• Title/Summary/Keyword: Gas-in-oil analysis

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Analysis of Volatile Flavor Components of the Essential Oil from Chrysanthemum coronarium var. spatiosum Bailey (쑥갓으로부터 추출한 정유의 휘발성 향기성분 분석)

  • Choi, Hyang-Sook
    • The Korean Journal of Food And Nutrition
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    • v.35 no.3
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    • pp.185-192
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    • 2022
  • This study investigated the volatile flavor components of the essential oil from Chrysanthemum coronarium var. spatiosumBailey. The essential oil obtained from the aerial parts of the plant by the hydrodistillation extraction method was analyzed by gas chromatography and gas chromatography-mass spectrometry. One hundred and one (99.11%) volatile flavor components were identified in the essential oil from the Chrysanthemum coronarium var. spatiosum Bailey. The major compounds were hexanedioic acid, bis(2-ethylhexyl) ester (12.45%), 6.10.14-trimethyl-2-pentadecanone (7.94%), 1-(phenylethynyl)-1-cyclohexanol (6.34%), α-farnesene (5.55%), phytol (4.99%), and α-caryophyllene (4.39%). When the volatile flavor components of Chrysanthemum coronarium var. spatiosum Bailey were classified by functional group, the content was high in the order of hydrocarbons, alcohols, esters, ketones, aldehydes, and phthalides. Sesquiterpene hydrocarbons were the most common hydrocarbons, mainly due to α-farnesene and α-caryophyllene. Among the alcohols, the content of aliphatic alcohols was significantly higher, mainly due to 1-(phenylethnyl)-1-cyclohexanol (6.34%) and phytol (4.99%). The analysis of the volatile flavor components of Chrysanthemum coronarium var. spatiosum Bailey in this study will provide useful information to consumers when purchasing food and to industries using fragrance ingredients.

The prevention of Fault by Analyzing the Gas in Oil of Oil-Filled Cable System (OF 케이블 절연유 가스분석을 통한 고장예방)

  • Kim, Du-Jin;Kim, Jae-Seung;Yoon, Jong-Keon
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.444-445
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    • 2008
  • This paper reviews the known techniques for diagnosing the condition of OF cable system and improving the service reliability. These tests are periodically achieved and intended to provide indications that the insulation system has deteriorated. One of these tests is analyzing the gas in oil on Oil-filled cable that is well known and widely accepted method. In this paper, this method of analysis and the relevant measurement standards overview and the concrete example of preventing fault incidence by performing this test is introduced.

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Changes on the Nature of Crude Oil and Heavy Fuel Oil exposed on the Sea Surface (해상에서 원유 및 중유의 경시변화 특성연구)

  • 김영희;이창섭
    • 한국해양학회지
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    • v.20 no.1
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    • pp.74-82
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    • 1985
  • Exposed on the sea, the oils are affected by the combined effects of evaporation, solution, chemical oxidation, and biological decomposition. Therefore the samples were taken after artificial weathering, and they were analyzed by gas chromatography for sulfur and hydrocarbons. The measurement results of gas chromatography have shown characteristic patterns. The peaks of the lower hydrocarbons in pollutant oil decreased with time. But the chromatograms for sulfur compound analysed by FPD showed little changes with lapse of time. The hydrocarbon and sulfur compound analysis by gas chromatography can be effectively used for analyzing oils for comparative identification.

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Trend of the Unconventional Energy Resources (비재래 에너지자원 동향)

  • Cho, Jin Dong;Kim, Jong Hyun;Park, Kwan Soon
    • Economic and Environmental Geology
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    • v.47 no.3
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    • pp.265-273
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    • 2014
  • Unconventional resources are natural resources which require greater than industry-standard levels of technology or investment to exploit the commercial development. The key point is that unconventional resources are lower quality fuel sources and are not as economically viable as crude oil and conventional gas. Over the past 100 years, Conventional oil and gas has been satisfied with the energy demands. But developing countries such as China and India, the introduction of the developed countries and the surge of energy due to the depletion of unconventional energy resources will be the limelight. According to be analyzed in the academic literature to unconventional gas and oil(2000~2012) by the program of 'web of science', the research activities 402 papers in unconventional gas and 1,581 papers in unconventional oil.

Analysis of Sterols and Its Hydrogenation to Stanols in Vegetable Oils for the Development of a Cholesterol Absorption-lowering Neutraceutical (콜레스테롤 흡수저하 기능성소재 개발을 위한 식물성 유지 중이 Sterols 분석 및 Stanol로의 수소첨가반응)

  • 인만진;김동청;채희정;김명희;임병순;김의용
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.5
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    • pp.980-983
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    • 1999
  • The contents of sterols and stanols in vegetable oils and mist oil were analyzed by gas chromatography using a capillary column. The total sterol contents showed high values of 0.67~0.89g/100g in corn oil, rice bran oil, red pepper seed oil and sesame oil. Mist oil, a byproduct of soybean oil manufacture, was a suitable raw material for the production of stanol since it showed high sterol content (10.2g/100g). In the hydrogenation of sterol contained in mist oil using Pd catalyst, the effects saponification of oil were examined. The conversion of sterol to stanol was improved by a factor of 4~5 through saponification of oil, compared to the reaction without saponification.

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Experimental Study on Wear Characteristics of Metallic Materials used in Oil Sands Plants (오일샌드 플랜트용 금속소재의 마모 특성에 대한 실험적 연구)

  • Won, Sung-Jae;Cho, Seung-Hyun;Kang, Dae-Kyung;Heo, Joong-Sik
    • Tribology and Lubricants
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    • v.33 no.1
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    • pp.31-35
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    • 2017
  • Recently, international attention has been focused on the development of non-traditional energy resources such as shale gas and oil sands, due to the steep increase in the demand for natural resources. The materials incorporated in an oil gas plant module experience extreme environments, and are prone to various problem such as fracture, corrosion and abrasion due to low-temperature brittleness. In order to improve the plant life, it is necessary to perform characteristics study and performance evaluation of the materials. In particular, this paper explains the main set of materials which are most frequently used in oil sands plant project. In order to investigate wear characteristics, the authors carried out abrasive wear tests of TP 316, stainless steel and SS 400, structural rolled steel. For the analysis of the abrasive wear resistance of an oil sands plant, the authors carried out the test according to ASTM G 105 "Standard Test Method for Conducting Wet Sand/Rubber Wheel Abrasion Test" standard guidelines. The authors have derived the results from the data associated with the loss of mass with respect to wear rate. During the test, for a given wear length for 10,000 revolutions, the rotational speed and applied force of the rubber wheel were varied.

Compositional Characterization of Petroleum Heavy Oils Generated from Vacuum Distillation and Catalytic Cracking by Positive-mode APPI FT-ICR Mass Spectrometry

  • Kim, Eun-Kyoung;No, Myoung-Han;Koh, Jae-Suk;Kim, Sung-Whan
    • Mass Spectrometry Letters
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    • v.2 no.2
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    • pp.41-44
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    • 2011
  • Molecular compositions of two types of heavy oil were studied using positive atmospheric pressure photoionization (APPI) Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS). Vacuum gas oil (VGO) was generated from vacuum distillation of atmospheric residual oil (AR), and slurry oil (SLO) was generated from catalytic cracking of AR. These heavy oils have similar boiling point ranges in the range of 210-$650^{\circ}C$, but they showed different mass ranges and double-bond equivalent (DBE) distributions. Using DBE and carbon number distributions, aromatic ring distributions, and the extent of alkyl side chains were estimated. In addition to the main aromatic hydrocarbon compounds, those containing sulfur, nitrogen, and oxygen heteroatoms were identified using simple sample preparation and ultra-high mass resolution FT-ICR MS analysis. VGO is primarily composed of mono- and di-aromatic hydrocarbons as well as sulfur-containing hydrocarbons, whereas SLO contained mainly polyaromatic hydrocarbons and sulfur-containing hydrocarbons. Both heavy oils contain polyaromatic nitrogen components. SLO inludes shorter aromatic alkyl side chains than VGO. This study demonstrates that APPI FT-ICR MS is useful for molecular composition characterization of petroleum heavy oils obtained from different refining processes.

Gas Chromatographic Determination of Flavor Stability of Cooking Oils (가스크로마토그래피에 의한 식용유의 향미 안정성 측정)

  • Kim, In-Hwan;Yoon, Suk-Hoo
    • Korean Journal of Food Science and Technology
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    • v.20 no.5
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    • pp.732-735
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    • 1988
  • Flavor stability of cooking oils such as rice bran oil, double fractionated palm olefin and soybean oil were determined by headspace analysis using gas chromatography. In the headspace, the contents of volatile compounds, oxygen and hydrogen were measured. The hydrogen content in the headspace correlated well with the contents of volatile compound (r > 0.95). Therefore, it is proposed that a single measurement of hydrogen and oxygen is used as a index of flavor stability of cooking oils instead of separate measurement of volatile compounds and oxygen. which have conventionally been used.

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Effects of Thermal Dispersion Damage on the Pyrolysis and Reactor Relarionship Using Comutational Fluids Dynamics (전산유체역학을 활용한 폐플라스틱열분해 반응기의 기체분산판에 대한 유동해석)

  • Jongil, Han;SungSoo, Park;InJea, Kim;Kwangho, Na
    • New & Renewable Energy
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    • v.19 no.4
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    • pp.53-60
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    • 2023
  • The Computational Fluid Dynamics (CFD) model is a method of studying the flow phenomenon of fluid using a computer and finding partial differential equations that dominate processes such as heat dispersion through numerical analysis. Through CFD, a lot of information about flow disorders such as speed, pressure, density, and concentration can be obtained, and it is used in various fields from energy and aircraft design to weather prediction and environmental modeling. The simulation used for fluid analysis in this study utilized Gexcon's (FLACS) CODE, such as Norway, through overseas journals, for the accuracy of the analysis results through many experiments. It was analyzed that a technology for treating two or more catalysts with physical properties under low-temperature atmospheric pressure conditions could not be found in the prior art. Therefore, it would be desirable to establish a continuous plan by reinforcing data that can prove the effectiveness of producing efficient synthetic oil (renewable oil) through the application that pyrolysis under low-temperature and atmospheric pressure conditions.

The Thermal Aging Characteristics of Cellulose Paper using Analysis for CO, $CO_2$ Gas and Furan Compounds (CO, $CO_2$ 가스와 Furan 함유량의 분석을 통한 셀룰로오스 절연지의 열 열화특성)

  • Kim, Jae-Hoon;Han, Sang-Ok
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.4
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    • pp.499-504
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    • 2009
  • The analysis for furan compound has provided a complementary technique to dissolved gas analysis(DGA) for monitoring transformers when total concentration of CO and $CO_2$ dissolved in oil only has been evaluated the aging of insulating paper. But, the analysis of furanic compounds by high performance liquid chromatography(HPLC) has been important more than DGA recently. Because it has been known that furanic components in transformer oil have come only from the decomposition of insulating paper. Therefore we have manufactured accelerating aging cell which was aged during 60 hours at 100, 150, 180 and $200^{\circ}C$, respectively, for investigating the characteristics of cellulose paper by thermal using analysis for CO, $CO_2$ and furan compound.