• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.43 no.3
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• pp.113-120
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• 2011

Precipitated calcium carbonate(PCC), particularly calcite crystal, is extensively used as a pigment, filler or extender in various industries such as paper, paint, textile, detergents, adhesives, rubber and plastics, food, cosmetics, and biomaterials. PCC is conventionally produced through the gas-liquid carbonation process, which consists on bubbling gaseous $CO_2$ through a concentrated calcium hydroxide slurry. This study is aimed to find some factors for controlling the morphology of engineered PCC in lab-scaled mixing batch. The experimental designs were based on temperature variables, $Ca(OH)_2$ concentration, $CO_2$ flow rate, and electrical conductivity. The model of engineered PCC morphology was finally controlled by adjustment of electrical conductivity(6.0~7.0 mS/cm) and $Ca(OH)_2$ concentration(10 g/L). Orthorhombic calcite crystals were mostly created at high concentration and electrical conductivity conditions because the increased ratio of $Ca^{2+}$ and $CO{_3}^{2-}$ ions affects the growth rate of orthorhombic faces. Excess calcium spices were contributed to the growth of faces in calcium carbonate crystal, and the non-stoichiometric reaction was occurred between $Ca^{2+}$ and $CO{_3}^{2-}$ ions during carbonation process.

• Nuclear Engineering and Technology
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• v.56 no.2
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• pp.611-623
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• 2024

The ISP-47 TOSQAN experiment was analyzed with containmentFOAM which is an open-source CFD code based on OpenFOAM. The containment phenomena taking place during the experiment are gas mixing, stratification and wall condensation in a mixture composed of steam and non-condensable gas. The k-ω SST turbulence model was adopted with buoyancy turbulence models. The wall condensation model used is based on the diffusion layer approach. We have simulated the full TOSQAN experiment which had a duration 20000 s. Sensitivity studies were conducted for the buoyancy turbulence models with SGDH and GGDH and there were not significant differences. All the main features of the experiments namely pressure history, temperature, velocity and gas species evolution were well predicted by containemntFOAM. The simulation results confirmed the formation of two large flow stream circulations and a mixing zone resulting by the combined effects of the condensation flow and natural convection flow. It was found that the natural convection in lower region of the vessel devotes to maintain two large circulations and to be varied the height of the mixing zone as result of sensitivity analysis of non-condensing wall temperature. The computational results obtained with the 2D mesh grid approach were comparable to the experimental results.

• Fire Science and Engineering
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• v.32 no.1
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• pp.7-15
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• 2018

The prediction performance of combustion models in the Fire Dynamics Simulator (FDS) were evaluated by comparing with experiment for compartment propane gas fires. The mixture fraction model in the FDS v5.5.3 and Eddy Dissipation Concept (EDC) model in the FDS v6.6.3 were adopted in the simulations. Four chemical reaction mechanisms, such as 1-step Mixing Controlled, 2-step Mixing Controlled, 3-step Mixing Controlled and 3-step Mixed (Mixing Controlled + finite chemical reactions) reactions, were implemented in the EDC model. The simulation results with each combustion model showed similar level for the temperature inside the compartment. The prediction performance of FDS with each combustion model showed significant differences for the CO concentration while no distinguished differences were identified for the $O_2$ and $CO_2$ concentrations. The EDC 3-step Mixing Controlled largely over-predicted the CO concentration obtained by experiment and the mixture fraction model under-predicted the experiment slightly. The EDC 3-step Mixed showed the best prediction performance for the CO concentration and the EDC 2-step Mixing Controlled also predicted the CO concentration reasonably. The EDC 1-step Mixing Controlled significantly under-predict the experimental CO concentration when the previously suggested CO yield was adopted. The FDS simulation with the EDC 1-step Mixing Controlled showed difficulties in predicting the $CO_2$ concentration when the CO yield was modified to predict the CO concentration reasonably.

• Journal of the Korean Institute of Gas
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• v.26 no.2
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• pp.49-55
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• 2022

According to reinforce environmental regulations, coal power plants have used selective catalytic reduction using ammonia as a reducing agent to reduce the amount of nitrogen oxide generation. The purpose of the present study was to derive a mixing device for effectively mixing dilute air and ammonia in the ammonia mixing pipe by performing computational fluid dynamic analysis. The mixing effect was compared by analysing the %RMS of ammonia concentration at the down stream cross section in the mixing pipe and the 16 outlets based on the case 1-1 shape, which is an existing mixing pipe without a mixing device. The mixing device was performed by changing the positions of a square plate on the downstream side of the ammonia supply pipe and an arc-shaped plate on the wall of the mixing pipe. In the case of the existing geometry(Case 1-1), the %RMS of ammonia concentration at the 16 outlets was 29.50%. The shape of the mixing device for Case 3-2 had a square plate on the downstream side of the ammonia supply pipe and an arc plate was installed adjacent to it. The %RMS of ammonia concentration for Case 3-2 was 2.08% at 16 outlets and it could be seen that the shape of Case 3-2 was the most effective mixing shape for ammonia mixing.

• Proceedings of the KSME Conference
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• 2005.11a
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• pp.42.2-42.2
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• 2005

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.6
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• pp.192-199
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• 2008

The key issues for the reduction technologies of the exhaust gas from diesel engine being developed are to reduce particulate matters and NOx. The SCR system is known to be one of the most efficient and stable technologies to remove NOx through the mixing of NOx and urea solution. In the present research, the effects of mixer configurations of SCR system have been investigated to enhance the SCR performance. First, a Schlieren technique is employed to visualize the mixing characteristics of urea solution and exhaust gas. The results show that a mixer is essential to obtain proper fluid mixing. In addition, numerical studies have been made to understand the mixing characteristics through the comparison of the mal-distribution index of concentration at the several locations of the diffuser. In particular, the effects of number of blade and mixer angles on mixing characteristics were studied. The results show that the blade angle has a larger effect on the mixing characteristics than the number of blades.

• Journal of the Korean Institute of Gas
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• v.21 no.4
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• pp.1-5
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• 2017

Leaking of natural gas, which is mostly methane, in a confined living space creates flammable atmosphere and gives rise to explosion accident. The minimum amount of leaked methane for explosion is highly dependent on the degree of mixing in the confined space. This paper proposes a method for estimating minimum amount of flammable gas for explosion by using Gaussian distribution explosion model(GDEM) and experimental explosion data. The explosion pressure in the confined space can be estimated by assuming the Gaussian distribution of flammable gas along the height of an enclosure and estimating the maximum amount of gas within flammable limits, combustion of the estimated gas with constant volume and adiabatic or isothermal mixing in the confined space. The predicted minimum gas amount for an explosion is tied to explosion pressure that results in a given building damage level. The result shows that very small amount of methane leaking in the confined space may results in a serious gas explosion accident. This result could be applied not only to setting the leak criteria for developing a gas safety appliance but also to accident investigating of explosion.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.287-289
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• 2012

The research and development history of the gas turbine combustor in Korea is introduced briefly. It is very important to understand the fuel spray, mixing phenomena in achieving combustion performance. In this paper, two kinds of fuel injection system such as duplex fuel injector and rotary spray system are introduced in developing gas turbine combustor in Korea. The extensive experimental research of fuel spray, ignition, performance and endurance rig test makes gas turbine combustor successfully in Korea.

• Journal of the Korean Society of Combustion
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• v.17 no.4
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• pp.60-65
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• 2012

The MILD combustion and pollutant emission characteristics were investigated computationally. The temperature of supplying air-stream and mixing rate (${\Omega}$) of exhaust gas in the air-stream were adjusted to investigate the effects of those parameters on the MILD combustion in jet flow field. The emission indices for NO (EINO) and CO (EICO) were introduced to quantify the amount of those species emitted from the combustion. The high-temperature region disappeared gradually as the mixing rate increased for fixed air-stream temperature. The EINO increased as the air-stream temperature became higher for fixed mixing rate, and the EINO decreased dramatically with increasing the mixing rate for each air-stream temperature condition. The EICO also decreased with increasing the mixing rate and it was nearly independent of air-stream temperature except for near ${\Omega}$ = 0.7. It was found that the CO supplied in the air-stream can be destroyed in the MILD combustion over the certain mixing rate.

• The Korean Journal of Ceramics
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• v.4 no.3
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• pp.235-239
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• 1998

Ultrafine $SnO_2$ powder was prepared by the diffusion mixing gas-phase reaction of $SnCl_4$(g) and water vapor. The effects of reaction variables, such as the chloride partial pressure, the reaction temperature, and the residence time is the reactor, on the powder size were examined systematically. Calculated concentration and distribution of chemical species, using the Burke-Schumann diffusion mixing model, were compared with the experimetal results. The effects of the reaction variables on the powder size were also discussed qualitatively.