^2$. Dry deposition of nitrogen was 64% of total nitrogen deposition. Dry deposition as well as wet deposition have to be considerd in the study on acidification of environment such as soil or watershed.

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Biofiltration of Gaseous Toluene Using Activated Carbon Containing Polyurethane Foam Media (활성탄 함유 폴리우레탄 담체를 사용하는 바이오필터에 의한 가스상 톨루엔의 처리)

  • Amarsanaa Altangerel;Shin Won-Sik;Choi Jeong-Hak;Choi Sang-June
    • Journal of Environmental Science International
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    • v.15 no.6
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    • pp.513-525
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    • 2006
  • In recent decades, biofiltration has been widely accepted for the treatment of contaminated air stream containing low concentration of odorous compounds or volatile organic compounds (VOCs). In this study, conventional biofilters packed with flexible synthetic polyurethane (PU) foam carriers were operated to remove toluene from a contaminated air stream. PU foams containing various amounts of pulverized activated carbon (PAC) were synthesized for the biofilter media and tested for toluene removal. Four biofilter columns were operated for 60 days to remove gaseous toluene from a contaminated air stream. During the biofiltration experiment, inlet toluene concentration was in the range of 0-150 ppm and EBRT (i.e., empty bed residence time) was kept at 26-42 seconds. Pressure drop of the biofilter bed was less than 3 mm $H_2O/m$ filter bed. The maximum removal capacity of toluene in the biofilters packed with PU-PAC foam was in the order of column II (PAC=7.08%) > column III (PAC=8.97%) > column I (PAC=4.95%) > column IV (PAC=13.52%), while the complete removal capacity was in the order of column II > column I > column III > column IV. The better biofiltration performance in column II was attributed to higher porosity providing favorable conditions for microbial growth. The results of biodegradation kinetic analysis showed that PU-PAC foam with 7.08% of PAC content had higher maximum removal rate ($V_m$=14.99 g toluene/kg dry material/day) than the other PU-PAC foams. In overall, the performance of biofiltration might be affected by the structure and physicochemical properties of PU foam induced by PAC content.