• Title/Summary/Keyword: Gaseous

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Expert System Approach for Vapor-Phase Infrared Spectra of Aromatic Compounds

  • Pyo Dongjin;Hwang Hoon;Lee Junyeoun
    • Bulletin of the Korean Chemical Society
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    • v.13 no.2
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    • pp.148-155
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    • 1992
  • Computerized interpretation of vapor phase infrared spectra using a novel expert system approach for spectra/structure correlation for vapor phase spectra is introduced. Rapid identification of aromatic functional groups of components in gaseous mixture can be achieved using this expert system.

Influence of Various Soil CharacteriBtics in GinBeng Field or the Growth and the Yield of Ginseng (Panax gisoseng C. A. Meyer) (인삼전지의 토양특성이 인삼의 생육및 수량에 미치는 영향에 관한 연구)

  • 이일호;육창수;한강완;박찬수;박현석;남기열
    • Journal of Ginseng Research
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    • v.4 no.2
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    • pp.175-185
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    • 1980
  • A study was made to clarify the topographical. and Physical characteristics of ginseng field in terms of soil science and to find the relationship between soil characteristics and ginseng growth, as well as yield of ginseng roots Forty nine farmer's red ginseng field of ginseng growing area were chosen for this study and investigated for two years. The results obtained were as follow. 1. Ginseng fie1ds with high yield which represent the more than 1.8kg of ginseng root per 3.2m2 were found in soil series of Bancheon, Yeongog, Weongog, etc. whose texture were the clay loam to clay soil. On the other hand, ginseng field with low yield were observed in soil series of seogto whose texture was loamy soil with high content of gravels. 2 Soil of ginseng field with high yield had higher content of clay. silt soil moisture and soil pore as compared with soils of low yields. These soil characteristics were positively correlated with stem length stem diameter and root weight of ginseng plsnt and negatively correlated with rate of missing plant 3. The adequate ranges of soil 3 phase from high yield ginseng field were 40 to 50% of solid Phase, 22 to 35% of liquid phase, 25 to 35% of gaseous phase in top soil and 45 to 55% of solid phase. 28 to 30% of liquid phase. 15 to 20% of gaseous phase in subsoil respectively.

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Kinetic Study on the Mixing Region of a Hydrocarbon Reformer (개질기 혼합영역에서 탄화수소 연료의 반응 특성에 대한 연구)

  • Kim, Sun-Young;Bae, Joong-Myeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.357-362
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    • 2011
  • Complete mixture preparation of reactants prior to catalytic reforming is an enormously important step for successful operation of a fuel reformer. Incomplete mixing between fuel and reforming agents such as air and steam can cause temperature overshoot and deposit formation which can lead the failure of operation. For that purpose it is required to apply computational models describing coupled kinetics and transport phenomena in the mixing region, which are computationally expensive. Therefore, it is advantageous to analyze the gas-phase reaction kinetics prior to application of the coupled model. This study suggests one of the important design constraints, the required residence time in the mixing chamber to avoid substantial gas-phase reactions which can lead serious deposit formation on the downstream catalyst. The reactivity of various gaseous and liquid fuels were compared, then liquid fuels are far more reactive than gaseous fuels. n-Octane was used as a surrogate among the various hydrocarbons, which is one of the traditional liquid fuel surrogates. The conversion was slighted effected by reactants composition described by O/C and S/C. Finally, threshold residence times in the mixing region of a hydrocarbon reformer were studied and the mixing chamber is required to be designed to make complete mixture of reactants by tens of milliseconds at the temperature lower than $400^{\circ}C$.

Simultaneous Removal Characteristics of Particulate and Elemental Mercury in Convergence Particulate Collector (융합형여과집진장치에서의 먼지입자와 원소수은의 제거 성능 특성)

  • Park, Young Ok;Jeong, Ju Yeong
    • Particle and aerosol research
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    • v.6 no.4
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    • pp.173-183
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    • 2010
  • The high temperature pleated filter bags which were used during this study were made of pleated nonwoven fabric of heat and acid resistant polysulfonate fibers which can withstand the heat up to $300^{\circ}C$ and have a filtration area which is 3 to 5 times larger than the conventional round filter bags. Cartridge module packed with 3 kind of the sulfur impregnated activated-carbon based sorbents were inserted in the inner of the pleated filter bag. This type of pleated filter bag was designed to remove not only the particulate matter but also the gaseous elemental mercury. The electrostatic precipitator part can enhance the particulate removal efficiency and reduce the pressure drop of the pleated filter bag by agglomerated particles to form a more porous dust layer on the surface of the pleated bag which is increased the filter bag cleaning efficiency. In addition, the most of particles are separated from the flue gas stream through the cyclone and the electrostatic precipitator part which were installed at the lower part and main body part of the convergence particulate collector, respectively. Thus reduce particulate loading of the high temperature pleated filter bags were applied in this study to analyze the removal characteristics of particulate matter and gaseous elemental mercury.

Evaluating Effective Volume and Hydrodynamic Behavior in a Full-Scale Ozone Contactor with CFD Simulation (전산유체역학을 이용한 실규모 오존 접촉에서의 수리거동과 유효 체적 평가에 관한 연구)

  • Park, No-Suk;Mizuno, Tadao;Tsuno, Hiroshi;Bea, Chul-Ho;Lee, Seon-Ju
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.5
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    • pp.656-665
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    • 2004
  • An Ozone reaction model combined with CFD(Computational Fluid Dynamics) technique was developed in this research, in the simulation of ozonation, hydrodynamic behavior as well as reaction model is important because ozone is supplied to treated water as gas ozone. In order to evaluate hydrodynamic behavior in an ozone contactor, CFD technique was applied. CFD technique elucidated hydrodynamic behavior in the selected ozone contactor, which consisted of three main chambers. Three back-mixing zones were found in the contactor. The higher velocities of water were observed in the second and third compartments than that in the first compartment. The flow of the opposite direction to the main flow was observed near the water surface. Based on the results of CFD simulation, the ozone contactor was divided into small compartments. Mass balance equations were established were established in each compartment with reaction terms. This reaction model was intended to predict dissolved ozone concentration, especially. We concluded that the model could predict favorably the mass balance of ozone, namely absorption efficiency of gaseous ozone, dissolved ozone concentration and ozone consumption. After establishing the model, we discussed the effect of concentration of gaseous ozone at inlet, temperature and organic compounds on dissolved ozone concentration.

A Review on the Characteristics of Air Pollutants Emitted from Passenger Cars in Korea

  • Jung, Sungwoon;Kim, Jeongsoo
    • Journal of ILASS-Korea
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    • v.21 no.4
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    • pp.223-236
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    • 2016
  • On-road source emissions are major air pollutants and have been associated with serious health effects in Seoul metropolis. Thus, it is of fundamental importance to have an accurate assessment of vehicle emissions in order to implement an effective air quality management policy. As a result, there is a need to overview vehicle emission characteristics of air pollutants. This article discusses vehicle exhaust sampling and chemical analysis, emission characteristics of air pollutants, and emission regulations from passenger cars. The vehicle exhaust sampling and chemical analysis methods were described in particulate matter and gaseous compounds. In this article, chassis dynamometer, measurement instrumentation for nano-particulate matter and carbon compounds analysis device were described. For the gasoline and diesel vehicles, the effective parameters of emissions were average vehicle speed, vehicle mileage and model year. The particle number emissions for diesel nano-particles were sensitive to the sampling conditions. Also, the particle number emissions with a diesel particle filter (DPF) largely reduced rather than those without it. This article also describes different emission characteristics of air pollutants according to biodiesel or bioethanol mixing ratio. The Korean emission standards for passenger cars were compared with those of the US and EU. Finally, the objective is to give an overview of relevant background information on emission characteristics of air pollutants from passenger cars in Korea.

Numerical Analysis of Recess Effects on Gaseous Hydrogen/Liquid Oxygen Coaxial Injector (수소-산소 동축 분사기에 대한 리세스 효과 수치해석)

  • Lee, Kibum;Park, Tae Seon
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.3
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    • pp.17-24
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    • 2016
  • The reacting flows of gaseous hydrogen/liquid oxygen 2D coaxial shear injector with varying recess length are numerically analyzed. The standard ${\kappa}-e$ model and laminar flamelet model are adopted for the steady turbulent combustion with the ideal and real gas equations. As the recess length increases, the recirculating region in the combustion chamber expands and the vorticity is intensified. Also, the variations of temperature, products, and pressure are strongly related to the recess length. The results show that an efficient combustor can be obtained by the introduction of the recessed injector.

Synthesis of Isopropyldichlorosilane by Direct Process

  • Lim, Weon-Cheol;Cho, Joo-Hyun;Han, Joon-Soo;Yoo, Bok-Ryul
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1661-1664
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    • 2007
  • Direct reaction of elemental silicon with a gaseous mixture of isopropyl chloride (1) and hydrogen chloride in the presence of copper catalyst using a stirred bed reactor equipped with a spiral band agitator gave isopropyldichlorosilane having a Si-H bond (2a) as a major product and isopropyltrichlorosilane (2b) along with chlorosilanes, trichlorosilane and tetrachlorosilane. A process for production of 2a was maximized using the 1:0.5 mole ratio of 1 to HCl and smaller size of elemental silicon at a reaction temperature of 220 °C. When a reaction was carried out by feeding a gaseous mixture of 1 [12.9 g/h (0.164 mol/h)] and HCl [2.98 g/h (0.082 mol/h)] to a contact mixture of elemental silicon (360 g) and copper (40 g) under the optimum condition for 45 h, 2a among volatile products kept up about 82 mol % until 35 h and then slowly decreased down 68 mol % in 45 h reaction. Finally 2a was obtained in 38% isolated yield (based on 1 used) with an 85% consumption of elemental silicon in a 45 h reaction. In addition to 2a, 2b was obtained as minor product along with chlorosilanes, trichlorosilane, and tetrachlorosilane. The decomposition of 1 was suppressed and the production of 2a improved by adding HCl to 1.