• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.17 no.1
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• pp.107-120
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• 2019

The decommissioning of one nuclear power plant in a multi-unit nuclear power plant (multi-unit NPP) site may pose radiation exposure risk to decommissioning workers. Thus, it is essentially required to evaluate the exposure dose of decommissioning workers of operating multi-unit NPPs nearby. The ENDOS program is a dose evaluation code developed by the Korea Atomic Energy Research Institute (KAERI). As two sub-programs of ENDOS, ENDOS-ATM to anticipate atmospheric transport and ENDOS-G to calculate exposure dose by gaseous radioactive effluents are used in this study. As a result, the annual maximum individual dose for decommissioning workers is estimated to be $2.31{\times}10^{-3}mSv{\cdot}y^{-1}$, which is insignificant compared with the effective dose limit of $1mSv{\cdot}y^{-1}$ for the public. Although it is revealed that the exposure dose of operating multi-unit NPPs does not result in a significant impact on decommissioning workers, closer examination of the effect of additional exposure due to actual demolition work is required. The calculation method of this study is expected to be utilized in the future for planned decommissioning projects in Korea. Because domestic NPPs are located in multi-unit sites, similar situations may occur.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.29 no.2
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• pp.45-49
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• 2019

Relatively fine silicon carbide (SiC) crystalline aggregates have been synthesized with the carbonized rice husks, paper sludge, coffee grounds as the carbon sources and the silica powder. The main reaction source to obtain silicon carbide (SiC) aggregates from the mixture of carbon sources and silica was inferred as the gaseous silicon monoxide (SiO) phase, being created from this mixture through the carbothermal reduction reaction. The silicon carbide (SiC) crystalline aggregates, fabricated from the carbonized rice husks and paper sludge, coffee grounds and silica ($SiO_2$) powder, were investigated by XRD patterns, FE-SEM and FE-TEM images. In these specimens, obtained from the carbonized rice husks, paper sludge and silica, XRD patterns showed rather high strong peak of (111) plane near $35^{\circ}$. The FE-TEM images and patterns of specimens, synthesized from carbonized rice husks, paper sludge, coffee grounds and silica under Ar atmosphere, showed relatively fine particles under $1{\mu}m$ and crystalline peak (110) of silicon carbide (SiC) diffraction pattern.

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.200-208
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• 2021

Compare to the gaseous hydrogen, liquid hydrogen has various advantages: easy to transport, high energy density, and low risk of explosion. However, the hydrogen liquefaction process is highly energy intensive because it requires lots of energy for refrigeration. On the other hand, the cold energy of the liquefied natural gas (LNG) is wasted during the regasification. It means there are opportunities to improve the energy efficiency of the hydrogen liquefaction process by recovering wasted LNG cold energy. In addition, hydrogen production by natural gas reforming is one of the most economical ways, thus LNG can be used as a raw material for hydrogen production. In this study, a novel hydrogen production and liquefaction process is proposed by using LNG as a raw material as well as a cold source. To develop this process, the hydrogen liquefaction process using hydrocarbon mixed refrigerant and the helium-neon refrigerant is selected as a base case design. The proposed design is developed by applying LNG as a cold source for the hydrogen precooling. The performance of the proposed process is analyzed in terms of energy consumption and exergy efficiency, and it is compared with the base case design. As the result, the proposed design shows 17.9% of energy reduction and 11.2% of exergy efficiency improvement compare to the base case design.

• Journal of Environmental Health Sciences
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• v.47 no.3
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• pp.259-266
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• 2021

Objectives: This study was conducted to identify the emissions characteristics of total particulate matter (TPM), fine dust (PM₁₀, PM_2.5), and gaseous pollutants (SOx, NOx) in iron and steel manufacturing facilities in order to investigate emissions factors suitable for domestic conditions. Methods: Total particulate matter (TPM), fine dust (PM₁₀, PM_2.5), and gas phase materials were investigated at the outlet of electric arc furnace facilities using a cyclone sampling machine and a gas analyzer. Results: The concentrations of TPM ranged from 1.64 to 3.14 mg/Sm³ and the average was 2.47 mg/Sm³. Particulate matter 10 (PM₁₀) averaged 1.49 mg/Sm³ with a range of 0.92 to 1.99 mg/Sm³, and the resulting ratio of PM₁₀ to TPM was around 60 percent. PM_2.5/PM₁₀ ranged from 33.7 to 47.9% and averaged 41.6%. Sulfur oxides (SOx) were not detected, and nitrogen oxides (NOx) averaged 6.8 ppm in the range of 5.50 to 8.67 ppm. TPM emission coefficients per product output were in the range of 0.60 to 1.26 g/kg, 0.13 to 0.79 g/kg for PM₁₀ and 0.12 to 0.36 g/kg for PM_2.5, and showed many differences from the emissions coefficients previously announced. An emissions coefficient for NOx is not currently included in the domestic notices, but the results were calculated to be 0.42 g/kg per product output. Conclusions: Investigation and research on emissions coefficients that can reflect the characteristics of various facilities in Korea should be conducted continuously, and the determination and application of unique emissions coefficients that are more suitable for domestic conditions are needed.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.519-524
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• 2022

Domestic building finishing materials are being evaluated according to KS F 2271 standards according to the notification of the Ministry of Land, Infrastructure and Transport, and this test is evaluated using laboratory animals. In this study, experiments were conducted on highly combustible organic insulation materials such as EPS, urethane, and phenolic foam. The purpose of this study was to analyze the cause of the behavioral suspension of the experimental mice by measuring the average behavioral suspension time of the mice caused by the harmful gas generated when these three types of insulation materials were burned. FTIR analysis and smoke density experiment were performed as a cause analysis method for the behavioral suspension of mice, and the experimental results were analyzed by dividing the causes of behavioral suspension into suffocation by particulate matter and toxic inhalation by gaseous substances. As a result of the test, urethane was evaluated as the most harmful insulation material, and as a result of FTIR analysis and smoke density test as a cause analysis for the gas toxicity test results, it is judged that the behavioral stop of the rats by suffocation is higher than the effect of toxic inhalation. This study is a basic study on the cause analysis of harmful gases, and it will be necessary to prepare the toxicity basis and analyze various materials and gases.

• Journal of the Korean Society of Floral Art and Design
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• no.45
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• pp.3-12
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• 2021

The 1-methylcyclopropene (1-MCP) is the gaseous ethylene action inhibitor, which delay senescence and wilting by blocking the binding of its receptors. We investigated the effects of 1-MCP with different treated duration (0h (Control), 1h, and 4h) in cut flowers of Eustoma grandiflorum 'Voyage' and Cymbidium 'Lapine Hat'. The relative water uptake increased by 14.5% than control (9.8%) and the flower diameter maintained high from 3 to 11 days in 1-MCP treatment for 4h in E. grandiflorum 'Voyage'. The relative fresh weight was averagely high in 1-MCP treatment for 4h, however, the vase life was not significantly different in both cut flowers. Since the effects of 1-MCP treatment was differently responded by plant species and cultivars, interacted studies of duration and levels of 1-MCP are needed for the pronounced effects of postharvest quality.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.32 no.1
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• pp.78-88
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• 2022

Objectives: To develop the smart sensor to protect worker's health from chemical exposure by adopting ICT (Information and Communications Technology) technologies. Methods: To develope real-time chemical exposure monitoring system, IoT (Internet of Things) sensor technology and regulations were reviewed. We developed and produced smart sensor. A smart sensor is a system consisting of a sensor unit, a communication unit, and a platform. To verify the performance of smart sensors, each sensor has been certified by the Korea Laboratory Accreditation Scheme (KOLAS). Results: Chemicals (TVOC; Total Volatile Organic Compounds, Cl₂: Chlorine, HF: Hydrogen fluoride and HCN: Hydrogen cyanide) were selected according to a priority logic (KOSHA Alert, acute poisoning statistics, literature review). Notifications were set according to OEL (occupational exposure limit). Sensors were selected based on OEL and the capabilities of the sensors. Communication is designed to use LTE (Long Term Evolution) and Wi-Fi at the same time for convenience. Electronic platform were applied to build this monitoring system. Conclusions: Real-time monitoring system for OEL of hazardous chemicals in workplace was developed. Smart sensor can detect chemicals to complement monitoring of traditional workplace environmental monitoring such as short term and peak exposure. Further research is needed to expand the scope of application, improve reliability, and systematically application.

• Analytical Science and Technology
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• v.19 no.5
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• pp.369-375
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• 2006

Calibration gas mixtures were prepared using dynamic volumetric method according to ISO 6145-5 and the uncertainty was evaluated. Ten identical capillaries with 0.25 mm in inner diameter and 50 cm in length were applied in this system. Dilution ratio of parent gas was determined by the number of capillaries that passes parent gas and that passes balance gas through. Capillaries were made of Teflon which had good chemical stability against adsorption of gaseous substances. Mechanical valves were introduced in this system in order to minimize the thermal effect of solenoid valves. Concentration of prepared gases were compared with master grade standard gases in cylinders made by RiGAS Co. and calibration of the instrument were completed using comparison method according to ISO 6143. Experimental results showed that the coefficient of variance of diluted oxygen standard gases showed less then 0.2% in most dilution range, that of diluted hydrogen sulfide standard gases showed less then 1.0%. Therefore, it is proven that the standard gases prepared by this system are appropriate to be used as a calibration standards in ambient monitoring, etc.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.6B
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• pp.689-694
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• 2006

The system performance of a bioactive foam reactor (BFR), that consists of a foam column using a surfactant and a biodegradation basin containing suspended bacteria, was investigated for the treatment of gaseous toluene or a mixture of four volatile organic compounds (VOCs, benzene, toluene, p-xylene, and styrene). Overall, the BFR achieved stable VOC removal efficiencies, indicating that it can be used as a potential alternative over conventional packed-bed biofilters. Furthermore, a dynamic loading test showed that relatively constant removal was maintained at the elevated loading due to a high mass transfer rate in the foam column. However, as the inlet concentration of VOCs increased, a portion of the VOCs mass-transferred to the liquid phase was stripped out from the biodegradation basin, resulting in a decrease in the overall removal efficiency. In the BFR, the removal efficiency of the individual VOC was mainly determined depending on the biodegradation rate (styrene > toluene > benzene > p-xylene), rather than the mass transfer rate. Consequently, increases in the microbial activity and the volume of the basin could improve the overall performance of the BFR system. Further investigation on microbial activity and community dynamics is required for the BFR when subjected to high loadings of VOC mixtures.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.123-133
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• 2023

Commercial hydrogen fuel cell vehicles are charged by compressing gaseous hydrogen to high pressure and storing it in a storage tank in the vehicle. This process causes the temperature of the gas to rise, to ensure the safety to storage tanks, the temperature is limited. Therefore, a heat transfer model is needed to explain this temperature rise. The heat transfer model includes the convective heat transfer phenomenon, and accurate estimation is required. In this study, the convective heat transfer coefficient in the hydrogen fueling process was calculated and compared using various correlation equations considering physical phenomena. The hydrogen fueling process was classified into the fueling line from the dispenser to the tank inlet and the storage tank in the vehicle, and the convective heat transfer coefficients were estimated according to process parameters such as mass flow rate, diameter, temperature and pressure. As a result, in the case of the inside of the filling line, the convective heat transfer coefficient was about 1000 times larger than that of the inside of the storage tank, and in the case of the outside of the filling line, the convective heat transfer coefficient was about 3 times larger than that of the outside of the storage tank. Finally, as a result of a comprehensive analysis of convective heat transfer coefficients in each process, it was found that outside the storage tank was lowest in the entire hydrogen fueling process, thus dominated the heat transfer phenomenon.