• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.12
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• pp.7443-7450
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• 2014

To resolve shortcomings of high-rate anaerobic processes, such as high upward flow velocity, this study sought to improve the structure of the high-rate anaerobic reactor and evaluate its performance. The improved reactor was manufactured by adjusting the diameter and dividing the reactor into three parts. The evaluation of the structurally improved reactor revealed that the reactor could stabilize a single circuit, and prevent the accumulation of solid matter and leakage of microbes, thereby stabilize the microbes. In the process of anaerobic digestion, an increase in pH and alkalinity within the reactor was presumably attributed to bicarbonate created in the process of organic matter decomposition and due to the re-dissolution of some biogas. To maintain a high rate of organic matter removal, the reactor should be operated with more than 9 hrs of HRT and an organic matter load of under $10.kgTCODcr/m^3{\cdot}d$. The methane gas generated in the anaerobic digestion process showed a high content of 65~83 % at the organic matter load of over $7.7kgTCODcr/m^3{\cdot}d$. per removal of CODcr. The methane quantity was generated at $0.10{\sim}0.23m^3CH_4/kgCOD_{rem}$, showing that it was smaller than the theoretical methane generation amount (0.35) in the STP state. In the latter part of high-rate anaerobic process, an advanced treatment process was required to remove nitrogen.

• Resources Recycling
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• v.24 no.5
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• pp.15-21
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• 2015

Waste plastic differs in its speed of combustion owing to its variety in composition as well as kinds of plastic. This study is aimed at examining the thermal weight analysis and determination of its kinetics in order to derive the design element in pyrolysis of RPF (Refused Plastic Fuel) as the plastic solid fuel. Based on the result of TGA (Thermogravimetric analysis), kinetic characteristics were analyzed by using Kissinger method which are the most common method for obtaining activation energy, and experimental conditions of TGA were set as follows: in a nitrogen atmosphere, gas flow rate of 20 ml/min, heating rate of $5{\sim}50^{\circ}C/min$, and maximum hottest temperature of $800^{\circ}C$. The method used for determining the property of waste plastic when thermally decomposed was thought feasible as the basic data in deciding the performance, design, and optimal operating condition of the reactor in the actual reactor.

• Journal of the Korean Chemical Society
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• v.4 no.1
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• pp.15-17
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• 1957

1. Preparation of Titanium tetrachloride; The following precesses were strictly followed as the preliminary step to obtain pure $TiOCl_2$, titanyl chloride; First, pure Titanium Oxide mixed with carbon is rolled into pills. After drying up perfectly, these pills are heated at 900∼1000${\circ}C$. And then the pills are subjected to the flow of $Cl_2$ gas in a quartz tube heated to 900-1000${\circ}C$. Thus Titanium tetrachloride is obtained. 2. Preparation of $TiOCl_2$ ; Yellowish trobrown solution is made by pouring 80 g of conc. HCl (sp.gr. 1.19) to 45 gr of Titanium tetrachloride (approx. 2 times of theoretical amount). Then this solution is kept settled for 5-days in a desiccator filled with phosphorous pentoxide at room temperature. As the colorless amorphous solid thus obtained is washed with aceton, 36.5 g of the pure salt are obtained. 3. Determination of composition. The analysis of the sample taken from the deposit desiccated gives the following data; (A) Qualitative analysis; a) $Ti(OH)_4$ is precipitated by adding NaOH in water solution of the salt. b) Adding $AgNO_3$ solution, the water solution of the salt gives white precipitate of AgCl. c) When acid and $H_2O_2$ are added, the solution turns its color to redish brown (This proves that $TiO^{++}$ was converted into $TiO^{++}$ by oxidation of $H_2O_2$. (B) Quantitative analysis; a) $Ti(OH)_4$ precipitated by $10{\%}$ NaOH isalitatsubjected consecutively to the filtration and ignition in porcelain crucible at approx. 1000${\circ}C$. , then $TiO_2$ thus formed is weighed and calculated into Ti content. b) Chlorine involved in water solution of the salt is determined by Vorhardt method. Result: The values obtained from previous analysis, devied by their atomic weight gives the following composition: Ti : Cl = 1 : 2 Therefore $TiOCl_2$ should be given as its molecular formula. 4. Summary. When $TiCl_4$ is additated into conc. HCl, $TiO^{++}$ formed exists as a stable form, and forms $TiOCl_2$. However $TiOCl_2$ is unstable to heating. When the temperature is raised to $65{\circ}C$the decomposition of the solution is accelerated, and gives $TiO_2$ aq. $TiOCl_2$ in addition is highly hygroscopic.

• Clean Technology
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• v.14 no.2
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• pp.110-116
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• 2008

The radioactive wastes generated from the nuclear industry can be divided into the forms of solid, liquid, or gas. Radioactive methyl iodide, a gaseous radioactive waste, is absorbed by activated carbon with 5 wt% of Trietylenediamine (1,4-diazania-bicycle[2.2.2]octane, TEDA) impregnated on the surface. Methyl Iodide ($CH_3I$) is combined chemically with TEDA (the final product : I-TEDA). To recycle radioactive activated carbon, removal of I-TEDA from activated carbon is needed. A wet method for recycling impregnated active carbon was developed to remove radioactive I-TEDA using an acetonitrile solution, which produces lots of secondary wastes. We suggest the removal of I-TEDA by supercritical carbon dioxide with co-solvents. In this experiment, we used a quartz crystal microbalance (QCM) for measuring the removal rate of the I-TEDA. From the experimental results, methanol was found to be the optimum co-solvent, and the optimum conditions such as temperature, pressure, and co-solvent flow rate were obtained. Possibility of using supercritical fluid in the removal of I-TEDA from radioactive activated carbon was also discussed.